Dichotomic reactivity of a stable silylene toward terminal alkynes: facile C-H bond insertion versus autocatalytic formation of silacycloprop-3-ene.
about
Formation of N-heterocyclic, donor-stabilized borenium ions.Reaction of an N-heterocyclic carbene-stabilized silicon(II) monohydride with alkynes: [2+2+1] cycloaddition versus hydrogen abstraction.A facile access to a novel NHC-stabilized silyliumylidene ion and C-H activation of phenylacetylene.Versatile conversion of N-heterocyclic silylene to silyl metal compounds by insertion of divalent silicon into metal-carbon and metal-hydrogen bonds.Twice silicon-induced C-H activation and tautomerisation of a beta-diketiminato ligand and formation of new types of N-heterocyclic silanes.Reductive Cleavage of Carbon Monoxide by a Disilenide.Synthesis of stable silicon heterocycles by reaction of organic substrates with a chlorosilylene [PhC(NtBu)2SiCl].NHC-stabilized silagermenylidene: a heavier analogue of vinylidene.Convenient Access to Monosilicon Epoxides with Pentacoordinate SiliconConvenient Access to Monosilicon Epoxides with Pentacoordinate Silicon
P2860
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P2860
Dichotomic reactivity of a stable silylene toward terminal alkynes: facile C-H bond insertion versus autocatalytic formation of silacycloprop-3-ene.
description
2008 nî lūn-bûn
@nan
2008年の論文
@ja
2008年学术文章
@wuu
2008年学术文章
@zh-cn
2008年学术文章
@zh-hans
2008年学术文章
@zh-my
2008年学术文章
@zh-sg
2008年學術文章
@yue
2008年學術文章
@zh
2008年學術文章
@zh-hant
name
Dichotomic reactivity of a sta ...... mation of silacycloprop-3-ene.
@en
Dichotomic reactivity of a sta ...... mation of silacycloprop-3-ene.
@nl
type
label
Dichotomic reactivity of a sta ...... mation of silacycloprop-3-ene.
@en
Dichotomic reactivity of a sta ...... mation of silacycloprop-3-ene.
@nl
prefLabel
Dichotomic reactivity of a sta ...... mation of silacycloprop-3-ene.
@en
Dichotomic reactivity of a sta ...... mation of silacycloprop-3-ene.
@nl
P2093
P356
P1476
Dichotomic reactivity of a sta ...... mation of silacycloprop-3-ene.
@en
P2093
Christoph van Wüllen
Shenglai Yao
Xiao-Ying Sun
P304
P356
10.1002/ANIE.200704939
P407
P577
2008-01-01T00:00:00Z