about
Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic propertiesUmpolung of Michael acceptors catalyzed by N-heterocyclic carbenesChemical behaviour of a prototype boryl(phosphino)carbene.Diaminocarbene- and Fischer-carbene complexes of palladium and nickel by oxidative insertion: preparation, structure, and catalytic activity.Combinatorial synthesis of functionalized chiral and doubly chiral ionic liquids and their applications as asymmetric covalent/non-covalent bifunctional organocatalysts.The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Catalytic Kinetic Resolution of a Dynamic Racemate: Highly Stereoselective β-Lactone Formation by N-Heterocyclic Carbene CatalysisThe Catalytic Asymmetric Intramolecular Stetter Reaction.N-heterocyclic carbene-initiated alpha-acylvinyl anion reactivity: additions of alpha-hydroxypropargylsilanes to aldehydesSynthesis and Structure of Fused N-Heterocylic Carbenes and Their Rhodium Complexes.Intermolecular Cross-Acyloin Reactions by Fluoride-Promoted Additions of O-Silyl Thiazolium Carbinols.Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference.Scope of the asymmetric intramolecular stetter reaction catalyzed by chiral nucleophilic triazolinylidene carbenes.Catalytic asymmetric intermolecular stetter reaction of heterocyclic aldehydes with nitroalkenes: backbone fluorination improves selectivity.Carbon-carbon bond activation of cyclobutenones enabled by the addition of chiral organocatalyst to ketoneQuantum mechanical investigation of the effect of catalyst fluorination in the intermolecular asymmetric Stetter reaction.Design and synthesis of C2-symmetric N-heterocyclic carbene precursors and metal carbenoidsα,β-Unsaturated acyl azoliums from N-heterocyclic carbene catalyzed reactions: observation and mechanistic investigation.Structurally Characterized Cationic Silver(I) and Ruthenium(II)carbene complexes of 1,2,3-Triazol-5-ylidenesMetallophosphite-induced nucleophilic acylation of alpha,beta-unsaturated amides: facilitated catalysis by a diastereoselective retro [1,4] Brook rearrangement.Metallophosphite-catalyzed asymmetric acylation of alpha,beta-unsaturated amides.Reversed-Polarity Synthesis of Diaryl Ketones through Palladium-Catalyzed Direct Arylation of 2-Aryl-1,3-dithianes.Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst.Cooperative Lewis acid/N-heterocyclic carbene catalysisStereocontrolled synthesis of α-amino-α'-alkoxy ketones by a copper-catalyzed cross-coupling of peptidic thiol esters and α-alkoxyalkylstannanes.An efficient synthesis of achiral and chiral 1,2,4-triazolium salts: bench stable precursors for N-heterocyclic carbenes.One-carbon extrusion from a tetraazafulvalene. Isolation of aldehydes and a study of their origin.Asymmetric synthesis of hydrobenzofuranones via desymmetrization of cyclohexadienones using the intramolecular Stetter reactionEnantioselective Synthesis of Hydrobenzofuranones Using an Asymmetric Desymmetrizing Intramolecular Stetter Reaction of Cyclohexadienones.Carbene catalystsRecent advances in the chemistry and biology of naturally occurring antibiotics.N-Heterocyclic carbene-catalyzed oxidative [3 + 2] annulation of dioxindoles and enals: cross coupling of homoenolate and enolate.Platensimycin and its relatives: a recent story in the struggle to develop new naturally derived antibiotics.Fluorine conformational effects in organocatalysis: an emerging strategy for molecular design.N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media.A continuum of progress: applications of N-hetereocyclic carbene catalysis in total synthesis.N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis.Chitosan as a sustainable organocatalyst: a concise overview.Acetaldehyde: A Small Organic Molecule with Big Impact on Organocatalytic Reactions.Synthesis of phosphaformamidines and phosphaformamidinates.
P2860
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P2860
description
2004 nî lūn-bûn
@nan
2004年の論文
@ja
2004年学术文章
@wuu
2004年学术文章
@zh-cn
2004年学术文章
@zh-hans
2004年学术文章
@zh-my
2004年学术文章
@zh-sg
2004年學術文章
@yue
2004年學術文章
@zh
2004年學術文章
@zh-hant
name
Nucleophilic carbenes in asymmetric organocatalysis.
@en
Nucleophilic carbenes in asymmetric organocatalysis.
@nl
type
label
Nucleophilic carbenes in asymmetric organocatalysis.
@en
Nucleophilic carbenes in asymmetric organocatalysis.
@nl
prefLabel
Nucleophilic carbenes in asymmetric organocatalysis.
@en
Nucleophilic carbenes in asymmetric organocatalysis.
@nl
P356
P1476
Nucleophilic carbenes in asymmetric organocatalysis.
@en
P2093
Dieter Enders
Tim Balensiefer
P304
P356
10.1021/AR030050J
P577
2004-08-01T00:00:00Z