Structure-reactivity relationship in alkane metathesis using well-defined silica-supported alkene metathesis catalyst precursors.

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Simple addition of silica to an alkane solution of a Wilkinson WMe6 or Schrock W alkylidyne complex gives an active complex for saturated and unsaturated hydrocarbon metathesis.

P2860

Q51782756-C7B37238-A0B7-4925-B1B2-8499078DEFE6

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Structure-reactivity relationship in alkane metathesis using well-defined silica-supported alkene metathesis catalyst precursors.

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http://www.wikidata.org/entity/Q46408263

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2008 nî lūn-bûn

@nan

2008年の論文

@ja

2008年学术文章

@wuu

2008年学术文章

@zh

2008年学术文章

@zh-cn

2008年学术文章

@zh-hans

2008年学术文章

@zh-my

2008年学术文章

@zh-sg

2008年學術文章

@yue

2008年學術文章

@zh-hant

name

Structure-reactivity relations ...... etathesis catalyst precursors.

@en

Structure-reactivity relations ...... etathesis catalyst precursors.

@nl

type

Item

label

Structure-reactivity relations ...... etathesis catalyst precursors.

@en

Structure-reactivity relations ...... etathesis catalyst precursors.

@nl

prefLabel

Structure-reactivity relations ...... etathesis catalyst precursors.

@en

Structure-reactivity relations ...... etathesis catalyst precursors.

@nl

P1476

Structure-reactivity relations ...... etathesis catalyst precursors.

@en

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Christophe Copéret

http://www.w3.org/2001/XMLSchema#string

Jean Thivolle-Cazat

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Understanding and exploiting C-H bond activation.

Design and understanding of heterogeneous alkene metathesis catalysts.

High resolution solid state NMR spectroscopy in surface organometallic chemistry: access to molecular understanding of active sites of well-defined heterogeneous catalysts.

Improved resolution in proton NMR spectroscopy of powdered solids.

Thermal activation of hydrocarbon C-H bonds by tungsten alkylidene complexes.

Hydrogenolysis of cycloalkanes on a tantalum hydride complex supported on silica and insight into the deactivation pathway by the combined use of 1D solid-state NMR and EXAFS spectroscopies.

Intermolecular activation of hydrocarbon C-H bonds under ambient conditions by 16-electron neopentylidene and benzyne complexes of molybdenum.

Detailed structural investigation of the grafting of [Ta(=CHtBu)(CH2tBu)3] and [Cp*TaMe4] on silica partially dehydroxylated at 700 degrees C and the activity of the grafted complexes toward alkane metathesis.

Beta-H transfer from the metallacyclobutane: a key step in the deactivation and byproduct formation for the well-defined silica-supported rhenium alkylidene alkene metathesis catalyst.

Primary products and mechanistic considerations in alkane metathesis.

P304

9030-9037

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P31

scholarly article

P356

10.1002/CHEM.200800864

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English

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http://www.w3.org/2001/XMLSchema#string

P478

http://www.w3.org/2001/XMLSchema#string

P50

Jean-Marie Basset

Frédéric Blanc

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2008-01-01T00:00:00Z

http://www.w3.org/2001/XMLSchema#dateTime

P698

18752230

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Structure-reactivity relationship in alkane metathesis using well-defined silica-supported alkene metathesis catalyst precursors.

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P2860

P2860

Structure-reactivity relationship in alkane metathesis using well-defined silica-supported alkene metathesis catalyst precursors.

description

name

type

label

prefLabel

P1433

P1476

P2093

P2860

P304

P31

P356

P407

P433

P478

P50

P577

P698

P356

P1433

P1476

P2093

P2860

P304

P31

P356

P407

P433

P478

P50

P577

P698