Lutidine/B(C6F5)3: at the boundary of classical and frustrated Lewis pair reactivity.
about
N-Methyl-Benzothiazolium Salts as Carbon Lewis Acids for Si-H σ-Bond Activation and Catalytic (De)hydrosilylationChloro- and phenoxy-phosphines in frustrated Lewis pair additions to alkynes.Superelectrophilic intermediates in nitrogen-directed aromatic borylation.Frustrated Lewis pair chemistry: development and perspectives.Transition Metal-Free Cleavage of CO.On the concept of frustrated Lewis pairs.Boron-Catalyzed N-Alkylation of Amines using Carboxylic Acids.A computational and conceptual DFT study on the mechanism of hydrogen activation by novel frustrated Lewis pairs.Hydrogen activation using a novel tribenzyltin Lewis acid.A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes.Enantioselective hydrogenation with chiral frustrated Lewis pairs.Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures.Borohydrides from organic hydrides: reactions of Hantzsch's esters with B(C(6)F(5))(3).Dispersion-oriented soft interaction in a frustrated Lewis pair and the entropic encouragement effect in its formation.Frustrated Lewis pairs as molecular receptors: colorimetric and electrochemical detection of nitrous oxide.Phosphinimine-borane combinations in frustrated Lewis pair chemistry.Metal-free pincer ligand chemistry polycationic phosphonium Lewis acids.Intramolecular Lewis pairs with two acid sites - reactivity differences between P- and N-based systems.Reaction of an "invisible" frustrated N/B Lewis pair with dihydrogen.Activation of isocyanates and carbon dioxide by a monomeric aluminium hydrazide as an active Lewis pair.Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.Catalytic hydrogenation with frustrated Lewis pairs: selectivity achieved by size-exclusion design of Lewis acids.B(C6F5)3-Promoted hydrogenations of N-heterocycles with ammonia borane.Understanding the Role of Dispersion in Frustrated Lewis Pairs and Classical Lewis Adducts: A Domain-Based Local Pair Natural Orbital Coupled Cluster Study.B(C6 F5 )3 -Catalyzed Ring Opening and Isomerization of Unactivated Cyclopropanes.Graphene from Alginate Pyrolysis as a Metal-Free Catalyst for Hydrogenation of Nitro Compounds.A Frustrated and Confused Lewis Pair.Atom-Efficient Synthesis of Alkynylfluoroborates Using BF3 -Based Frustrated Lewis Pairs.Frustrated Lewis pairs incorporating the bifunctional Lewis acid 1,1'-fc{B(C6F5)2}2: reactivity towards small molecules.Testing the nature of reaction coordinate describing interaction of H2 with carbonyl carbon, activated by Lewis acid complexation, and the Lewis basic solvent: A Born-Oppenheimer molecular dynamics study with explicit solvent.A computational experiment to study hydrogenations of various unsaturated compounds catalyzed by a rationally designed metal-free catalyst.Organometallic frustrated Lewis pair chemistry.Heterolytic Si-H Bond Cleavage at a Molybdenum-Oxido-Based Lewis Pair.Quantification of Lewis acid induced Brønsted acidity of protogenic Lewis bases.Carbonyl Activation by Borane Lewis Acid Complexation: Transition States of H2 Splitting at the Activated Carbonyl Carbon Atom in a Lewis Basic Solvent and the Proton-Transfer Dynamics of the Boroalkoxide Intermediate.Ring-opening of cyclic ethers by aluminum hydridotriphenylborate.Bypassing a highly unstable frustrated Lewis pair: dihydrogen cleavage by a thermally robust silylium-phosphine adduct.Aluminium Diphosphamethanides: Hidden Frustrated Lewis Pairs.Reactivity of a frustrated lewis pair and small-molecule activation by an isolable Arduengo carbene-B{3,5-(CF3)2C6H3}3 complex.Mechanistic insights into the full hydrogenation of 2,6-substituted pyridine catalyzed by the Lewis acid C6F5(CH2)2B(C6F5)2.
P2860
Q31138954-0114A560-9850-484D-9BC8-09028A6DC350Q34014576-79BBBE40-02C8-450F-B676-C87483726CD6Q37390486-FB5903A9-8EBE-40AD-942D-54C1AD9A0C99Q38479992-CECA7483-D7F0-4EF8-BAA4-424E4B022AFAQ38620616-36108AE2-03F2-40DD-8C03-77558AB65ED2Q39455502-64ACB7BD-B035-45C4-A43C-670E6288E135Q40294296-7737FC29-61DA-4220-AAC3-0C974474CE95Q41155344-BF778E84-C7B9-42CA-8D13-0113C78FBCA8Q41220256-C5884ACC-113D-4BF0-8F1B-2EBC8DC89A9CQ41905794-36FA52A4-AFB8-49E2-ABD0-7EEFA07E29E8Q42843925-D7CBD1CB-2925-4A25-BDCD-239BDD137DFEQ42846341-CBE26A9C-231C-4F75-BB39-77D1B230EC20Q43121361-2AE5EF64-21B1-4DF2-8463-431F182276AEQ43240710-65E12FDD-3811-4562-BACB-2F25413A8B05Q43582963-38907ECF-ED4A-4BB7-8B09-83BFE1A668A8Q44285289-C2643270-D126-4112-8200-85132AEF09FAQ46408132-8C3C3F36-F3B6-42F1-B1C9-623E82DB921FQ46466857-04EDB075-AB11-4AC6-8853-D86F5C62AFCCQ46641714-5768CED8-7B5E-4D51-8A95-8C87DE394015Q46952178-6B6F6B43-24D6-4D22-8E63-B1ACD69E86CDQ47137424-637377F5-4967-4999-9941-7FC924A2F238Q47338562-1CAC8D78-A84E-45C6-81BD-B612359C7457Q47849496-1C94533C-1D30-43EA-8F7D-03E3BEA0D30FQ48053395-6CEBE5E8-D698-4438-8D89-3C08742D4115Q48156580-D65BA7AA-3083-4B40-B537-4E869DF01F40Q48217542-24AC5A72-052F-4860-A6F3-45792E54CB38Q48248440-86964984-8790-4DDF-98F2-697AA1130889Q48269436-36AD59AA-74B0-4E85-9770-F130181EB621Q50093172-7CAF7741-EA6C-4797-B590-DBD3A42C9C79Q50196519-B9AA0F37-9C9D-4A18-8E82-43A8A1681AC7Q50501496-FCC02BCF-F2A6-4D49-8114-0934BCCD5A5FQ51876723-01392832-42A7-4D7B-911E-50EA6834842FQ52361894-BCF55F5E-0509-47E3-8547-6AB4CFA14782Q52675914-86E65A53-3EE0-4A0F-80C0-0A54C45BDBFEQ52772731-C145D5A4-8726-4C08-A449-406F7EA70BF3Q52782883-DE83FA7C-E2F6-464F-8940-C8ECCA1F4216Q53021608-E545B373-1FE8-4F42-9DF7-60431729BC74Q53061757-8E42D9AD-8B43-4184-ABB3-25628D1BE928Q53134329-5461F813-CA66-44D5-AB8F-BABA1FA69730Q53254763-E85972FA-B16A-4B14-BF63-E87601D86829
P2860
Lutidine/B(C6F5)3: at the boundary of classical and frustrated Lewis pair reactivity.
description
2009 nî lūn-bûn
@nan
2009年の論文
@ja
2009年学术文章
@wuu
2009年学术文章
@zh
2009年学术文章
@zh-cn
2009年学术文章
@zh-hans
2009年学术文章
@zh-my
2009年学术文章
@zh-sg
2009年學術文章
@yue
2009年學術文章
@zh-hant
name
Lutidine/B
@nl
Lutidine/B(C6F5)3: at the boundary of classical and frustrated Lewis pair reactivity.
@en
type
label
Lutidine/B
@nl
Lutidine/B(C6F5)3: at the boundary of classical and frustrated Lewis pair reactivity.
@en
prefLabel
Lutidine/B
@nl
Lutidine/B(C6F5)3: at the boundary of classical and frustrated Lewis pair reactivity.
@en
P356
P1476
Lutidine/B(C6F5)3: at the boundary of classical and frustrated Lewis pair reactivity.
@en
P2093
Douglas W Stephan
Stephen J Geier
P304
P356
10.1021/JA900572X
P407
P577
2009-03-01T00:00:00Z