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The lipoxygenase pathway in tulip (Tulipa gesneriana): detection of the ketol routeUnprecedented pathogen-inducible complex oxylipins from flax--linolipins A and B.Recent developments in biochemistry of the plant lipoxygenase pathway.Hydroperoxide lyase and divinyl ether synthase.Identification of CYP443D1 (CYP74 clan) of Nematostella vectensis as a first cnidarian epoxyalcohol synthase and insights into its catalytic mechanism.Oxylipin biosynthesis in spikemoss Selaginella moellendorffii: Molecular cloning and identification of divinyl ether synthases CYP74M1 and CYP74M3.Clavulones and related tert-hydroxycyclopentenone fatty acids: occurrence, physiological activity and problem of biogenetic origin.Oxylipins in the spikemoss Selaginella martensii: Detection of divinyl ethers, 12-oxophytodienoic acid and related cyclopentenones.Stereospecific biosynthesis of (9S,13S)-10-oxo-phytoenoic acid in young maize roots.Divinyl ether synthase from garlic (Allium sativum L.) bulbs: sub-cellular localization and substrate regio-and stereospecificity.Hexadecanoid pathway in plants: Lipoxygenase dioxygenation of (7Z,10Z,13Z)-hexadecatrienoic acid.Specificity of oxidation of linoleic acid homologs by plant lipoxygenases.Detection and molecular cloning of CYP74Q1 gene: identification of Ranunculus acris leaf divinyl ether synthase.Hydroperoxide lyase cascade in pea seedlings: Non-volatile oxylipins and their age and stress dependent alterations.Isolation and structure elucidation of linolipins C and D, complex oxylipins from flax leaves.Detection of an enol intermediate in the hydroperoxide lyase chain cleavage reaction.The "heterolytic hydroperoxide lyase" is an isomerase producing a short-lived fatty acid hemiacetal.The novel pathway for ketodiene oxylipin biosynthesis in Jerusalem artichoke (Helianthus tuberosus) tubers.Detection of divinyl ether synthase in Lily-of-the-Valley (Convallaria majalis) roots.Tomato CYP74C3 is a multifunctional enzyme not only synthesizing allene oxide but also catalyzing its hydrolysis and cyclization.Determinants governing the CYP74 catalysis: conversion of allene oxide synthase into hydroperoxide lyase by site-directed mutagenesis.A lipoxygenase-divinyl ether synthase pathway in flax (Linum usitatissimum L.) leaves.The chloroplast membrane associated ceQORH putative quinone oxidoreductase reduces long-chain, stress-related oxidized lipids.[Geometrical configuration of 12,13-epoxy-9,11-octadecadienoic acid, a product of the reaction catalyzed by flaxseed allene oxide synthase (CYP74A)]Oxidation of glycerolipids by maize 9-lipoxygenase and its A562G mutant.Detection of a pathway from linoleate to a novel cyclopentenone: cis-12-oxo-10-phytoenoic acid in sunflower roots.Regio- and stereospecificity of recombinant soybean lipoxygenase-2.Green leaf divinyl ether synthase: gene detection, molecular cloning and identification of a unique CYP74B subfamily member.Rearrangement of vinyl allene oxide geometric isomers to cyclopentenones. Further computational insights with biologically relevant model systems.Double function hydroperoxide lyases/epoxyalcohol synthases (CYP74C) of higher plants: identification and conversion into allene oxide synthases by site-directed mutagenesis.A unifying mechanism for the rearrangement of vinyl allene oxide geometric isomers to cyclopentenones.Screening of divinyl ether synthase activity in nonphotosynthetic tissue of asparagales.Epoxyalcohol synthase of Ectocarpus siliculosus. First CYP74-related enzyme of oxylipin biosynthesis in brown algae.Hydroperoxide lyases (CYP74C and CYP74B) catalyze the homolytic isomerization of fatty acid hydroperoxides into hemiacetals.Alteration of the catalytic properties of divinyl ether synthase as a result of substitutions of unique amino acids.Allene Oxide Synthase Pathway in Cereal Roots: Detection of Novel Oxylipin Graminoxins.Synthesis of 3-oxalinolenic acid and β-oxidation-resistant 3-oxa-oxylipinsDouble hydroperoxidation of alpha-linolenic acid by potato tuber lipoxygenaseHydroperoxides of alpha-ketols. Novel products of the plant lipoxygenase pathwayCyclization of natural allene oxide fatty acids. The anchimeric assistance of beta, gamma-double bond beside the oxirane and the reaction mechanism
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