Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions.
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Synthetic Strategies for 5- and 6-Membered Ring Azaheterocycles Facilitated by Iminyl RadicalsFunctionalised Oximes: Emergent Precursors for Carbon-, Nitrogen- and Oxygen-Centred RadicalsNew amination strategies based on nitrogen-centered radical chemistry.Triiodide-Mediated δ-Amination of Secondary C-H Bonds.Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical-radical coupling.Synthesis of Arylamines via Aminium Radicals.Visible-light-mediated, nitrogen-centered radical amination of tertiary alkyl halides under metal-free conditions to form α-tertiary amines.Photoredox Imino Functionalizations of Olefins.A Simple and Broadly Applicable C-N Bond Forming Dearomatization Protocol Enabled by Bifunctional Amino Reagents.Aggregation-induced visible light absorption makes reactant 1,2-diisocyanoarenes act as photosensitizers in double radical isocyanide insertions.Copper-Catalyzed Intermolecular Heck-Like Coupling of Cyclobutanone Oximes Initiated by Selective C-C Bond Cleavage.Reagent-Free C-H/N-H Cross-Coupling: Regioselective Synthesis of N-Heteroaromatics from Biaryl Aldehydes and NH3.Divergent Iron-Catalyzed Coupling of O-Acyloximes with Silyl Enol Ethers.A Visible-Light-Driven Iminyl Radical-Mediated C-C Single Bond Cleavage/Radical Addition Cascade of Oxime Esters.Visible-Light-Induced Carbo-2-pyridylation of Electron-Deficient Alkenes with Pyridinium Salts.Organophotocatalytic Generation of N- and O-Centred Radicals Enables Aerobic Oxyamination and Dioxygenation of Alkenes.Donor-Acceptor Complex Enables Alkoxyl Radical Generation for Metal-Free C(sp3 )-C(sp3 ) Cleavage and Allylation/Alkenylation.Alkene functionalization for the stereospecific synthesis of substituted aziridines by visible-light photoredox catalysis.Iminyl-Radicals by Oxidation of α-Imino-oxy Acids: Photoredox-Neutral Alkene Carboimination for the Synthesis of Pyrrolines.Visible-Light Promoted Distereodivergent Intramolecular Oxyamidation of Alkenes.Teaching Old Compounds New Tricks: DDQ-Photocatalyzed C-H Amination of Arenes with Carbamates, Urea, and N-Heterocycles.Visible-Light-Induced Direct Oxidative C-H Amidation of Heteroarenes with Sulfonamides.Photoinduced Remote Functionalisations by Iminyl Radical Promoted C-C and C-H Bond Cleavage Cascades.α-Aminoxy-Acid-Auxiliary-Enabled Intermolecular Radical γ-C(sp3 )-H Functionalization of Ketones.Visible-light promoted γ-cyanoalkyl radical generation: three-component cyanopropylation/etherification of unactivated alkenes.Metal-Free Photoredox Catalyzed Cyclization of O-(2,4-Dinitrophenyl)oximes to Phenanthridines.A Rhodium Catalyst Superior to Iridium Congeners for Enantioselective Radical Amination Activated by Visible Light.γ-Functionalizations of Amines through Visible-Light-Mediated, Redox-Neutral C-C Bond Cleavage.Fe-Catalyzed Amination of (Hetero)Arenes with a Redox-Active Aminating Reagent under Mild Conditions.Visible-Light-Mediated Remote Aliphatic C-H Functionalizations through a 1,5-Hydrogen Transfer Cascade.Dichotomous mechanistic behavior in Narasaka–Heck cyclizations: electron rich Pd-catalysts generate iminyl radicals† †Electronic supplementary information (ESI) available: Experimental procedures and characterisation data for all compounds are proviEnantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complexα-Aminoxy-Acid-Auxiliary-Enabled Intermolecular Radical γ-C(sp3 )−H Functionalization of KetonesIminyl-Radicals by Oxidation of α-Imino-oxy Acids: Photoredox-Neutral Alkene Carboimination for the Synthesis of Pyrrolines
P2860
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P2860
Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions.
description
2015 nî lūn-bûn
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2015年の論文
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2015年学术文章
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2015年学术文章
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2015年学术文章
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2015年学术文章
@zh-hans
2015年学术文章
@zh-my
2015年学术文章
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2015年學術文章
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2015年學術文章
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name
Visible-Light-Mediated Generat ...... ylation Cyclization Reactions.
@en
Visible-Light-Mediated Generat ...... ylation Cyclization Reactions.
@nl
type
label
Visible-Light-Mediated Generat ...... ylation Cyclization Reactions.
@en
Visible-Light-Mediated Generat ...... ylation Cyclization Reactions.
@nl
prefLabel
Visible-Light-Mediated Generat ...... ylation Cyclization Reactions.
@en
Visible-Light-Mediated Generat ...... ylation Cyclization Reactions.
@nl
P2093
P2860
P356
P1476
Visible-Light-Mediated Generat ...... ylation Cyclization Reactions.
@en
P2093
Jacob Davies
Robert A W Dryfe
Stephanie Essafi
P2860
P304
14017-14021
P356
10.1002/ANIE.201507641
P407
P577
2015-09-28T00:00:00Z