Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts.
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Mapping the Reaction Coordinates of Enzymatic DefluorinationCatalytic Promiscuity of Transaminases: Preparation of Enantioenriched β-Fluoroamines by Formal Tandem Hydrodefluorination/DeaminationH(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.High yield C-derivatization of weakly coordinating carborane anions.Triethylsilyl Perfluoro-Tetraphenylborate, [Et(3)Si][F(20)-BPh(4)], a widely used Non-Existent Compound.Comparative study on catalytic hydrodehalogenation of halogenated aromatic compounds over Pd/C and Raney Ni catalysts.How Many Conformations of Enzymes Should Be Sampled for DFT/MM Calculations? A Case Study of Fluoroacetate Dehalogenase.Electrophilic C-H Borylation and Related Reactions of B-H Boron CationsCations and dications of heavier group 14 elements in low oxidation states.Phosphorus Lewis acids: emerging reactivity and applications in catalysis.A Tale of Two Elements: The Lewis Acidity/Basicity Umpolung of Boron and Phosphorus.Synthesis of fluorinated building blocks by transition-metal-mediated hydrodefluorination reactions.Fluorocarbene, fluoroolefin, and fluorocarbyne complexes of Rh.Arylation of hydrocarbons enabled by organosilicon reagents and weakly coordinating anions.Hydrodefluorination of carbon-fluorine bonds by the synergistic action of a ruthenium-palladium catalyst.Perhalogenated carba-closo-dodecaborate anions as ligand substituents: applications in gold catalysis.Copper-mediated C-C cross-coupling reaction of monocarba-closo-dodecaborate anion for the synthesis of functional molecules.C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions.Selective C-F bond activation: substitution of unactivated alkyl fluorides using YbI₃.Catalytic hydrodefluorination of fluoromethanes at room temperature by silylium-ion-like surface species.Palladium-catalyzed ortho-selective C-F activation of polyfluoroarenes with triethylsilane: a facile access to partially fluorinated aromatics.Chemistry. Lewis acids with a difference.Isolation of a carborane-fused triazole radical anion.Fusing N-heterocyclic carbenes with carborane anions.Transition-Metal-Mediated Cleavage of Fluoro-Silanes under Mild Conditions.Synthesis of a silylium zwitterion.Anionic and zwitterionic carboranyl N-heterocyclic carbene Au(i) complexes.Mild and selective activation and substitution of strong aliphatic C-F bonds.Synthesis of unsymmetrical N-carboranyl NHCs: directing effect of the carborane anion.Difunctionalized {closo-1-CB11 } clusters: 1- and 2-amino-12-ethynylcarba-closo-dodecaborates.NHC-catalyzed [4+2] cycloaddition reactions for the synthesis of 3'-spirocyclic oxindoles via a C-F bond cleavage protocol.Use of Trifluoromethyl Groups for Catalytic Benzylation and Alkylation with Subsequent Hydrodefluorination.Oxoborane (RBO) Complexation and Concomitant Electrophilic Bond Activation Processes."Dumbbell"- and "Clackers"-Shaped Dimeric Derivatives of Monocarba-closo-dodecaborate.Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C-H and C-F Bond Activation.B-H functionalization of the monocarba-closo-dodecaborate anion by rhodium and iridium catalysis.Consecutive Transformations of Tetrafluoropropenes: Hydrogermylation and Catalytic C-F Activation Steps at a Lewis Acidic Aluminum Fluoride.Palladium-Catalyzed Carbon-Fluorine and Carbon-Hydrogen Bond Alumination of Fluoroarenes and Heteroarenes.Fusing Carborane Carboxylic Acids with Alkynes: 3D Analogues of Isocoumarins via Regioselective B-H Activation.Ligand versus Complex: C-F and C-H Bond Activation of Polyfluoroaromatics at a Cyclic (Alkyl)(Amino)Carbene.
P2860
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P2860
Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts.
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年学术文章
@wuu
2008年学术文章
@zh
2008年学术文章
@zh-cn
2008年学术文章
@zh-hans
2008年学术文章
@zh-my
2008年学术文章
@zh-sg
2008年學術文章
@yue
2008年學術文章
@zh-hant
name
Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts.
@en
Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts.
@nl
type
label
Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts.
@en
Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts.
@nl
prefLabel
Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts.
@en
Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts.
@nl
P2860
P356
P1433
P1476
Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts.
@en
P2093
Christos Douvris
Oleg V Ozerov
P2860
P304
P356
10.1126/SCIENCE.1159979
P407
P577
2008-08-01T00:00:00Z