Stable N-heterocyclic carbene adducts of arylchlorosilylenes and their germanium homologues.
about
[2+2+1] cycloadditions of bis(dialkylamino)acetylenes with SiI2(Idip): syntheses and reactivity studies of unprecedented 2,3,4,5-tetraamino-1 H-siloles.Advances in Phosphasilene Chemistry.Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene.Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+.Rhenium-germanium triple bonds: syntheses and reactions of the germylidyne complexes mer-[X2(PMe3)3Re≡Ge-R] (X=Cl, I, H; R=m-terphenyl).A multiply functionalized base-coordinated Ge(II) compound and its reversible dimerization to the digermene.Si=Si Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene.The donor-stabilized silylene bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): synthesis, electronic structure, and reactivity.From an Isolable Acyclic Phosphinosilylene Adduct to Donor-Stabilized Si=E Compounds (E=O, S, Se).A Persistent 1,2-Dihydrophosphasilene Adduct.NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity.Adduct Formation, B-H Activation and Ring Expansion at Room Temperature from Reactions of HBcat with NHCs.Reactivity of NHC Alane Adducts towards N-Heterocyclic Carbenes and Cyclic (Alkyl)(amino)carbenes: Ring Expansion, Ring Opening, and Al-H Bond Activation.Cyclic amino(carboranyl) silylene: synthesis, structure and reactivity.One-Electron Oxidation of a Disilicon(0) Compound: An Experimental and Theoretical Study of [Si2](+) Trapped by N-Heterocyclic Carbenes.Assembly of NHC-stabilized 2-hydrophosphasilenes from Si(iv) precursors: a Lewis acid-base complex.A facile access to a novel NHC-stabilized silyliumylidene ion and C-H activation of phenylacetylene.A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom.Reactivity of an NHC-stabilized silylene towards ketones. Formation of silicon bis-enolates vs. bis-silylation of the C[double bond, length as m-dash]O bond.Silylation of N-heterocyclic carbene with aminochlorosilane and -disilane: dehydrohalogenation vs. Si-Si bond cleavage.Synthesis of stable silicon heterocycles by reaction of organic substrates with a chlorosilylene [PhC(NtBu)2SiCl].
P2860
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P2860
Stable N-heterocyclic carbene adducts of arylchlorosilylenes and their germanium homologues.
description
2010 nî lūn-bûn
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2010年の論文
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2010年学术文章
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2010年学术文章
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2010年学术文章
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2010年学术文章
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name
Stable N-heterocyclic carbene ...... nd their germanium homologues.
@en
Stable N-heterocyclic carbene ...... nd their germanium homologues.
@nl
type
label
Stable N-heterocyclic carbene ...... nd their germanium homologues.
@en
Stable N-heterocyclic carbene ...... nd their germanium homologues.
@nl
prefLabel
Stable N-heterocyclic carbene ...... nd their germanium homologues.
@en
Stable N-heterocyclic carbene ...... nd their germanium homologues.
@nl
P2093
P356
P1476
Stable N-heterocyclic carbene ...... nd their germanium homologues.
@en
P2093
Alexander C Filippou
Burgert Blom
Gregor Schnakenburg
Kai W Stumpf
Oleg Chernov
P304
P356
10.1002/CHEM.200903019
P407
P577
2010-03-01T00:00:00Z