Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation.
about
Supramolecular coordination: self-assembly of finite two- and three-dimensional ensemblesMetal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.Molecular recognition of hydrocarbon guests by a supramolecular capsule formed by the 4:4 self-assembly of tris(Zn(2+)-cyclen) and trithiocyanurate in aqueous solution.Asymmetric spiroacetalization catalysed by confined Brønsted acids.Size-selective encapsulation of hydrophobic guests by self-assembled M4L6 cobalt and nickel cages.Experimental and theoretical studies on the Nazarov cyclization/Wagner-Meerwein rearrangement sequence.Protein-like proton exchange in a synthetic host cavity.Acceleration of an aromatic Claisen rearrangement via a designed spiroligozyme catalyst that mimics the ketosteroid isomerase catalytic dyad.Artificial enzymes based on supramolecular scaffolds.Building on architectural principles for three-dimensional metallosupramolecular construction.Supramolecular catalysis. Part 2: artificial enzyme mimics.Molecular containers in complex chemical systems.Chiral metallosupramolecular architectures.Functional behaviour from controlled self-assembly: challenges and prospects.Virtual screening for high affinity guests for synthetic supramolecular receptors.Nazarov cyclization of 1,4-pentadien-3-ols: preparation of cyclopenta[b]indoles and spiro[indene-1,4'-quinoline]s.pH-dependent binding of guests in the cavity of a polyhedral coordination cage: reversible uptake and release of drug moleculesElectrostatic origin of the catalytic effect of a supramolecular host catalyst.Beyond the Divinyl Ketone: Innovations in the Generation and Nazarov Cyclization of Pentadienyl Cation Intermediates.Tailored oxido-vanadium(V) cage complexes for selective sulfoxidation in confined spaces.Coordination-driven self-assembly of truncated tetrahedra capable of encapsulating 1,3,5-triphenylbenzene.Pairwise assembly of organopalladium(II) units with cyanurato(3-) and trithiocyanurato(3-) ligands: formation of chiral Pd12, Pd10, and Pd9 cage-moleculesDifferent and Often Opposing Forces Drive the Encapsulation and Multiple Exterior Binding of Charged Guests to a M4 L6 Supramolecular Vessel in Water.Light-triggered guest uptake and release by a photochromic coordination cage.Supramolecular bulky phosphines comprising 1,3,5-triaza-7-phosphaadamantane and Zn(salphen)s: structural features and application in hydrosilylation catalysis.Encapsulation of sodium alkyl sulfates by the cyclotriveratrylene-based, [Pd(6)L(8)](12+) stella octangula cage.Synthesis of a large functional cage compound based on four Ga-Ga single bonds and its application as an oligoacceptor: on the way to bio-organogallium hybrid molecules.A supramolecular approach to combining enzymatic and transition metal catalysis.Iminium Catalysis inside a Self-Assembled Supramolecular Capsule: Modulation of Enantiomeric Excess.Enzyme-like control of carbocation deprotonation regioselectivity in supramolecular catalysis of the Nazarov cyclization.Origins of large rate enhancements in the Nazarov cyclization catalyzed by supramolecular encapsulation.Controlled self-sorting in self-assembled cage complexes.Influence of size, shape, heteroatom content and dispersive contributions on guest binding in a coordination cage.Triggering autocatalytic reaction by host-guest interactions.Octahedral [Pd6 L8 ]12+ Metallosupramolecular Cages: Synthesis, Structures and Guest-Encapsulation Studies.A Self-Assembled Trigonal Prismatic Molecular Vessel for Catalytic Dehydration Reactions in Water.Stereospecific Decarboxylative Nazarov Cyclization Mediated by Carbon Dioxide for the Preparation of Highly Substituted 2-Cyclopentenones.Solid-State Gas Adsorption Studies with Discrete Palladium(II) [Pd2 (L)4 ]4+ Cages.A supramolecular microenvironment strategy for transition metal catalysis.Giant hollow M(n)L(2n) spherical complexes: structure, functionalisation and applications.
P2860
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P2860
Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh-hant
name
Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation.
@en
Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation.
@nl
type
label
Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation.
@en
Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation.
@nl
prefLabel
Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation.
@en
Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation.
@nl
P2093
P356
P1476
Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation.
@en
P2093
Courtney J Hastings
Kenneth N Raymond
Robert G Bergman
P304
P356
10.1021/JA102633E
P407
P577
2010-05-01T00:00:00Z