Molybdenum triamidoamine complexes that contain hexa-tert-butylterphenyl, hexamethylterphenyl, or p-bromohexaisopropylterphenyl substituents. An examination of some catalyst variations for the catalytic reduction of dinitrogen.
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Catalytic reduction of dinitrogen to ammonia at a single molybdenum centerA Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench (57)Fe Mössbauer Data, and a Hydride Resting StateSynthesis of [(DPPNCH2CH2)3N]3- molybdenum complexes (DPP = 3,5-(2,5-Diisopropylpyrrolyl)2C6H3) and studies relevant to catalytic reduction of dinitrogen.Synthesis of diamidopyrrolyl molybdenum complexes relevant to reduction of dinitrogen to ammonia.Catalytic reduction of dinitrogen to ammonia at a single molybdenum center.Synthesis of molybdenum complexes that contain "hybrid" triamidoamine ligands, [(hexaisopropylterphenyl-NCH2CH2)2NCH2CH2N-aryl]3-, and studies relevant to catalytic reduction of dinitrogen.Alkylation of dinitrogen in [(HIPTNCH(2)CH(2))(3)N]Mo complexes (HIPT = 3,5-(2,4,6-i-Pr(3)C(6)H(2))(2)C(6)H(3)).Molybdenum triamidoamine systems. Reactions involving dihydrogen relevant to catalytic reduction of dinitrogen.Coordination chemistry insights into the role of alkali metal promoters in dinitrogen reduction.Catalytic NH3 synthesis using N2/H2 at molecular transition metal complexes - concepts for lead structure determination using computational chemistry.N-H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe-N2 and Fe-CN Reductions.Formation of {[HIPTN(3)N]Mo(III)H}(-) by heterolytic cleavage of H(2) as established by EPR and ENDOR spectroscopy.Experimental and theoretical EPR study of Jahn-Teller-active [HIPTN(3)N]MoL complexes (L = N(2), CO, NH(3)).Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation.N2 -to-NH3 Conversion by a triphos-Iron Catalyst and Enhanced Turnover under Photolysis.Design and preparation of molybdenum-dinitrogen complexes with ferrocenyldiphosphine and pentamethylcyclopentadienyl moieties as auxiliary ligands.Cobalt-catalyzed transformation of molecular dinitrogen into silylamine under ambient reaction conditions.Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum-dinitrogen complexes: unique behavior of ferrocene moiety as redox active site.Synthesis and reactivity of iron-dinitrogen complexes bearing anionic methyl- and phenyl-substituted pyrrole-based PNP-type pincer ligands toward catalytic nitrogen fixation.Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands.Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes.Heterolytic outer-sphere cleavage of H2 for the reduction of N2 in the coordination sphere of transition metals--a DFT study.Synthesis of 2,6-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu3C6H2)2C6H3X, where X = I, Li, OH, SH, N3, or NH2.Synthesis and Reactivity of Iron- and Cobalt-Dinitrogen Complexes Bearing PSiP-Type Pincer Ligands toward Nitrogen FixationSynthesis and Reactivity of Molybdenum-Dinitrogen Complexes Bearing PNN-Type Pincer LigandMolybdenum-catalyzed reduction of molecular dinitrogen under mild reaction conditionsGradient-driven molecule construction: An inverse approach applied to the design of small-molecule fixating catalysts
P2860
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P2860
Molybdenum triamidoamine complexes that contain hexa-tert-butylterphenyl, hexamethylterphenyl, or p-bromohexaisopropylterphenyl substituents. An examination of some catalyst variations for the catalytic reduction of dinitrogen.
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年学术文章
@wuu
2004年学术文章
@zh-cn
2004年学术文章
@zh-hans
2004年学术文章
@zh-my
2004年学术文章
@zh-sg
2004年學術文章
@yue
2004年學術文章
@zh
2004年學術文章
@zh-hant
name
Molybdenum triamidoamine compl ...... lytic reduction of dinitrogen.
@en
Molybdenum triamidoamine compl ...... lytic reduction of dinitrogen.
@nl
type
label
Molybdenum triamidoamine compl ...... lytic reduction of dinitrogen.
@en
Molybdenum triamidoamine compl ...... lytic reduction of dinitrogen.
@nl
prefLabel
Molybdenum triamidoamine compl ...... lytic reduction of dinitrogen.
@en
Molybdenum triamidoamine compl ...... lytic reduction of dinitrogen.
@nl
P2093
P50
P356
P1476
Molybdenum triamidoamine compl ...... alytic reduction of dinitrogen
@en
P2093
Dmitry V Yandulov
Richard R Schrock
William M Davis
P304
P356
10.1021/JA0306415
P407
P577
2004-05-01T00:00:00Z