Chemistry of tris(pentamethylcyclopentadienyl) f-element complexes, (C(5)Me(5))(3)M.
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C-H bond activation through steric crowding of normally inert ligands in the sterically crowded gadolinium and yttrium (C5Me5)3M complexesCyclometalative C-H bond activation in rare earth and actinide metal complexes.Lanthanide versus actinide reactivity in the formation of sterically crowded [(C(5)Me(5))(3)ML(n)] nitrile and isocyanide complexes.Selective transformations of cyclopentadienyl ligands of transition-metal and rare-earth metal complexes.Versatile reactivity of a lithium tris(aryl)plumbate(II) towards organolanthanoid compounds: stable lead-lanthanoid-metal bonds or redox processes.Reductive assembly of cyclobutadienyl and diphosphacyclobutadienyl rings at uranium.Group 3 metal stilbene complexes: synthesis, reactivity, and electronic structure studies.Rare earth metal bis(silylamide) complexes bearing pyridyl-functionalized indenyl ligand: synthesis, structure and performance in the living polymerization of L-lactide and rac-lactide.Yttrium complexes incorporating the chelating diamides [ArN(CH2)xNAr]2- (Ar = C6H3-2,6-iPr2, x= 2, 3) and their unusual reaction with phenylsilane.Synthesis, structure, and catalytic activity of novel trinuclear rare-earth metal amido complexes incorporating μ-η5:η1 bonding indolyl and μ3-oxo groups.Synthesis of a thorium tuck-in complex, [(eta(5):eta(1)-C(5)Me(4)CH(2))(eta(5)-C(5)Me(5))Th{iPrNC(Me)NiPr}], by C-H bond activation initiated by (C(5)Me(5))(-).Tris(polyalkylcyclopentadienyl) complexes: the elusive [(η5-C5R5)2M(η1-C5R5)] structure and trihapto cyclopentadienyl coordination involving a methyl substituent.Structural analysis of zincocenes with substituted cyclopentadienyl rings.An amidato divalent ytterbium cluster: synthesis and molecular structure, its reactivity to carbodiimides and application in the guanylation reaction.The distinct affinity of cyclopentadienyl ligands towards trivalent uranium over lanthanide ions. Evidence for cooperative ligation and back-bonding in the actinide complexes.The importance of a single methyl group in determining the reaction chemistry of pentamethylcyclopentadienyl cyclooctatetraenyl uranium metallocenes.Computational insights into carbon-carbon homocoupling reactions mediated by organolanthanide(III) complexes.Ln(III) methyl and methylidene complexes stabilized by a bulky hydrotris(pyrazolyl)borate ligand.Theoretical treatment of one electron redox transformation of a small molecule using f-element complexes.Evidence for single metal two electron oxidative addition and reductive elimination at uranium.Formation and ligand-based reductive chemistry of bridged bis-alkylidene scandium(iii) complexes.Substituent size effects in lewis base induced reductions in organolanthanide chemistry.A naphthyl-substituted pentamethylcyclopentadienyl ligand and its Sm(II) bent-metallocene complexes with solvent-induced structure change.Mono(boratabenzene) rare-earth metal dialkyl complexes: synthesis, structure and catalytic behaviors for styrene polymerization.Insertion/Rearrangement Reactivity of a Lutetacyclopentadiene towards N,N'-Diphenylcarbodiimide: Cooperative Effect of the Metal Center, Concentration of LiCl, and Solvent.Terminal Uranium(V/VI) Nitride Activation of Carbon Dioxide and Carbon Disulfide: Factors Governing Diverse and Well-Defined Cleavage and Redox Reactions.Heteroscorpionate rare-earth metal zwitterionic complexes: syntheses, characterization, and heteroselective catalysis on the ring-opening polymerization of rac-lactide.
P2860
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P2860
Chemistry of tris(pentamethylcyclopentadienyl) f-element complexes, (C(5)Me(5))(3)M.
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name
Chemistry of tris(pentamethylcyclopentadienyl) f-element complexes, (C(5)Me(5))(3)M.
@en
Chemistry of tris(pentamethylcyclopentadienyl) f-element complexes, (C(5)Me(5))(3)M.
@nl
type
label
Chemistry of tris(pentamethylcyclopentadienyl) f-element complexes, (C(5)Me(5))(3)M.
@en
Chemistry of tris(pentamethylcyclopentadienyl) f-element complexes, (C(5)Me(5))(3)M.
@nl
prefLabel
Chemistry of tris(pentamethylcyclopentadienyl) f-element complexes, (C(5)Me(5))(3)M.
@en
Chemistry of tris(pentamethylcyclopentadienyl) f-element complexes, (C(5)Me(5))(3)M.
@nl
P356
P1433
P1476
Chemistry of tris(pentamethylcyclopentadienyl) f-element complexes, (C(5)Me(5))(3)M.
@en
P2093
Benjamin L Davis
William J Evans
P304
P356
10.1021/CR010298R
P577
2002-06-01T00:00:00Z