Chloride assisted supramolecular assembly of a luminescent gigantic cluster: [Ag216S56Cl7(C[triple bond, length as m-dash]CPh)98(H2O)12]- with pseudo-Th skeleton and five-shell arrangement.

Chloride assisted supramolecular assembly of a luminescent gigantic cluster: [Ag216S56Cl7(C[triple bond, length as m-dash]CPh)98(H2O)12]- with pseudo-Th skeleton and five-shell arrangement.