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Mononuclear and dinuclear complexes with a [Ru(tBu2PCH2CH2PtBu2)(CO)] core.Substitution and derivatization reactions of a water soluble iron(II) complex containing a self-assembled tetradentate phosphine ligand.Transition metal catalysed reactions of alcohols using borrowing hydrogen methodology.Copper diamidocarbene complexes: characterization of monomeric to tetrameric species.Computation provides chemical insight into the diverse hydride NMR chemical shifts of [Ru(NHC)4(L)H]0/+ species (NHC = N-heterocyclic carbene; L = vacant, H2, N2, CO, MeCN, O2, P4, SO2, H-, F- and Cl-) and their [Ru(R2PCH2CH2PR2)2(L)H]+ congeners.Experimental and computational investigation of C-N bond activation in ruthenium N-heterocyclic carbene complexes.Ni(I) and Ni(II) ring-expanded N-heterocyclic carbene complexes: C-H activation, indole elimination and catalytic hydrodehalogenation.[Ru(NHC)(xantphos)(CO)H(2)] complexes: intramolecular C-H activation and applications in C-C bond formation.Synthesis, characterization, and electrochemistry of a series of iron(II) complexes containing self-assembled 1,5-diaza-3,7-diphosphabicyclo[3.3.1]nonane ligands.The influence of N-heterocyclic carbenes (NHC) on the reactivity of [Ru(NHC)(4)H](+) with H(2), N(2), CO and O(2).Three-coordinate nickel(I) complexes stabilised by six-, seven- and eight-membered ring n-heterocyclic carbenes: synthesis, EPR/DFT studies and catalytic activity.C-C and C-H bond activation reactions in N-heterocyclic carbene complexes of ruthenium.Substitution reactions of [Ru(dppe)(CO)(H(2)O)(3)][OTf](2).Water-soluble hydroxyalkylated phosphines: examples of their differing behaviour toward ruthenium and rhodium.N-Alkylation of phenethylamine and tryptamine.Formation of [Ru(NHC)4(eta(2)-O2)H]+: an unusual, high frequency hydride chemical shift and facile, reversible coordination of O2.Synthesis and characterization of phosphorescent two-coordinate copper(i) complexes bearing diamidocarbene ligands.Ruthenium xantphos complexes in hydrogen transfer processes: reactivity and mechanistic studies.Activation of an alkyl C-H bond geminal to an agostic interaction: an unusual mode of base-induced C-H activation.Catalytic hydrodefluorination of aromatic fluorocarbons by ruthenium N-heterocyclic carbene complexes.Mono- and dinuclear Ni(i) products formed upon bromide abstraction from the Ni(i) ring-expanded NHC complex [Ni(6-Mes)(PPh3)Br].Well-Defined Heterobimetallic Reactivity at Unsupported Ruthenium-Indium Bonds.Influence of Ring-Expanded N-Heterocyclic Carbenes on the Structures of Half-Sandwich Ni(I) Complexes: An X-ray, Electron Paramagnetic Resonance (EPR), and Electron Nuclear Double Resonance (ENDOR) Study.Activation of H2 over the Ru-Zn Bond in the Transition Metal-Lewis Acid Heterobimetallic Species [Ru(IPr)2(CO)ZnEt](.).Stoichiometric and catalytic reactivity of the N-heterocyclic carbene ruthenium hydride complexes [Ru(NHC)(L)(CO)HCl] and [Ru(NHC)(L)(CO)H(eta2-BH4)] (L=NHC, PPh3).Stoichiometric and catalytic C-F bond activation by the trans-dihydride NHC complex [Ru(IEt2Me2)2(PPh3)2H2] (IEt2Me2 = 1,3-diethyl-4,5-dimethylimidazol-2-ylidene).Unexpected migratory insertion reactions of M(alkyl)2 (M=Zn, Cd) and diamidocarbenes.Experimental and Computational Studies of the Copper Borate Complexes [(NHC)Cu(HBEt3 )] and [(NHC)Cu(HB(C6 F5 )3 )].Room Temperature Regioselective Catalytic Hydrodefluorination of Fluoroarenes with trans-[Ru(NHC)4 H2 ] through a Concerted Nucleophilic Ru-H Attack Pathway.[Ru3(6-NHC)(CO)10]: synthesis, characterisation and reactivity of rare 46-electron tri-ruthenium clusters.Ruthenium bidentate phosphine complexes for the coordination and catalytic dehydrogenation of amine- and phosphine-boranes.Comparison of the photochemistry of organometallic N-heterocyclic carbene and phosphine complexes of manganese.A Comparison of the Stability and Reactivity of Diamido- and Diaminocarbene Copper Alkoxide and Hydride Complexes.C-F Bond Activation of P(CF) by Ruthenium Dihydride Complexes: Isolation and Reactivity of the "Missing" Ru(PPh)H(halide) Complex, Ru(PPh)HFStereoelectronic Effects in C–H Bond Oxidation Reactions of Ni(I) N-Heterocyclic Carbene ComplexesSynthesis, Electronic Structure, and Magnetism of [Ni(6-Mes)2]+: A Two-Coordinate Nickel(I) Complex Stabilized by Bulky N-Heterocyclic CarbenesThe reaction of M(CO)3(Ph2PCH2CH2PPh2) (M = Fe, Ru) with parahydrogen: probing the electronic structure of reaction intermediates and the internal rearrangement mechanism for the dihydride productsMono- and Bimetallic Zwitterionic Chromium(0) and Tungsten(0) AllenylsStructure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride ComplexRuthenium induced C-N bond activation of an N-heterocyclic carbene: isolation of C- and N-bound tautomers
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description
hulumtues
@sq
researcher
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wetenschapper
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հետազոտող
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name
Michael K. Whittlesey
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Michael K. Whittlesey
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Michael K. Whittlesey
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Michael K. Whittlesey
@nl
Michael K. Whittlesey
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type
label
Michael K. Whittlesey
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Michael K. Whittlesey
@en
Michael K. Whittlesey
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Michael K. Whittlesey
@nl
Michael K. Whittlesey
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prefLabel
Michael K. Whittlesey
@ast
Michael K. Whittlesey
@en
Michael K. Whittlesey
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Michael K. Whittlesey
@nl
Michael K. Whittlesey
@sl
P106
P1153
7003609532
P21
P31
P496
0000-0002-5082-3203