Axial ligand orientations in a distorted porphyrin macrocycle: synthesis, structure, and properties of low-spin bis(imidazole)iron(III) and iron(II) porphyrinates.

Axial ligand orientations in a distorted porphyrin macrocycle: synthesis, structure, and properties of low-spin bis(imidazole)iron(III) and iron(II) porphyrinates.

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http://www.wikidata.org/entity/Q43175600
Fractional transfer of a free unpaired electron to overcome energy barriers in the formation of Fe(4+) from Fe(3+) during the core contraction of macrocycles: implication for heme distortion.Hydrogen-Bonding Interactions Trigger a Spin-Flip in Iron(III) Porphyrin ComplexesUnusual stabilization of an intermediate spin state of iron upon the axial phenoxide coordination of a diiron(III)-bisporphyrin: effect of heme-heme interactions.Synthesis of cyclic carbonates from epoxides and carbon dioxide catalyzed by an easy-to-handle ionic iron(III) complex.Diiron(III)-μ-Fluoro Bisporphyrins: Effect of Bridging Ligand on the Metal Spin State.Synthesis and characterization of a modified "picket fence" porphyrin complex - stronger π bonding interactions between Fe(ii) and axial ligands.Protonation of an oxo-bridged diiron unit gives two different iron centers: synthesis and structure of a new class of diiron(III)-μ-hydroxo bisporphyrins and the control of spin states by using counterions.Hydroxo-bridged diiron(iii) and dimanganese(iii) bisporphyrins: modulation of metal spins by counter anions.Effect of Inter-Porphyrin Distance on Spin-State in Diiron(III) μ-Hydroxo Bisporphyrins.Oxidation triggers extensive conjugation and unusual stabilization of two di-heme dication diradical intermediates: role of bridging group for electronic communication.
P2860

Axial ligand orientations in a distorted porphyrin macrocycle: synthesis, structure, and properties of low-spin bis(imidazole)iron(III) and iron(II) porphyrinates.

Item
http://www.wikidata.org/entity/Q43175600
description
2010 nî lūn-bûn
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2010年の論文
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2010年学术文章
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2010年学术文章
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2010年学术文章
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2010年学术文章
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2010年学术文章
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2010年學術文章
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name
Axial ligand orientations in a ...... I) and iron(II) porphyrinates.
@en
Axial ligand orientations in a ...... I) and iron(II) porphyrinates.
@nl
type
label
Axial ligand orientations in a ...... I) and iron(II) porphyrinates.
@en
Axial ligand orientations in a ...... I) and iron(II) porphyrinates.
@nl
prefLabel
Axial ligand orientations in a ...... I) and iron(II) porphyrinates.
@en
Axial ligand orientations in a ...... I) and iron(II) porphyrinates.
@nl
P1433
P1476
P2093
P304
P31
P356
P407
P433
P478
P50
P577
P698
P356
P1433
P1476
Axial ligand orientations in a ...... II) and iron(II) porphyrinates
@en
P2093
P304
P31
P356
P407
P433
P478
P50
P577
P698