WMe6 tamed by silica: ≡Si-O-WMe5 as an efficient, well-defined species for alkane metathesis, leading to the observation of a supported W-methyl/methylidyne species.
about
Single site silica supported tetramethyl niobium by the SOMC strategy: synthesis, characterization and structure-activity relationship in the ethylene oligomerization reaction.Methyl Complexes of the Transition Metals.Reactive surface organometallic complexes observed using dynamic nuclear polarization surface enhanced NMR spectroscopy.Effect of support on metathesis of n-decane: drastic improvement in alkane metathesis with WMe5 linked to silica-alumina.Direct observation of supported W bis-methylidene from supported W-methyl/methylidyne species.Simple addition of silica to an alkane solution of a Wilkinson WMe6 or Schrock W alkylidyne complex gives an active complex for saturated and unsaturated hydrocarbon metathesis.Synthesis and characterization of a homogeneous and silica supported homoleptic cationic tungsten(vi) methyl complex: application in olefin metathesis.Controlling the hydrogenolysis of silica-supported tungsten pentamethyl leads to a class of highly electron deficient partially alkylated metal hydrides† †Electronic supplementary information (ESI) available: Complete experimental and quantum chemicPredicting the DNP-SENS efficiency in reactive heterogeneous catalysts from hydrophilicity.
P2860
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P2860
WMe6 tamed by silica: ≡Si-O-WMe5 as an efficient, well-defined species for alkane metathesis, leading to the observation of a supported W-methyl/methylidyne species.
description
2014 nî lūn-bûn
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2014年の論文
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2014年学术文章
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2014年学术文章
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2014年学术文章
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2014年学术文章
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2014年学术文章
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2014年學術文章
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name
WMe6 tamed by silica: ≡Si-O-WM ...... W-methyl/methylidyne species.
@en
WMe6 tamed by silica: ≡Si-O-WM ...... W-methyl/methylidyne species.
@nl
type
label
WMe6 tamed by silica: ≡Si-O-WM ...... W-methyl/methylidyne species.
@en
WMe6 tamed by silica: ≡Si-O-WM ...... W-methyl/methylidyne species.
@nl
prefLabel
WMe6 tamed by silica: ≡Si-O-WM ...... W-methyl/methylidyne species.
@en
WMe6 tamed by silica: ≡Si-O-WM ...... W-methyl/methylidyne species.
@nl
P2093
P50
P356
P1476
WMe6 tamed by silica: ≡Si-O-WM ...... W-methyl/methylidyne species.
@en
P2093
Edy Abou-Hamad
Emmanuel Callens
Manoja K Samantaray
P304
P356
10.1021/JA410747G
P407
P577
2014-01-10T00:00:00Z