Oxygen activation by nonheme iron(II) complexes: alpha-keto carboxylate versus carboxylate.
about
Molecular characterization and functional expression of flavonol 6-hydroxylaseMechanistic studies on three 2-oxoglutarate-dependent oxygenases of flavonoid biosynthesis: anthocyanidin synthase, flavonol synthase, and flavanone 3beta-hydroxylaseIntramolecular C-H and C-F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron ComplexesA family of four-coordinate iron(II) complexes bearing the sterically hindered tris(pyrazolyl)borato ligand Tp(tBu,Me).Oxygen activation at mononuclear nonheme iron centers: a superoxo perspectiveIntermediates in the oxygenation of a nonheme diiron(II) complex, including the first evidence for a bound superoxo speciesChiral hydroxylation at the mononuclear nonheme Fe(II) center of 4-(S) hydroxymandelate synthase--a structure-activity relationship analysis.Direct spectroscopic detection of a C-H-cleaving high-spin Fe(IV) complex in a prolyl-4-hydroxylase.Substrate-triggered activation of a synthetic [Fe2(μ-O)2] diamond core for C-H bond cleavage.A synthetic model of the putative Fe(II)-iminobenzosemiquinonate intermediate in the catalytic cycle of o-aminophenol dioxygenasesToward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes.Copper(I)-alpha-ketocarboxylate complexes: characterization and O2 reactions that yield copper-oxygen intermediates capable of hydroxylating arenesShape-selective interception by hydrocarbons of the O2-derived oxidant of a biomimetic nonheme iron complex.Structural, spectroscopic, and electrochemical properties of nonheme Fe(II)-hydroquinonate complexes: synthetic models of hydroquinone dioxygenases.Fe(II) complexes that mimic the active site structure of acetylacetone dioxygenase: O2 and NO reactivityElectronic structure analysis of the oxygen-activation mechanism by Fe(II)- and α-ketoglutarate (αKG)-dependent dioxygenases.A personal perspective on the discovery of dioxygen adducts of copper and iron by Nobumasa Kitajima.Aromatic C-F Hydroxylation by Nonheme Iron(IV)-Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations.Copper/alpha-ketocarboxylate chemistry with supporting peralkylated diamines: reactivity of copper(I) complexes and dicopper-oxygen intermediates.Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective.Secondary coordination sphere influence on the reactivity of nonheme iron(II) complexes: an experimental and DFT approach.An Iron(II)(1,3-bis(2'-pyridylimino)isoindoline) Complex as a Catalyst for Substrate Oxidation with H2O2. Evidence for a Transient Peroxodiiron(III) Species.Direct observation of a nonheme iron(IV)-oxo complex that mediates aromatic C-F hydroxylation.Selectivity of C-H versus C-F Bond Oxygenation by Homo- and Heterometallic Fe4 , Fe3 Mn, and Mn4 Clusters.The second coordination sphere of FIH controls hydroxylation.Synthesis and characterization of iron(II) quinaldate complexes.Synthesis, X-ray Structures, Electronic Properties, and O2/NO Reactivities of Thiol Dioxygenase Active-Site Models.Functional models of α-keto acid dependent nonheme iron oxygenases: synthesis and reactivity of biomimetic iron(II) benzoylformate complexes supported by a 2,9-dimethyl-1,10-phenanthroline ligand.Incorporation of oxygen into the succinate co-product of iron(II) and 2-oxoglutarate dependent oxygenases from bacteria, plants and humans.Synthesis and characterization of coordinatively unsaturated nickel(II) and manganese(II) alkyl complexes supported by the hydrotris(3-phenyl-5-methylpyrazolyl)borate (Tp(Ph,Me)) ligand.Mechanistic insights into dioxygen activation, oxygen atom exchange and substrate epoxidation by AsqJ dioxygenase from quantum mechanical/molecular mechanical calculations.Spectroscopic and computational studies of reversible O2 binding by a cobalt complex of relevance to cysteine dioxygenase.New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(III) complexes with dinucleating ligands.A structural and functional model for the 1-aminocyclopropane-1-carboxylic acid oxidase.Olefin cis-Dihydroxylation and Aliphatic C-H Bond Oxygenation by a Dioxygen-Derived Electrophilic Iron-Oxygen Oxidant.CopperII-mediated aromatic ortho-hydroxylation: a hybrid DFT and AB initio exploration.Nucleophilic reactivity of a copper(II)-superoxide complex.Mimicking the Aromatic-Ring-Cleavage Activity of Gentisate-1,2-Dioxygenase by a Nonheme Iron Complex.A trispyrazolylborato iron cysteinato complex as a functional model for the cysteine dioxygenase.Oxidative carbon-carbon bond cleavage of a α-hydroxy ketone by a functional model of 2,4'-dihydroxyacetophenone dioxygenase.
P2860
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P2860
Oxygen activation by nonheme iron(II) complexes: alpha-keto carboxylate versus carboxylate.
description
2003 nî lūn-bûn
@nan
2003年の論文
@ja
2003年学术文章
@wuu
2003年学术文章
@zh-cn
2003年学术文章
@zh-hans
2003年学术文章
@zh-my
2003年学术文章
@zh-sg
2003年學術文章
@yue
2003年學術文章
@zh
2003年學術文章
@zh-hant
name
Oxygen activation by nonheme iron
@nl
Oxygen activation by nonheme i ...... arboxylate versus carboxylate.
@en
type
label
Oxygen activation by nonheme iron
@nl
Oxygen activation by nonheme i ...... arboxylate versus carboxylate.
@en
prefLabel
Oxygen activation by nonheme iron
@nl
Oxygen activation by nonheme i ...... arboxylate versus carboxylate.
@en
P2093
P356
P1476
Oxygen activation by nonheme i ...... carboxylate versus carboxylate
@en
P2093
Eric L Hegg
Lawrence Que
Mark P Mehn
P304
P356
10.1021/JA028867F
P407
P577
2003-07-01T00:00:00Z