Pd(II) acts simultaneously as a Lewis acid and as a transition-metal catalyst: synthesis of cyclic alkenyl ethers from acetylenic aldehydes.
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A simple and mild synthesis of 1H-isochromenes and (Z)-1-alkylidene-1,3-dihydroisobenzofurans by the iodocyclization of 2-(1-alkynyl)benzylic alcohols.Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates.Enantioselective total synthesis of (-)-acetylaranotin, a dihydrooxepine epidithiodiketopiperazine.Synthesis of 3-iodoindoles by the Pd/Cu-catalyzed coupling of N,N-dialkyl-2-iodoanilines and terminal acetylenes, followed by electrophilic cyclization.Syntheses of isochromenes and naphthalenes by electrophilic cyclization of acetylenic arenecarboxaldehydes.Recent advances in heterobimetallic catalysis across a "transition metal-tin" motif.Inverse-Electron-Demand Diels-Alder Reactions: Principles and Applications.Ruthenium(0)-Catalyzed [4+2] Cycloaddition of Acetylenic Aldehydes with α-Ketols: Convergent Construction of Angucycline Ring Systems.Palladium-catalyzed carbocyclization of alkynyl ketones proceeding through a carbopalladation pathway.Density Functional Study of Mo-Carbonyl-Catalyzed Alkynol Cycloisomerization: Comparison with W-Catalyzed Reaction.Gold-catalyzed annulations of 2-alkynyl benzaldehydes with vinyl ethers: synthesis of dihydronaphthalene, isochromene, and bicyclo[2.2.2]octane derivatives.Silver-catalyzed C-C bond formation with carbon dioxide: significant synthesis of dihydroisobenzofurans.Mild rhodium(III)-catalyzed cyclization of amides with α,β-unsaturated aldehydes and ketones to azepinones: application to the synthesis of the homoprotoberberine framework.Gold-catalyzed tandem Diels-Alder reactions of enynals/enynones with alkenes: generation and trapping of cyclic o-QDMs.Bioinspired intramolecular Diels-Alder reaction: a rapid access to the highly-strained cyclopropane-fused polycyclic skeleton.Tetracyclic dihydronaphthalene derivatives via gold-catalyzed aminative homodimerization of ortho-alkynylbenzaldehydes.Metal-Free Reaction of ortho-Carbonylated Alkynyl-Substituted Arylaldehydes with Common Amines: Selective Access to Functionalized Isoindolinone and Indenamine Derivatives.One-pot synthesis of 1H-isochromenes and 1,2-dihydroisoquinolines by a sequential isocyanide-based multicomponent/Wittig reaction.Rapid Access to 2-Methylene Tetrahydrofurans and γ-Lactones: A Tandem Four-Step Process.Palladium-catalyzed highly regioselective 6-exo-dig cyclization and alkenylation of ortho-ethynylanilides: the synthesis of polyene-substituted benzo[d][1,3]oxazines.Metal-catalyzed formation of 1,3-cyclohexadienes: a catalyst-dependent reaction.C,O-Chelated BINOL/Gold(III) Complexes: Synthesis and Catalysis with Tunable Product Profiles.The First Formation of (1Z)-1-Alkylidene-1H-isobenzofuranium Amides and 1H-Inden-1-ones: Acid-Promoted 5-exoCyclization and Hydration/Aldol Condensation Reactions ofo-Ethynylbenzophenones
P2860
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P2860
Pd(II) acts simultaneously as a Lewis acid and as a transition-metal catalyst: synthesis of cyclic alkenyl ethers from acetylenic aldehydes.
description
2002 nî lūn-bûn
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2002年の論文
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2002年学术文章
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name
Pd(II) acts simultaneously as ...... ers from acetylenic aldehydes.
@en
type
label
Pd(II) acts simultaneously as ...... ers from acetylenic aldehydes.
@en
prefLabel
Pd(II) acts simultaneously as ...... ers from acetylenic aldehydes.
@en
P2093
P356
P1476
Pd(II) acts simultaneously as ...... ers from acetylenic aldehydes.
@en
P2093
Kumiko Takahashi
Naoki Asao
Tsutomu Nogami
Yoshinori Yamamoto
P304
P356
10.1021/JA017366B
P407
P577
2002-02-01T00:00:00Z