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Chiral recognition by mass-resolved laser spectroscopy.Dissymmetry effects on the laser spectroscopy of supersonically expanded rare gas/chiral arene heteroclusters.Photo-ionization spectroscopy and mass spectrometry of some molecular and supramolecular asymmetric systems in the isolated state.Gas-phase facial diastereoselectivity of equatorial and axial 4-chloro-adamant-2-yl cations.Troposelective substitutions in microsolvated systems.Origin of diastereofacial selectivity in tertiary 2-adamantyl cations.Hindered inversion of chiral ion-dipole pairs.R2PI Study of intermolecular hydrogen bond in solvent-free chiral complexes.Enantioselective guest exchange in a chiral resorcin[4]arene cavity.Isomeric alkyl cation/arene complexes in the gas phase.Facial selectivity of the (R)-1,3-dimethyl-1-cyclohexyl cation in the gas phase.Role of the solvent on the stability of cycloserine under ESI-MS conditions.Importance of entropy in the diastereoselectivity of 5-substituted 2-methyladamant-2-yl cations.Chiral recognition by resorcin[4]arene receptors: intrinsic kinetics and dynamics.Cavity effects on the enantioselectivity of chiral amido[4]resorcinarene stereoisomers.Polar substituent effects in the bicyclo[1.1.1]pentane ring system: acidities of 3-substituted bicyclo[1.1.1]pentane-1-carboxylic acids.Does a chiral alcohol really racemize when its OH group is protected with Boyer's reaction?Unexpected behavior of diastereomeric ions in the GasPhase: a stimulus for pondering on ee measurements by ESI-MS.Reaction diastereoselectivity of chiral aminoalcohols/[Co(II)NO3]+ complexes in evaporating ESI nanodroplets: new insights from a joint experimental and computational investigation.Crucial role of elusive isomeric eta-complexes in gas-phase electrophilic aromatic alkylations.Angle-resolved photoelectron spectroscopy of randomly oriented 3-hydroxytetrahydrofuran enantiomers.Fast stereoselective reactions in electrosprayed Co(II)/neurotransmitter nanodroplets.Exceptional gas-phase enantioselectivity of chiral tetramide macrocycles.Diastereoselective fragmentation of chiral alpha-aminophosphonic acids/metal ion aggregates.Induced-fit in the gas phase: conformational effects on the enantioselectivity of chiral tetra-amide macrocycles.Flattened cone 2,8,14,20-tetrakis(L-valinamido)[4]resorcinarene: an enantioselective allosteric receptor in the gas phase.Electronic structure and conformational flexibility of D-cycloserine.Eliminative Ring Opening of Oxiranium Ions in the Gas Phase This work was supported by the Ministero della Università e della Ricerca Scientifica e Tecnologica (MURST) and the Consiglio Nazionale delle Ricerche (CNR). Thanks are due to Claudio LilloEnantiodiscrimination of chiral alpha-aminophosphonic acids by mass spectrometryChiral Recognition of O-Phosphoserine by Mass Spectrometry This work was supported by the Ministero della Università e della Ricerca Scientifica e Tecnologica (MURST) and the Consiglio Nazionale delle Ricerche (CNR). The authors express their gratitGas-phase activation and reaction dynamics of chiral ion-dipole complexesSubstituent effects on the stereochemistry of gas-phase intracomplex nucleophilic substitutionsGas-phase enantioselectivity of chiral amido[4]resorcinarene receptorsGas-phase diastereoselectivity of secondary 5-substituted (X)-adamant-2-yl (X = F, Si(CH(3))(3)) cationsGaseous ion activation dynamics: the role of the bulk gas in the racemization of chiral oxonium ionsCyclochiral resorcin[4]arenes as effective enantioselectors in the gas phaseThe "bridge" game: role of the fourth player in chiral recognitionChirality effects on the IRMPD spectra of basket resorcinarene/nucleoside complexesEnantioselective supramolecular carriers for nucleoside drugs. A thermodynamic and kinetic gas phase investigationSpectroscopic evidence for a gas-phase librating G-quartet-Na(+) complex
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hulumtues
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wetenschapper
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հետազոտող
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Antonello Filippi
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Antonello Filippi
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Antonello Filippi
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Antonello Filippi
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Antonello Filippi
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Antonello Filippi
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Antonello Filippi
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Antonello Filippi
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Antonello Filippi
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Antonello Filippi
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Antonello Filippi
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Antonello Filippi
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7006977737
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0000-0001-8827-2825