Spectroscopic and electronic structure studies of the diamagnetic side-on CuII-superoxo complex Cu(O2)[HB(3-R-5-iPrpz)3]: antiferromagnetic coupling versus covalent delocalization.
about
Copper active sites in biologySpectroscopic and computational insight into the activation of O2 by the mononuclear Cu center in polysaccharide monooxygenasesImino-oxy acetic acid dealkylation as evidence for an inner-sphere alcohol intermediate in the reaction catalyzed by peptidylglycine alpha-hydroxylating monooxygenase.A little spin on the side: solvent and temperature dependent paramagnetism in [Ru(II)(bpy)2(phendione)](2+).Intermediates in the oxygenation of a nonheme diiron(II) complex, including the first evidence for a bound superoxo speciesCopper dioxygen (bio)inorganic chemistrySpectroscopic and computational characterization of CuII-OOR (R = H or cumyl) complexes bearing a Me6-tren ligandComments on the nature of the bonding in oxygenated dinuclear copper enzyme models.Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.Cu-ZSM-5: A biomimetic inorganic model for methane oxidationX-ray absorption edge spectroscopy and computational studies on LCuO2 species: Superoxide-Cu(II) versus peroxide-Cu(III) bonding.Stopped-Flow Studies of the Reduction of the Copper Centers Suggest a Bifurcated Electron Transfer Pathway in Peptidylglycine Monooxygenase.Effects of thioether substituents on the O2 reactivity of beta-diketiminate-Cu(I) complexes: probing the role of the methionine ligand in copper monooxygenasesMononuclear Cu-O2 complexes: geometries, spectroscopic properties, electronic structures, and reactivityStructure of the Reduced Copper Active Site in Preprocessed Galactose Oxidase: Ligand Tuning for One-Electron O2 Activation in Cofactor Biogenesis.Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct.A [Cu2O]2+ core in Cu-ZSM-5, the active site in the oxidation of methane to methanolL-edge X-ray absorption spectroscopy and DFT calculations on Cu2O2 species: direct electrophilic aromatic attack by side-on peroxo bridged dicopper(II) complexes.O2 activation by binuclear Cu sites: noncoupled versus exchange coupled reaction mechanismsCopper is a Cofactor of the Formylglycine-Generating EnzymeTransition-metal ions in zeolites: coordination and activation of oxygen.A personal perspective on the discovery of dioxygen adducts of copper and iron by Nobumasa Kitajima.Substrate-Induced Carbon Monoxide Reactivity Suggests Multiple Enzyme Conformations at the Catalytic Copper M-Center of Peptidylglycine Monooxygenase.Side-on cupric-superoxo triplet complexes as competent agents for H-abstraction relevant to the active site of PHM.An anionic, tetragonal copper(II) superoxide complex.Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms.Defining the electronic and geometric structure of one-electron oxidized copper-bis-phenoxide complexes.Correlation of the electronic and geometric structures in mononuclear copper(II) superoxide complexes.Spectroscopic and computational studies of an end-on bound superoxo-Cu(II) complex: geometric and electronic factors that determine the ground state.O2 and N2O activation by Bi-, Tri-, and tetranuclear Cu clusters in biology.Singlet-triplet gaps in large multireference systems: spin-flip-driven alternatives for bioinorganic modeling.Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex.Dioxygen Binding, Activation, and Reduction to H2O by Cu Enzymes.Investigation of the hydroxylation mechanism of noncoupled copper oxygenases by ab initio molecular dynamics simulations.Oxygen Activation by Cu LPMOs in Recalcitrant Carbohydrate Polysaccharide Conversion to Monomer Sugars.Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal-ligand interactions.Scorpionate chemistry at the 50th anniversary.Electronic tuning of β-diketiminate ligands with fluorinated substituents: effects on the O2-reactivity of mononuclear Cu(i) complexes
P2860
Q28658988-C44428E1-DB84-45A7-93CD-C597FFE36B32Q30363161-840F6C77-CB59-4EDD-A8E4-5DFF200D843EQ30490664-783237C7-07B1-44ED-99E3-6497746B2E96Q30850520-F3D22B38-64EE-46C8-AC7B-8BB5779E9EDBQ33936596-CF3B8CDA-8D4F-47E9-B879-E612DE84C69BQ34711388-4C33A0BD-8F59-4CD9-88F8-1732907BE2FCQ35868665-0753E2A2-D9A1-43FB-AF74-5D0DB2390DE0Q36012380-9AFCBB73-AD89-4749-821B-45A614FF9906Q36253692-160E83A2-92FE-4C1A-AE33-82F28A904527Q36673416-E454CF98-AD5D-42DD-AF6C-5DE8855738AAQ36916645-AE5FA3FD-C0F2-40DA-AE8C-1374837D1839Q36934070-A74D5E47-E2AC-4F2E-8F3A-6BB020E4AA9BQ36995957-3DDFB91A-EE44-4375-9664-F666496DFBCEQ36995982-B234A5D5-5088-48A8-A25C-E25EE25618E0Q37334684-4B72AE74-2BE0-4E3C-B8DC-B5404C298410Q37417089-0801C340-DFCA-441D-BF3C-FF4F0E0FF060Q37419166-ED5B2C8F-EB3A-4D56-BD1D-76767602ED9CQ37478705-27CB2028-6DFB-409A-A4C7-465DFFECC32CQ37513164-39BB5632-4E90-482C-95FD-092D5B151D76Q37664124-936BD7D6-C193-41D7-BA17-50348F1A7119Q37727953-753B21FA-FDFD-42CA-9E3A-51F087EE4294Q39093128-8531141A-6F28-483C-97FD-D890EE925D83Q39116769-9D0B1A22-DD4D-4486-A6EA-257228632685Q40837027-564F36B3-0925-4B01-A230-0C76FEA6DAD2Q41570933-A4B11B66-1F56-4854-8F8A-D65FB04E4FB8Q41644846-F8F309F6-7CA1-4CE0-83CF-69FAEC0A4895Q41846588-7B241414-6C8C-467E-BCB4-3FAD9EBB3BB2Q41853600-061236D6-F803-45D2-A45A-E2B27734004DQ41973096-69638FD3-8A77-4873-B45D-1886D896E1B3Q42138043-D80873D8-D081-4C6E-A0B1-2FB14B01EC27Q42610028-73078F8E-E665-40C3-B0C7-23F5FE20F3A5Q42738967-6AB2AA7F-45E9-443C-8A0B-281F84975C14Q44915600-773F90DD-CC13-4C98-BA3A-0B773B26DA1BQ45527739-6F6BAEC6-C7BF-46B5-BACD-FFF41303D247Q46245164-FAF79691-C35E-4FD1-9416-ED2F48210A0BQ49274156-4D25EF3E-7CB1-4AC4-A103-80E9DC551EEAQ54537718-0DF54CE2-523E-4ADC-AF14-615CFBC0E949Q57250555-F40D6D3D-F8B3-4059-8B53-347A0369F0A5
P2860
Spectroscopic and electronic structure studies of the diamagnetic side-on CuII-superoxo complex Cu(O2)[HB(3-R-5-iPrpz)3]: antiferromagnetic coupling versus covalent delocalization.
description
2003 nî lūn-bûn
@nan
2003年の論文
@ja
2003年学术文章
@wuu
2003年学术文章
@zh-cn
2003年学术文章
@zh-hans
2003年学术文章
@zh-my
2003年学术文章
@zh-sg
2003年學術文章
@yue
2003年學術文章
@zh
2003年學術文章
@zh-hant
name
Spectroscopic and electronic s ...... de-on CuII-superoxo complex Cu
@nl
Spectroscopic and electronic s ...... ersus covalent delocalization.
@en
type
label
Spectroscopic and electronic s ...... de-on CuII-superoxo complex Cu
@nl
Spectroscopic and electronic s ...... ersus covalent delocalization.
@en
prefLabel
Spectroscopic and electronic s ...... de-on CuII-superoxo complex Cu
@nl
Spectroscopic and electronic s ...... ersus covalent delocalization.
@en
P2093
P356
P1476
Spectroscopic and electronic s ...... ersus covalent delocalization.
@en
P2093
Cecelia Campochiaro
David E Root
Kiyoshi Fujisawa
P304
P356
10.1021/JA020969I
P407
P577
2003-01-01T00:00:00Z