Questioning the paradigm of metal complex promoted phosphodiester hydrolysis: [Mo7O24](6-) polyoxometalate cluster as an unlikely catalyst for the hydrolysis of a DNA model substrate.
about
A survey of the different roles of polyoxometalates in their interaction with amino acids, peptides and proteins.Recent advances on polyoxometalate-based molecular and composite materials.Use of MoO2Cl2(DMF)2 as a precursor for molybdate promoted hydrolysis of phosphoester bonds.Hydrolytic cleavage of DNA-model substrates promoted by polyoxovanadates.Amino acid side chain induced selectivity in the hydrolysis of peptides catalyzed by a Zr(IV)-substituted Wells-Dawson type polyoxometalate.Molecular interactions between serum albumin proteins and Keggin type polyoxometalates studied using luminescence spectroscopy.When structural and electronic analogy leads to reactivity: the unprecedented phosphodiesterase activity of vanadates.Selective hydrolysis of oxidized insulin chain B by a Zr(IV)-substituted Wells-Dawson polyoxometalate.Hydrolysis of DNA model substrates catalyzed by metal-substituted Wells-Dawson polyoxometalates.Integrating 31P DOSY NMR spectroscopy and molecular mechanics as a powerful tool for unraveling the chemical structures of polyoxomolybdate-based amphiphilic nanohybrids in aqueous solution.Polyoxometalates as a novel class of artificial proteases: selective hydrolysis of lysozyme under physiological pH and temperature promoted by a cerium(IV) Keggin-type polyoxometalate.Hydrolysis of the RNA model substrate catalyzed by a binuclear Zr(IV)-substituted Keggin polyoxometalate.Use of Organomolybdenum Compounds for Promoted Hydrolysis of Phosphoester Bonds in Aqueous MediaInteraction Study and Reactivity of ZrIV-Substituted Wells-Dawson Polyoxometalate towards Hydrolysis of Peptide Bonds in Surfactant SolutionsHydrolysis of carboxyesters promoted by vanadium(v) oxyanionsSelectivity and Reactivity of Zr and Ce Substituted Keggin Type Polyoxometalates Toward Cytochrome c in Surfactant Solutions
P2860
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P2860
Questioning the paradigm of metal complex promoted phosphodiester hydrolysis: [Mo7O24](6-) polyoxometalate cluster as an unlikely catalyst for the hydrolysis of a DNA model substrate.
description
2008 nî lūn-bûn
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2008年の論文
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2008年学术文章
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2008年学术文章
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name
Questioning the paradigm of metal complex promoted phosphodiester hydrolysis: [Mo7O24]
@nl
Questioning the paradigm of me ...... ysis of a DNA model substrate.
@en
type
label
Questioning the paradigm of metal complex promoted phosphodiester hydrolysis: [Mo7O24]
@nl
Questioning the paradigm of me ...... ysis of a DNA model substrate.
@en
prefLabel
Questioning the paradigm of metal complex promoted phosphodiester hydrolysis: [Mo7O24]
@nl
Questioning the paradigm of me ...... ysis of a DNA model substrate.
@en
P2860
P356
P1476
Questioning the paradigm of me ...... lysis of a DNA model substrate
@en
P2093
Els Cartuyvels
Gregory Absillis
P2860
P356
10.1039/B714860G
P407
P577
2008-01-01T00:00:00Z