An unexpected bispericyclic transition structure leading to 4+2 and 2+4 cycloadducts in the endo dimerization of cyclopentadiene.
about
Diels-Alderase-free, bis-pericyclic, [4+2] dimerization in the biosynthesis of (±)-paracaseolide ABifurcations on potential energy surfaces of organic reactionsNatural [4 + 2]-Cyclases.Overriding the alkynophilicity of gold: catalytic pathways from higher energy Au(I)-substrate complexes and reactant deactivation via unproductive complexation in the gold(I)-catalyzed propargyl Claisen rearrangement.Dynamic effects on the periselectivity, rate, isotope effects, and mechanism of cycloadditions of ketenes with cyclopentadiene.Racing carbon atoms. Atomic motion reaction coordinates and structural effects on Newtonian kinetic isotope effects.Control elements in dynamically determined selectivity on a bifurcating surfaceDynamically Complex [6+4] and [4+2] Cycloadditions in the Biosynthesis of Spinosyn ADynamic origin of the stereoselectivity of a nucleophilic substitution reaction.Newtonian kinetic isotope effects. Observation, prediction, and origin of heavy-atom dynamic isotope effects.Origins of stereoselectivity in the trans Diels-Alder paradigmRecrossing and dynamic matching effects on selectivity in a Diels-Alder reaction.Molecular dynamics calculation of molecular volumes and volumes of activation.Total Synthesis of a Dimeric Thymol Derivative Isolated from Arnica sachalinensis.Wave packets in a bifurcating region of an energy landscape: Diels-Alder dimerization of cyclopentadiene.Total Synthesis of a Dimeric Thymol Derivative Isolated from Arnica sachalinensis
P2860
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P2860
An unexpected bispericyclic transition structure leading to 4+2 and 2+4 cycloadducts in the endo dimerization of cyclopentadiene.
description
2002 nî lūn-bûn
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2002年の論文
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2002年学术文章
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2002年学术文章
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2002年学术文章
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2002年学术文章
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2002年学术文章
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2002年学术文章
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2002年學術文章
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name
An unexpected bispericyclic tr ...... merization of cyclopentadiene.
@en
An unexpected bispericyclic tr ...... merization of cyclopentadiene.
@nl
type
label
An unexpected bispericyclic tr ...... merization of cyclopentadiene.
@en
An unexpected bispericyclic tr ...... merization of cyclopentadiene.
@nl
prefLabel
An unexpected bispericyclic tr ...... merization of cyclopentadiene.
@en
An unexpected bispericyclic tr ...... merization of cyclopentadiene.
@nl
P356
P1476
An unexpected bispericyclic tr ...... imerization of cyclopentadiene
@en
P2093
Pierluigi Caramella
P304
P356
10.1021/JA016622H
P407
P577
2002-02-01T00:00:00Z