Trapping a diradical transition state by mechanochemical polymer extension.
about
Mechanical gating of a mechanochemical reaction cascadeMolecular engineering of mechanophore activity for stress-responsive polymeric materialsImpact of local compressive stress on the optical transitions of single organic dye molecules.Anti-Arrhenius cleavage of covalent bonds in bottlebrush macromolecules on substrate.Stress-responsive polymers containing cyclobutane core mechanophores: reactivity and mechanistic insights.Thermally controlling the singlet-triplet energy gap of a diradical in the solid state.Mechanochemical strengthening of a synthetic polymer in response to typically destructive shear forces.Chemomechanics: chemical kinetics for multiscale phenomena.External regulation of controlled polymerizations.Methods for activating and characterizing mechanically responsive polymers.Photocontrolled Living Polymerization Systems with Reversible Deactivations through Electron and Energy Transfer.Experimental Polymer Mechanochemistry and its Interpretational Frameworks.Differences in the Abilities to Mechanically Eliminate Activation Energies for Unimolecular and Bimolecular Reactions.Combined Constant-Force and Constant-Velocity Single-Molecule Force Spectroscopy of the Conrotatory Ring Opening Reaction of Benzocyclobutene.Theoretical simulation of the infrared signature of mechanically stressed polymer solids.High Mechanophore Content Polyester-Acrylate ABA Block Copolymers: Synthesis and Sonochemical Activation.Mechanical control of nanomaterials and nanosystems.Bicyclo[3.2.0]heptane mechanophores for the non-scissile and photochemically reversible generation of reactive bis-enones.Inducing and quantifying forbidden reactivity with single-molecule polymer mechanochemistry.Model studies of force-dependent kinetics of multi-barrier reactions.Comparison of the predictive performance of the Bell-Evans, Taylor-expansion and statistical-mechanics models of mechanochemistry.Chemistry. Mechanically throwing a reaction into reverse.The mechanochemical production of phenyl cations through heterolytic bond scission.An algorithm to locate optimal bond breaking points on a potential energy surface for applications in mechanochemistry and catalysis.Tough Self-Healing Elastomers by Molecular Enforced Integration of Covalent and Reversible Networks.Mechanochemical unzipping of insulating polyladderene to semiconducting polyacetylene.Optomechanical Control of Quantum Yield in Trans-Cis Ultrafast Photoisomerization of a Retinal Chromophore Model.Finding mechanochemical pathways and barriers without transition state search.Mechanochromism and Mechanical-Force-Triggered Cross-Linking from a Single Reactive Moiety Incorporated into Polymer Chains.Mechanically modulating the photophysical properties of fluorescent protein biocomposites for ratio- and intensiometric sensors.On the calculation of internal forces in mechanically stressed polyatomic molecules.Exploring the topography of the stress-modified energy landscapes of mechanosensitive molecules.A mechanochemical study of the effects of compression on a Diels-Alder reaction.Highly Sensitive Built-In Strain Sensors for Polymer Composites: Fluorescence Turn-On Response through Mechanochemical Activation.Perspective: Mechanochemistry of biological and synthetic molecules.A backbone lever-arm effect enhances polymer mechanochemistry.Mechanophores with a reversible radical system and freezing-induced mechanochemistry in polymer solutions and gels.A novel reaction of gem-difluorocyclopropyl ketones with nitriles leading to 2-fluoropyrroles.Mechanically driven activation of polyaniline into its conductive form.Force distribution analysis of mechanochemically reactive dimethylcyclobutene.
P2860
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P2860
Trapping a diradical transition state by mechanochemical polymer extension.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年論文
@yue
2010年論文
@zh-hant
2010年論文
@zh-hk
2010年論文
@zh-mo
2010年論文
@zh-tw
2010年论文
@wuu
2010年论文
@zh
2010年论文
@zh-cn
name
Trapping a diradical transition state by mechanochemical polymer extension.
@en
Trapping a diradical transition state by mechanochemical polymer extension.
@nl
type
label
Trapping a diradical transition state by mechanochemical polymer extension.
@en
Trapping a diradical transition state by mechanochemical polymer extension.
@nl
prefLabel
Trapping a diradical transition state by mechanochemical polymer extension.
@en
Trapping a diradical transition state by mechanochemical polymer extension.
@nl
P2093
P2860
P50
P356
P1433
P1476
Trapping a diradical transition state by mechanochemical polymer extension.
@en
P2093
Jeremy M Lenhardt
Mitchell T Ong
Robert Choe
P2860
P304
P356
10.1126/SCIENCE.1193412
P407
P577
2010-08-01T00:00:00Z