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6-Substituted purines containing thienyl or furyl substituents as artificial nucleobases for metal-mediated base pairing.Platinum(II) and palladium(II) complexes of tridentate hydrazone-based ligands as selective guanine quadruplex binders.Synthesis of cationic R2P5(+) cages and subsequent chalcogenation reactions.Structural diversity in bishydroxylamine complexes of gallium.Activation of isocyanates and carbon dioxide by a monomeric aluminium hydrazide as an active Lewis pair.Small Molecule Activation with N,NR-MIC Platinum Complexes.Cooperative Activation of Isocyanates by Al-N-Based Active Lewis Pairs and the Generation of a C5 Chain by Simultaneous Formation of Two C-C Bonds.Reactions of an Al/P Frustrated Lewis Pair with α,β-Unsaturated Carbonyl Compounds - FLPs as Efficient 2e Reductants with the Formation of Enolates, a cis-Enediolate and an Allene.Molybdenum and tungsten eta2-alkyne-1-thio complexes acting as sulfur donors in homoleptic Werner type complexes with nickel(II) and palladium(II).Alkynyl functionalized Al/P-based frustrated Lewis pairs - aluminium alkynide elimination and evidence for the formation of 3H-phosphaallenes [R-P=C=C(H)-(t)Bu].Regioselectivity of the C-metalation of 6-furylpurine: importance of directing effects.Oligonuclear gallium nitrogen cage compounds: molecular intermediates on the way from gallium hydrazides to gallium nitride.A Family of Hydrazone-Based Nucleosides for Use in Metal-Mediated Base PairsSilver(I) and Mercury(II) Complexes with 1-Methyl-1,2,4-triazole as Models for Metal-Mediated Base Pairs - Formation of Discrete Complexes in Solution vs. One- and Two-Dimensional Coordination Polymers in the Solid StateSynthesis and Reactivity of Intramolecularly NHC-Stabilized Germylenes and StannylenesNeutral and Cationic Hydridoruthenium Tetrakiscarbene ComplexesFormation of Cationic [RP5Cl]+-Cages via Insertion of [RPCl]+-Cations into a P–P Bond of the P4 Tetrahedronπ-Bonding in Complexes of Benzannulated Biscarbenes, -germylenes, and -stannylenes: An Experimental and Theoretical StudyMononuclear and dinuclear bromo bridged iridium(I) complexes with N-allyl substituted imidazolin-2-ylidene ligandsZwitterionic and cationic P5-clusters from four-membered phosphorus–nitrogen–metal heterocyclesGold(III)-mediated cyclization of 2-hydrazinylquinolinesMetal complexes of 6-pyrazolylpurine derivatives as models for metal-mediated base pairsUnprecedented dinuclear silver(i)-mediated base pair involving the DNA lesion 1,N6-ethenoadenineA Family of “Click” Nucleosides for Metal-Mediated Base Pairing: Unravelling the Principles of Highly Stabilizing Metal-Mediated Base PairsThe reactions of dialkylgallium hydrides with tert-butylethynylbenzenes--a systematic investigation into the course of hydrogallation reactionsThe role of amines in the growth of terbium(III)-doped cerium phosphate nanoparticlesCarbanions with two N substituents: nucleophilic acyl-group-transfer reagentsHydroxylaminato yttrate and samarate complexesTrapping of tin(II) and lead(II) homologues of carbon monoxide by a benzannulated lutidine-bridged bisstannyleneVinylgallium and alkyllithium compounds: transmetalation and generation of oligolithium cagesSynthesis of silver(I) and gold(I) complexes with cyclic tetra- and hexacarbene ligandsCoordination chemistry of bisstannylenes with platinum(0)The missing link in the coordination chemistry of hydrazines--a hydrazinetriide [N-N(Me)](3-) anion coordinated to five Al atomsOrgano-aluminium and -gallium complexes with omega-NH-functional alkoxide ligandsDimeric aluminum-phosphorus compounds as masked frustrated Lewis pairs for small molecule activationFacile formation of a persistent butadien-2-yl cation stabilized by hyperconjugation with an Al-C bondPalladium and platinum complexes of a benzannulated N-heterocyclic plumbylene with an unusual bonding modeAlkynide and acetonitrile activation by strained AlPC2 heterocyclesHydroalumination of alkynyl-aminophosphines as a promising tool for the synthesis of unusual phosphines: P-N bond activation, a transient phosphaallene, a zwitterionic AlP2C2 heterocycle and a masked Al/P-based frustrated Lewis pairFunctionalized alkynyl-chlorogermanes: hydrometallation, Ge-Cl bond activation, Ge-H bond formation and chlorine-tert-butyl exchange via a transient germyl cation
P50
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P50
description
hulumtues
@sq
onderzoeker
@nl
researcher
@en
հետազոտող
@hy
name
Alexander Hepp
@ast
Alexander Hepp
@en
Alexander Hepp
@es
Alexander Hepp
@nl
Alexander Hepp
@sl
type
label
Alexander Hepp
@ast
Alexander Hepp
@en
Alexander Hepp
@es
Alexander Hepp
@nl
Alexander Hepp
@sl
prefLabel
Alexander Hepp
@ast
Alexander Hepp
@en
Alexander Hepp
@es
Alexander Hepp
@nl
Alexander Hepp
@sl
P106
P21
P31
P496
0000-0003-1288-925X