Identification of modular chiral bisphosphines effective for Cu(i)-catalyzed asymmetric allylation and propargylation of ketones.
about
Direct and highly regioselective and enantioselective allylation of β-diketonesModulation of multifunctional N,O,P ligands for enantioselective copper-catalyzed conjugate addition of diethylzinc and trapping of the zinc enolate.Brønsted acid catalyzed asymmetric propargylation of aldehydesSynthesis and ring-chain-ring tautomerism of bisoxazolidines, thiazolidinyloxazolidines, and spirothiazolidines.Enantioselective synthesis of anti- and syn-homopropargyl alcohols via chiral Brønsted acid catalyzed asymmetric allenylboration reactions.Chiral Brønsted acid catalyzed enantioselective synthesis of anti-homopropargyl alcohols via kinetic resolution-aldehyde allenylboration using racemic allenylboronates.Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones.An Expeditious Synthesis of Sialic Acid Derivatives by Copper(I)-Catalyzed Stereodivergent Propargylation of Unprotected Aldoses.Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine, and Oxetane Substrates: Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates.Practical and Broadly Applicable Catalytic Enantioselective Additions of Allyl-B(pin) Compounds to Ketones and α-Ketoesters.C-Propargylation Overrides O-Propargylation in Reactions of Propargyl Chloride with Primary Alcohols: Rhodium-Catalyzed Transfer Hydrogenation.Enantioselective synthesis of homoallylic amines through reactions of (pinacolato)allylborons with aryl-, heteroaryl-, alkyl-, or alkene-substituted aldimines catalyzed by chiral C1-symmetric NHC-Cu complexes.Diastereo- and enantioselective reactions of bis(pinacolato)diboron, 1,3-enynes, and aldehydes catalyzed by an easily accessible bisphosphine-Cu complex.Asymmetric propargylation of ketones using allenylboronates catalyzed by chiral biphenols.Mechanism of ketone allylation with allylboronates as catalyzed by zinc compounds: a DFT study.Weak arene C-H···O hydrogen bonding in palladium-catalyzed arylation and vinylation of lactones.Development of a novel multifunctional n,p ligand for highly enantioselective palladium-catalyzed asymmetric allylic etherification of alcohols and silanols.Silver-catalyzed allenylation and enantioselective propargylation reactions of ketones.A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes.Practical, Broadly Applicable, α-Selective, Z-Selective, Diastereoselective, and Enantioselective Addition of Allylboron Compounds to Mono-, Di-, Tri-, and Polyfluoroalkyl Ketones.Nickel-catalyzed asymmetric transfer hydrogenation of hydrazones and other ketimines.Three-dimensional correlation of steric and electronic free energy relationships guides asymmetric propargylation.Ni(II)-catalyzed asymmetric alkenylations of ketimines.Copper-catalyzed synthesis of allenylboronic acids. Access to sterically encumbered homopropargylic alcohols and amines by propargylboration.
P2860
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P2860
Identification of modular chiral bisphosphines effective for Cu(i)-catalyzed asymmetric allylation and propargylation of ketones.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh-hant
name
Identification of modular chiral bisphosphines effective for Cu
@nl
Identification of modular chir ...... and propargylation of ketones.
@en
type
label
Identification of modular chiral bisphosphines effective for Cu
@nl
Identification of modular chir ...... and propargylation of ketones.
@en
prefLabel
Identification of modular chiral bisphosphines effective for Cu
@nl
Identification of modular chir ...... and propargylation of ketones.
@en
P2093
P356
P1476
Identification of modular chir ...... and propargylation of ketones
@en
P2093
Masakatsu Shibasaki
Motomu Kanai
Shi-Liang Shi
P304
P356
10.1021/JA101948S
P407
P577
2010-05-01T00:00:00Z