Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes.
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Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds.Borylenes: An Emerging Class of Compounds.Generation of 1,2-azaboretidines via reduction of ADC borane adducts.Ambiphilic boron in 1,4,2,5-diazadiborinine.Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N3)].A snapshot of inorganic Janovsky complex analogues featuring a nucleophilic boron center.Triaminotriborane(3): A Homocatenated Boron Chain Connected by B-B Multiple Bonds.From Borane to Borylene without Reduction: Ambiphilic Behavior of a Monovalent Silylisonitrile Boron Species.N-Heterocyclic Carbene Stabilized Boryl Radicals.Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square.Interactions of Isonitriles with Metal-Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron.Base-Stabilized Phosphinidene Boranes by Silylium-Ion Abstraction.Serendipitous Observation of Al(I) Insertion into a CO Bond in L2 PhB: (L=oxazol-2-ylidene).The synthesis and structure of a carbene-stabilized iminocarboranyl-boron(I) compound.Encapsulating Inorganic Acetylene, HBNH, Using Flanking Coordinative Interactions.Multiple complexation of CO and related ligands to a main-group element.Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor.Diverse reactivity of a tricoordinate organoboron L2PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors.Crystalline boron-linked tetraaminoethylene radical cations.Crystalline Neutral Allenic Diborene.A DFT Study on the Stabilization of the B≡B Triple Bond in a Metallaborocycle: Contrasting Electronic Structures of Boron and Carbon Analogues.Reactivity of a Dihydrodiborene with CO: Coordination, Insertion, Cleavage, and Spontaneous Formation of a Cyclic Alkyne.Synthesis and Reduction of Sterically Encumbered Mesoionic Carbene-Stabilized Aryldihaloboranes.Synthesis and Trapping of Iminoboranes by M=B/C=N Bond Metathesis.Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C-H and C-F Bond Activation.Ambireactive (R3 P)2 BH2 Groups Facilitating Temperature-Switchable Bond Activation by an Iron Complex.Phosphine-Stabilized Borylenes and Boryl Anions as Ligands? Redox Reactivity in Boron-Based Pincer Complexes.Addition of dihydrogen to a borylborenium center.Donor ligands based on tricoordinate boron formed by B-H-activation of bis(phosphine)boronium salts.Boron compounds tackle dinitrogen.Striking transformations of the hydroborylene ligand in a HB:→NiII complex with isocyanides and CO.Transition metal-mediated donor-acceptor coordination of low-oxidation state Group 14 element halides.Reduction of a diamidocarbene-supported borenium cation: isolation of a neutral boryl-substituted radical and a carbene-stabilized aminoborylene.Exceptionally Strong Electron-Donating Ability of Bora-Ylide Substituent vis-à-vis Silylene and Silylium Ion.The Lightest Element Phosphoranylidene: NHC-Supported Cyclic Borylidene-Phosphorane with Significant B=P Character.Uncatalyzed Hydrogenation of First-Row Main Group Multiple Bonds.New Trinuclear Complexes of Group 6, 8, and 9 Metals with a Triply Bridging Borylene Ligand.Closely related yet different: a borylene and its dimer are non-interconvertible but connected through reactivity.Anorganische Chemie 2014Formation of a Carbene-Phosphinidene Adduct by NHC-Induced P-P Bond Cleavage in Sodium Tetramesityltetraphosphanediide
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Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes.
description
2014 nî lūn-bûn
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2014年の論文
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2014年学术文章
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2014年学术文章
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2014年学术文章
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name
Synthesis and reactivity of a ...... ctronic with singlet carbenes.
@en
Synthesis and reactivity of a ...... ctronic with singlet carbenes.
@nl
type
label
Synthesis and reactivity of a ...... ctronic with singlet carbenes.
@en
Synthesis and reactivity of a ...... ctronic with singlet carbenes.
@nl
prefLabel
Synthesis and reactivity of a ...... ctronic with singlet carbenes.
@en
Synthesis and reactivity of a ...... ctronic with singlet carbenes.
@nl
P2093
P2860
P356
P1476
Synthesis and reactivity of a ...... ctronic with singlet carbenes.
@en
P2093
David Martin
Douglas W Stephan
Fatme Dahcheh
P2860
P304
13159-13163
P356
10.1002/ANIE.201408371
P407
P50
P577
2014-09-29T00:00:00Z