Dative bonds in main-group compounds: a case for fewer arrows!
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A simple complex on the verge of breakdown: isolation of the elusive cyanoformate ionA comparative study of the coordination behavior of cyclo-P5 and cyclo-As5 ligand complexes towards the trinuclear Lewis acid complex (perfluoro-ortho-phenylene)mercuryDonor-acceptor chemistry in the main group.Interpnictogen cations: exploring new vistas in coordination chemistry.Reactive p-block cations stabilized by weakly coordinating anions.Group 14 inorganic hydrocarbon analogues.Design, Synthesis, and Structural Analysis of Divalent N(I) Compounds and Identification of a New Electron-Donating Ligand.Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties.Ambiphilic boron in 1,4,2,5-diazadiborinine.Preparation and characterization of chemically bonded argon-boroxol ring cation complexes.Bond fission in monocationic frameworks: diverse fragmentation pathways for phosphinophosphonium cations.The Bonding Situation in Metalated Ylides.Carbones as Ligands in Novel Main-Group Compounds E[C(NHC)2 ]2 (E=Be, B+ , C2+ , N3+ , Mg, Al+ , Si2+ , P3+ ): A Theoretical Study.Dimerization of a marginally stable disilenyl germylene to tricyclic systems: evidence for reversible NHC-coordination.Serendipitous Observation of Al(I) Insertion into a CO Bond in L2 PhB: (L=oxazol-2-ylidene).Multiple complexation of CO and related ligands to a main-group element.Structural, spectroscopic and computational examination of the dative interaction in constrained phosphine-stibines and phosphine-stiboranes.The fate of NHC-stabilized dicarbon.Isolation of an imino-N-heterocyclic carbene/germanium(0) adduct: a mesoionic germylene equivalent.Diverse reactivity of a tricoordinate organoboron L2PhB: (L = oxazol-2-ylidene) towards alkali metal, group 9 metal, and coinage metal precursors.Theoretical Evidence for the Utilization of Low-Valent Main-Group Complexes as Rare-Synthon Equivalents.A Disilene Base Adduct with a Dative Si-Si Single Bond.Using the Lewis Acid Me3 Si-F-Al(ORF )3 To Prepare Phosphino-Phosphonium Cations with the Least-Coordinating Anion [(RF O)3 Al-F-Al(ORF )3 ].Nature of Bonding in Donor-Acceptor Interactions Exemplified by Complexes of N-Heterocyclic Carbenes with 1,2,5-Telluradiazoles.A comparative study of the structure and bonding in heavier pnictinidene complexes [(ArE)M(CO)n] (E = As, Sb and Bi; M = Cr, Mo, W and Fe).Curly arrows, electron flow, and reaction mechanisms from the perspective of the bonding evolution theory.Bonding analysis of telluroketones H₂A = Te (A = C, Si, Ge).Expanding the Ligand Framework Diversity of Carbodicarbenes and Direct Detection of Boron Activation in the Methylation of Amines with CO2.Synthesis and structural characterization of a C₄ cumulene including 4-pyridylidene units, and its reactivity towards ammonia-borane.NHC-Stabilised Acetylene-How Far Can the Analogy Be Pushed?Formation and characterization of the boron dicarbonyl complex [B(CO)2](-).Unprecedented solvent induced inter-conversion between monomeric and dimeric silylene-zinc iodide adducts.Assembly of NHC-stabilized 2-hydrophosphasilenes from Si(iv) precursors: a Lewis acid-base complex.Stabilization of heterodiatomic SiC through ligand donation: theoretical investigation of SiC(L)2 (L=NHC(Me) , CAAC(Me) , PMe3 ).Anorganische Chemie 2013Charge Density and Chemical BondingPeculiar boron startles again
P2860
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P2860
Dative bonds in main-group compounds: a case for fewer arrows!
description
2013 nî lūn-bûn
@nan
2013年の論文
@ja
2013年学术文章
@wuu
2013年学术文章
@zh
2013年学术文章
@zh-cn
2013年学术文章
@zh-hans
2013年学术文章
@zh-my
2013年学术文章
@zh-sg
2013年學術文章
@yue
2013年學術文章
@zh-hant
name
Dative bonds in main-group compounds: a case for fewer arrows!
@en
Dative bonds in main-group compounds: a case for fewer arrows!
@nl
type
label
Dative bonds in main-group compounds: a case for fewer arrows!
@en
Dative bonds in main-group compounds: a case for fewer arrows!
@nl
prefLabel
Dative bonds in main-group compounds: a case for fewer arrows!
@en
Dative bonds in main-group compounds: a case for fewer arrows!
@nl
P2860
P356
P1476
Dative bonds in main-group compounds: a case for fewer arrows!
@en
P2093
Andreas Schnepf
Daniel Himmel
P2860
P304
P356
10.1002/ANIE.201300461
P407
P577
2013-11-15T00:00:00Z