Silylene transfer to carbonyl compounds and subsequent Ireland-Claisen rearrangements to control formation of quaternary carbon stereocenters.
about
Synthesis of gamma,delta-unsaturated glycolic acids via sequenced brook and Ireland--claisen rearrangements.Silylene transfer to alpha-keto esters and application to the synthesis of gamma-lactonesSilylene-mediated polarity reversal of dienoates: additions of dienoates to aldehydes at the δ-position to form trans-dioxasilacyclononenesSynthesis of silyloxy dienes by silylene transfer to divinyl ketones: application to the asymmetric synthesis of substituted cyclohexanes.Intermolecular silacarbonyl ylide cycloadditions: a direct pathway to oxasilacyclopentenes.Synthesis of azasilacyclopentenes and silanols via Huisgen cycloaddition-initiated C-H bond insertion cascades.Reactivity of an NHC-stabilized silylene towards ketones. Formation of silicon bis-enolates vs. bis-silylation of the C[double bond, length as m-dash]O bond.Convenient Access to Monosilicon Epoxides with Pentacoordinate SiliconConvenient Access to Monosilicon Epoxides with Pentacoordinate Silicon
P2860
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P2860
Silylene transfer to carbonyl compounds and subsequent Ireland-Claisen rearrangements to control formation of quaternary carbon stereocenters.
description
2005 nî lūn-bûn
@nan
2005年の論文
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2005年学术文章
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2005年学术文章
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2005年学术文章
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2005年学术文章
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name
Silylene transfer to carbonyl ...... aternary carbon stereocenters.
@en
Silylene transfer to carbonyl ...... aternary carbon stereocenters.
@nl
type
label
Silylene transfer to carbonyl ...... aternary carbon stereocenters.
@en
Silylene transfer to carbonyl ...... aternary carbon stereocenters.
@nl
prefLabel
Silylene transfer to carbonyl ...... aternary carbon stereocenters.
@en
Silylene transfer to carbonyl ...... aternary carbon stereocenters.
@nl
P356
P1476
Silylene transfer to carbonyl ...... aternary carbon stereocenters.
@en
P2093
K A Woerpel
Stacie A Calad
P304
P356
10.1021/JA042893R
P407
P577
2005-02-01T00:00:00Z