about
Highly effective water oxidation catalysis with iridium complexes through the use of NaIO4.C-H Bond Oxidation Catalyzed by an Imine-Based Iron Complex: A Mechanistic Insight.Spectroscopic, Electrochemical and Computational Characterisation of Ru Species Involved in Catalytic Water Oxidation: Evidence for a [Ru(V) (O)(Py2 (Me) tacn)] Intermediate.Fast O2 binding at dicopper complexes containing Schiff-base dinucleating ligands.An FeIV=O complex of a tetradentate tripodal nonheme ligandModeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.Triggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by Ru(II) photocatalysis.Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates.Pro-Oxidant Activity of Amine-Pyridine-Based Iron Complexes Efficiently Kills Cancer and Cancer Stem-Like CellsNonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity.Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation.Kinetic analysis of the conversion of nonheme (alkylperoxo)iron(III) species to iron(IV) complexes.Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives.Recent Advances in the Selective Oxidation of Alkyl C-H Bonds Catalyzed by Iron Coordination Complexes.Metallosupramolecular receptors for fullerene binding and release.Generation, Spectroscopic, and Chemical Characterization of an Octahedral Iron(V)-Nitrido Species with a Neutral Ligand Platform.Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase.Enzyme-triggered delivery of chlorambucil from conjugates based on the cell-penetrating peptide BP16.Biologically Inspired C-H and C=C Oxidations with Hydrogen Peroxide Catalyzed by Iron Coordination Complexes.Identification of BP16 as a non-toxic cell-penetrating peptide with highly efficient drug delivery properties.Enantioselective hydroformylation by a Rh-catalyst entrapped in a supramolecular metallocage.Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.Unraveling the mechanism of water oxidation catalyzed by nonheme iron complexes.Identification and spectroscopic characterization of nonheme iron(III) hypochlorite intermediates.Highly Enantioselective Oxidation of Nonactivated Aliphatic C-H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes.O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding.Copper-catalyzed aerobic oxidative functionalization of an arene C-H bond: evidence for an aryl-copper(III) intermediate.Asymmetric epoxidation with H2O2 by manipulating the electronic properties of non-heme iron catalysts.A nonheme iron(II) complex that models the redox cycle of lipoxygenase.Regioselective oxidation of nonactivated alkyl C-H groups using highly structured non-heme iron catalysts.Robust iron coordination complexes with N-based neutral ligands as efficient Fenton-like catalysts at neutral pH.A synthetic model for the putative Fe(IV)(2)O(2) diamond core of methane monooxygenase intermediate Q.Olefin cis-dihydroxylation versus epoxidation by non-heme iron catalysts: two faces of an Fe(III)-OOH coin.Copper(I)-dioxygen reactivity of [(L)Cu(I)](+) (L = tris(2-pyridylmethyl)amine): kinetic/thermodynamic and spectroscopic studies concerning the formation of Cu-O2 and Cu2-O2 adducts as a function of solvent medium and 4-pyridyl ligand substituent vaA dramatic push effect on the homolysis of FeIII(OOR) intermediates to form non-heme FeIV=O complexes.Role of carboxylate bridges in modulating nonheme diiron(II)/O(2) reactivity.Spin states: discussion of an open problem.A structural and Mössbauer study of complexes with Fe(2)(micro-O(H))(2) cores: stepwise oxidation from Fe(II)(micro-OH)(2)Fe(II) through Fe(II)(micro-OH)(2)Fe(III) to Fe(III)(micro-O)(micro-OH)Fe(III).XAS characterization of end-on and side-on peroxoiron(III) complexes of the neutral pentadentate N-donor ligand N-methyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine.Observation and mechanistic study of facile C-O bond formation between a well-defined aryl-copper(III) complex and oxygen nucleophiles.
P50
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P50
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Miquel Costas
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Miquel Costas
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P214
P227
P244
P1053
H-6920-2012
P1153
7005238641
P21
P214
P227
1102903019
P244
n2015030824
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P3829
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0000-0001-6326-8299
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1971-01-01T00:00:00Z
P734
P735
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lccn-n2015030824