about
Synthesis, crystal structure, aqueous speciation, and kinetics of substitution reactions in a water-soluble Mo3S4 cluster bearing hydroxymethyl diphosphine ligands.Hydrogen and copper ion induced molecular reorganizations in two new scorpiand-like ligands appended with pyridine rings.Kinetics Aspects of the Reversible Assembly of Copper in Heterometallic Mo3CuS4 Clusters with 4,4'-Di-tert-butyl-2,2'-bipyridine.Mechanism of [3+2] cycloaddition of alkynes to the [Mo3 S4 (acac)3 (py)3 ][PF6 ] cluster.Combined experimental and computational investigations of rhodium-catalysed C - H functionalisation of pyrazoles with alkenes.Chiral [Mo3S4H3(diphosphine)3]+ hydrido clusters and study of the effect of the metal atom on the kinetics of the acid-assisted substitution of the coordinated hydride: Mo vs W.Site specific ligand substitution in cubane-type Mo3FeS(4)(4+) clusters: kinetics and mechanism of reaction and isolation of mixed ligand Cl/SPh complexes.The role of solvent on the mechanism of proton transfer to hydride complexes: the case of the [W(3)PdS(4)H(3)(dmpe)(3)(CO)](+) cubane cluster.Three-coordinate nickel(I) complexes stabilised by six-, seven- and eight-membered ring n-heterocyclic carbenes: synthesis, EPR/DFT studies and catalytic activity.Computational study of the double C-Cl bond activation of dichloromethane and phosphine alkylation at [CoCl(PR3)3].Computational insights on the geometrical arrangements of Cu(II) with a mixed-donor N3S3 macrobicyclic ligand.A combined experimental and computational study of fluxional processes in sigma amine-borane complexes of rhodium and iridium.Combined kinetic and DFT studies on the stabilization of the pyramidal form of H3PO2 at the heterometal site of [Mo3M'S4(H2O)10]4+ clusters (M' = Pd, Ni).Unprecedented solvent-assisted reactivity of Hydrido W3CuS4 cubane clusters: the non-innocent behaviour of the cluster-core unit.Synthesis, reactivity, and kinetics of substitution in W3PdSe4 cuboidal clusters. A reexamination of the kinetics of substitution of the related W3S4 cluster with thiocyanate.Geometric isomerism in pentacoordinate Cu2+ complexes: equilibrium, kinetic, and density functional theory studies reveal the existence of equilibrium between square pyramidal and trigonal bipyramidal forms for a tren-derived ligand.Mechanistic Elucidation of Zirconium-Catalyzed Direct Amidation.Computational Insights on the Mechanism of H2 Activation at Ir2S2(PPh3)4: A Combination of Multiple Reaction Pathways Involving Facile H Migration Processes.Computational insights into the S3 transfer reaction: A special case of double group transfer reaction featuring bicyclically delocalized aromatic transition state geometries.Kinetic Analysis and Mechanism of the Hydrolytic Degradation of Squaramides and Squaramic Acids.A DFT and TD-DFT approach to the understanding of statistical kinetics in substitution reactions of M3Q4 (M = Mo, W; Q = S, Se) cuboidal clusters.Kinetic and DFT studies on the mechanism of C-S bond formation by alkyne addition to the [Mo3S4(H2O)9]4+ cluster.Synthesis, Electronic Structure, and Magnetism of [Ni(6-Mes)2]+: A Two-Coordinate Nickel(I) Complex Stabilized by Bulky N-Heterocyclic CarbenesMixed Explicit–Implicit Solvation Approach for Modeling of Alkane Complexation in Water-Soluble Self-Assembled CapsulesCuboidal Mo3S4 Clusters as a Platform for Exploring Catalysis: A Three-Center Sulfur Mechanism for Alkyne SemihydrogenationStudies on the Reactivity of the [W3 S4 Br3 (edpp)3 ]+ [edpp = (2-aminoethyl)diphenylphosphine] Cluster Cation towards Bases: The Active Role of the Amino GroupA combined stopped-flow, electrospray ionization mass spectrometry and31P NMR study on the acetic acid-mediated fragmentation of the hydroxo-chalcogenide cluster [W3Se4(OH)3(dmpe)3]+(dmpe = 1,2-bis(dimethylphosphanyl)ethane) to yield the dinuclear [WNew Insights into the Mechanism of Proton Transfer to Hydride Complexes: Kinetic and Theoretical Evidence Showing the Existence of Competitive Pathways for Protonation of the Cluster [W3S4H3(dmpe)3]+ with AcidsSynthesis of the Novel [W3PdS4H3(dmpe)3(CO)]+Cubane Cluster and Kinetic Studies on the Substitution of Coordinated Hydrides in Acidic MediaThe Structure of ([W3Q4X3(dmpe)3]+, Y-) Ion Pairs (Q = S, Se; X = H, OH, Br; Y = BF4, PF6, dmpe = Me2PCH2CH2PMe2) in Dichloromethane Solution and the Effect of Ion-Pairing on the Kinetics of Proton Transfer to the Hydride Cluster [W3S4H3(dmpe)3]+The Solution Chemistry of Cu2+-tren Complexes Revisited: Exploring the Role of Species That Are Not Trigonal BipyramidalCatalytic effect of a second H3PO2 in the mechanism of stabilisation of the unstable pyramidal tautomer of H3PO2 coordinated at [Mo3S4M'] clusters (M' = Ni, Pd)Dihydrogen complexes: striking effect of ion pairing to BF(4)(-) on the rotation of coordinated dihydrogen and the (19)F relaxation timeKinetic, DFT and TD-DFT studies on the mechanism of stabilization of pyramidal H3PO3 at the [Mo3M'S4(H2O)10]4+ clusters (M' = Pd, Ni)Synthesis and characterization of a rhodium(I) σ-alkane complex in the solid stateOn the Critical Effect of the Metal (Mo vs. W) on the [3+2] Cycloaddition Reaction of M3 S4 Clusters with Alkynes: Insights from Experiment and TheoryCombined experimental and computational investigations of rhodium- and ruthenium-catalyzed C-H functionalization of pyrazoles with alkynesCoordination Chemistry of Cu2+ Complexes of Small N-Alkylated Tetra-azacyclophanes with SOD Activity
P50
Q31121552-59DD0566-02D2-49C4-9B7A-DB98F784DD1CQ33627964-C55A2ECD-C3FB-4BE3-9325-DC5672B787FDQ38817269-66215FC7-67C6-4DC8-A039-5FE8EF0928BCQ41662616-37B10EF1-A0BA-46F6-8EDB-2728F4B8737BQ41959623-583D7305-B2EA-4BC0-A0A8-DD5608A23BD8Q43049130-33B74520-3274-48ED-A30A-7DE4BBB54118Q43114248-260CC8C8-BD4A-4309-9F18-9C5463EA6B63Q43210947-EDEBC5D0-DBC8-404C-BDD7-EAE4F5BF2B97Q43500396-7856CB0E-FD78-48E9-A9D5-AB3DF243D9A1Q44551441-1169754F-2958-4CE2-8C23-3CAD6A0A8B7FQ44764652-B97D07FE-5925-45FA-810A-9E86507501D9Q45978762-8A3E9715-EF9C-4938-A146-081133C14412Q46022428-BEA3B987-9DBD-44CD-9F92-EA11C839BF81Q46085899-AAFC31D6-136B-4DE0-A469-739694307678Q46091001-46D6BAAC-37A9-4E72-84C1-B141A31671FFQ46149806-4D06FCF6-34A6-454D-B48E-CD65DB9075E6Q46430716-A23F27A4-07AE-421C-A193-6F875E6E95D8Q48051932-62900A0C-0FB5-4789-9B1E-28D1D744D2BDQ48060412-880AC529-223A-4110-A05A-333C19033DE6Q48329701-23CB7B2C-DDEC-4071-BB32-9332659B99ADQ51405140-B1924EAA-80AB-42A5-AE9E-3119EE0F4AC5Q54550516-C1EF29C3-F0B2-4A70-9AAF-0F9EE44EBB02Q59801749-2AC1042C-E1C6-4F70-BE95-641269AB8305Q60210334-74B19765-608F-4621-8374-AF86C5F7E934Q60221242-22F5274C-C807-4FA4-8076-C07A82F8B215Q60221243-66D722B7-9A48-4521-BE66-F0242F511017Q60221434-300CCEAD-BE3C-4E7F-A6B5-AB1140019BE1Q60221441-E8FF8FEC-CA2E-4632-9C91-DB41974DBC32Q60221444-DCB0137B-399A-4310-A9C7-A6F4F21C6138Q60221446-D0E3D814-15A4-4987-8B78-4AC0320DC43BQ64034302-26A36E16-FE41-4A56-9BCF-9CFC5E63F737Q80636605-CA62C378-F80D-437A-9C56-66837D87944FQ84255555-2ECF89C1-7D46-4201-A9C1-09B75F8A91B0Q84629084-0DD9CFE0-ACD8-4C60-A525-A58C8D88BFB1Q84872679-E8AA9D5C-0D34-436E-BF52-D7F461C2B71BQ86187718-F31A2522-2155-4A1B-BF67-51B278306C34Q87349839-10D68378-0B73-472F-8BC2-3BC45F82F943Q91060527-97C6D495-8FD3-41AE-8B22-681BE215FEEE
P50
description
hulumtues
@sq
onderzoeker
@nl
researcher
@en
հետազոտող
@hy
name
Andrés G Algarra
@ast
Andrés G Algarra
@en
Andrés G Algarra
@es
Andrés G Algarra
@nl
type
label
Andrés G Algarra
@ast
Andrés G Algarra
@en
Andrés G Algarra
@es
Andrés G Algarra
@nl
prefLabel
Andrés G Algarra
@ast
Andrés G Algarra
@en
Andrés G Algarra
@es
Andrés G Algarra
@nl
P1053
C-1280-2011
P106
P21
P31
P3829
P496
0000-0002-5062-2858