A structurally rigid bis(amido) ligand framework in low-coordinate Ni(I), Ni(II), and Ni(III) analogues provides access to a Ni(III) methyl complex via oxidative addition.
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Recent advances in homogeneous nickel catalysisA bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation statesCarbon-carbon cross-coupling reactions catalyzed by a two-coordinate nickel(II)-bis(amido) complex via observable Ni(I) , Ni(II) , and Ni(III) intermediatesUseful Method for the Preparation of Low-Coordinate Nickel(I) Complexes via Transformations of the Ni(I) Bis(amido) Complex K{Ni[N(SiMe3)(2,6- (i) Pr2-C6H3)]2}Methyl Complexes of the Transition Metals.Heteroleptic, two-coordinate [M(NHC){N(SiMe3)2}] (M = Co, Fe) complexes: synthesis, reactivity and magnetism rationalized by an unexpected metal oxidation state.Complexes of Ni(i): a "rare" oxidation state of growing importance.Structural Diversity in Alkali Metal and Alkali Metal Magnesiate Chemistry of the Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilino Ligand.Homoleptic Two-Coordinate Silylamido Complexes of Chromium(I), Manganese(I), and Cobalt(I).Salts of the two-coordinate homoleptic manganese(I) dialkyl anion [Mn{C(SiMe3)3}2](-) with quenched orbital magnetism.Mono- and dinuclear Ni(i) products formed upon bromide abstraction from the Ni(i) ring-expanded NHC complex [Ni(6-Mes)(PPh3)Br].Dispersion-Force-Assisted Disproportionation: A Stable Two-Coordinate Copper(II) Complex.Accessing perfluoroalkyl nickel(II), (III), and (IV) complexes bearing a readily attached [C4F8] ligand.Nickel(I) monomers and dimers with cyclopentadienyl and indenyl ligands.A Ni(iii) complex stabilized by silica nanoparticles as an efficient nanoheterogeneous catalyst for oxidative C-H fluoroalkylation.Nickel-Alkyl Complexes with a Reactive PNC-Pincer Ligand.
P2860
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P2860
A structurally rigid bis(amido) ligand framework in low-coordinate Ni(I), Ni(II), and Ni(III) analogues provides access to a Ni(III) methyl complex via oxidative addition.
description
2013 nî lūn-bûn
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name
A structurally rigid bis(amido ...... omplex via oxidative addition.
@en
A structurally rigid bis(amido ...... omplex via oxidative addition.
@nl
type
label
A structurally rigid bis(amido ...... omplex via oxidative addition.
@en
A structurally rigid bis(amido ...... omplex via oxidative addition.
@nl
prefLabel
A structurally rigid bis(amido ...... omplex via oxidative addition.
@en
A structurally rigid bis(amido ...... omplex via oxidative addition.
@nl
P2093
P356
P1476
A structurally rigid bis(amido ...... omplex via oxidative addition.
@en
P2093
Michael I Lipschutz
Ruchira Chatterjee
T Don Tilley
P304
15298-15301
P356
10.1021/JA408151H
P407
P577
2013-10-03T00:00:00Z