about
Synthesis, Characterization, and Reactivity of Functionalized Trinuclear Iron-Sulfur Clusters - A New Class of Bioinspired Hydrogenase ModelsSynthesis of new asymmetric substituted boron amidines - reactions with CO and transfer hydrogenations of phenylacetylene.Stable GaX2, InX2 and TlX2 radicals.Direct estimate of the internal π-donation to the carbene centre within N-heterocyclic carbenes and related moleculesDirectly Predicting Water Quality Criteria from Physicochemical Properties of Transition Metals.Thermally controlling the singlet-triplet energy gap of a diradical in the solid state.New perspectives for "non-classical" molecules: heavy [1.1.1]propellanes of group 14.Donor-acceptor chemistry in the main group.Group 14 inorganic hydrocarbon analogues.Cations and dications of heavier group 14 elements in low oxidation states.Advances in Phosphasilene Chemistry.Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations.Experimental Observation of the Nature of Weak Chemical Bonds in Labile Compounds.Reactivity and catalytic activity of tert-butoxy-aluminium hydride reagents.Borylenes: An Emerging Class of Compounds.Designing effective 'frustrated Lewis pair' hydrogenation catalysts.Unique molecular geometries of reduced 4- and 5-coordinate zinc complexes stabilised by diiminopyridine ligand.Reaction of a diaryldigermyne with ethyleneBoron-mediated sequential alkyne insertion and C-C coupling reactions affording extended π-conjugated molecules.Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3-Induced C-H Functionalizations.1,3,2,5-Diazadiborinine featuring nucleophilic and electrophilic boron centres.Lewis Acidic Ionic LiquidsDiaryldichalcogenide radical cations.On the Ambiphilic Reactivity of Geometrically Constrained Phosphorus(III) and Arsenic(III) Compounds: Insights into Their Interaction with Ionic Substrates.Stable singlet carbenes as mimics for transition metal centers.Multi-electron reactivity of a cofacial di-tin(ii) cryptand: partial reduction of sulfur and selenium and reversible generation of S3˙.A Brief Survey of our Contribution to Stable Carbene Chemistry.Ambiphilic boron in 1,4,2,5-diazadiborinine.Metal-ligand multiple bonds as frustrated Lewis pairs for C-H functionalization.Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes(Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles.Cesium's Off-the-Map Valence Orbital.Cleavage of the Sn-Sn multiple bond in a distannyne by cyclooctatetraene: formation of the pi-bound inverse sandwich complex [(Ar'Sn)2(mu2-eta2:eta3-cot)].E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound.The role of 2,6-diaminopyridine ligands in the isolation of an unprecedented, low-valent tin complex.Activation of gaseous PH3 with low coordinate diaryltetrylene compounds.Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene.C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions.Stereoselective synthesis, structural aspects, and NMR properties of stable C-fluorinated phosphaalkenes.Replacing tin in lactide polymerization: design of highly active germanium-based catalysts.
P2860
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P2860
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh
2010年學術文章
@zh-hant
name
Main-group elements as transition metals.
@en
Main-group elements as transition metals.
@nl
type
label
Main-group elements as transition metals.
@en
Main-group elements as transition metals.
@nl
prefLabel
Main-group elements as transition metals.
@en
Main-group elements as transition metals.
@nl
P2860
P356
P1433
P1476
Main-group elements as transition metals.
@en
P2093
Philip P Power
P2860
P2888
P304
P356
10.1038/NATURE08634
P407
P577
2010-01-01T00:00:00Z
P6179
1023439466