Tetrel bond-σ-hole bond as a preliminary stage of the SN2 reaction.
about
Highly Selective Halide Receptors Based on Chalcogen, Pnicogen, and Tetrel Bonds.Nature of noncovalent carbon-bonding interactions derived from experimental charge-density analysis.Negative hyperconjugation and red-, blue- or zero-shift in X-Z∙∙∙Y complexes.Halogen bonding interaction of chloromethane with several nitrogen donating molecules: addressing the nature of the chlorine surface σ-hole.Synthesis of Electron-Rich, Planarized Silicon(IV) Species and a Theoretical Analysis of Dimerizing Aminosilanes.Interpretation of Spectroscopic Markers of Hydrogen Bonds.1,1,2,2-Tetracyanocyclopropane (TCCP) as supramolecular synthon.Cleavage of hydrogen by activation at a single non-metal centre - towards new hydrogen storage materials.A σ-hole interaction with radical species as electron donors: does single-electron tetrel bonding exist?Close contacts involving germanium and tin in crystal structures: experimental evidence of tetrel bonds.The effect of atomic ions on model σ-hole bonded complexes of AH3Y (A = C, Si, Ge; Y = F, Cl, Br).Influence of ring size on the strength of carbon bonding complexes between anions and perfluorocycloalkanes.Tetrel Bonding Interactions.Mapping the Trajectory of Nucleophilic Substitution at Silicon Using a peri-Substituted Acenaphthyl Scaffold.Hypervalency, secondary bonding and hydrogen bonding: siblings under the skin.Comparison of tetrel bonds in neutral and protonated complexes of pyridineTF3 and furanTF3 (T = C, Si, and Ge) with NH3.Revealing the physical nature and the strength of charge-inverted hydrogen bonds by SAPT(DFT), MP2, SCS-MP2, MP2C, and CCSD(T) methods.Reactivity of electrophilic chlorine atoms due to σ-holes: a mechanistic assessment of the chemical reduction of a trichloromethyl group by sulfur nucleophiles.Comparison of Various Means of Evaluating Molecular Electrostatic Potentials for Noncovalent Interactions.Interplay between tetrel and triel bonds in RC6H4CN⋯MF3CN⋯BX3 complexes: A combined symmetry-adapted perturbation theory, Møller-Plesset, and quantum theory of atoms-in-molecules study.Hydrogen bonds and other interactions as a response to protect doublet/octet electron structure.Halogen Bonding Involving CO and CS with Carbon as the Electron Donor.The silane-methane dimer revisited: more than a dispersion-bound system?Heteronuclear cobalt(iii)/sodium complexes with salen type compartmental Schiff base ligands: methylene spacer regulated variation in nuclearity.Alkaline-earth (Be, Mg and Ca) bonds at the origin of huge acidity enhancements.Hydrogen bonds, and σ-hole and π-hole bonds - mechanisms protecting doublet and octet electron structures.Continuum in the X-Z---Y weak bonds: Z= main group elements.Tetrel bond of pseudohalide anions with XH3F (X = C, Si, Ge, and Sn) and its role in SN2 reaction.Significant evidence of C···O and C···C long-range contacts in several heterodimeric complexes of CO with CH3-X, should one refer to them as carbon and dicarbon bonds!An exploration of the ozone dimer potential energy surface.Intermolecular carbon-carbon, nitrogen-nitrogen and oxygen-oxygen non-covalent bonding in dipolar molecules.Modulating the strength of tetrel bonding through beryllium bonding.Halogen Bonding in Hypervalent Iodine Compounds.Theoretical study of the cooperative effects between the triel bond and the pnicogen bond in BF3···NCXH2···Y (X = P, As, Sb; Y = H2O, NH3) complexes.Design of Lead(II) Metal-Organic Frameworks Based on Covalent and Tetrel Bonding.Unusual bonding modes of perfluorobenzene in its polymeric (dimeric, trimeric and tetrameric) forms: entirely negative fluorine interacting cooperatively with entirely negative fluorine.Triel Bonds, π-Hole-π-Electrons Interactions in Complexes of Boron and Aluminium Trihalides and Trihydrides with Acetylene and Ethylene.
P2860
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P2860
Tetrel bond-σ-hole bond as a preliminary stage of the SN2 reaction.
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年学术文章
@wuu
2014年学术文章
@zh
2014年学术文章
@zh-cn
2014年学术文章
@zh-hans
2014年学术文章
@zh-my
2014年学术文章
@zh-sg
2014年學術文章
@yue
2014年學術文章
@zh-hant
name
Tetrel bond-σ-hole bond as a preliminary stage of the SN2 reaction.
@en
Tetrel bond-σ-hole bond as a preliminary stage of the SN2 reaction.
@nl
type
label
Tetrel bond-σ-hole bond as a preliminary stage of the SN2 reaction.
@en
Tetrel bond-σ-hole bond as a preliminary stage of the SN2 reaction.
@nl
prefLabel
Tetrel bond-σ-hole bond as a preliminary stage of the SN2 reaction.
@en
Tetrel bond-σ-hole bond as a preliminary stage of the SN2 reaction.
@nl
P2860
P356
P1476
Tetrel bond-σ-hole bond as a preliminary stage of the SN2 reaction.
@en
P2093
Sławomir J Grabowski
P2860
P304
P356
10.1039/C3CP53369G
P407
P577
2014-02-01T00:00:00Z