Gold(I)-catalyzed diazo coupling: strategy towards alkene formation and tandem benzannulation.
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Recent Developments in Coinage Metal Catalyzed Transformations of Stabilized Vinyldiazo Compounds: Beyond Carbenic Pathways.Synthesis of Functionalized Cyclopentene Derivatives from Vinyldiazo Compounds and Vinylazides through Sequential Copper-Promoted [3+2] Cycloaddition/Azide Rearrangement.Gold-catalyzed cycloaddition reactions of ethyl diazoacetate, nitrosoarenes, and vinyldiazo carbonyl compounds: synthesis of isoxazolidine and benzo[b]azepine derivatives.Gold-catalyzed para-selective C-H bond alkylation of benzene derivatives with donor/acceptor-substituted diazo compounds.Gold-catalyzed sequential annulations towards 3,4-fused bi/tri-cyclic furans involving a [3+2+2]-cycloaddition.Isolation of a Reactive Tricoordinate α-Oxo Gold Carbene Complex.Copper(I)-Catalyzed Chemoselective Coupling of Cyclopropanols with Diazoesters: Ring-Opening C-C Bond Formations.Gold-catalyzed highly regio- and enantioselective vinylcarbene insertion into O-H bonds of 2-pyridones.One-pot construction of sterically challenging and diverse polyarylphenols via transition-metal-free benzannulation and their potent in vitro antioxidant activity.Highly para-Selective C-H Alkylation of Benzene Derivatives with 2,2,2-Trifluoroethyl α-Aryl-α-Diazoesters.Catalytic Divergent [3+3]- and [3+2]-Cycloaddition by Discrimination Between Diazo Compounds.Highly Stereoselective Gold-Catalyzed Coupling of Diazo Reagents and Fluorinated Enol Silyl Ethers to Tetrasubstituted Alkenes.Gold-catalysed facile access to indene scaffolds via sequential C-H functionalization and 5-endo-dig carbocyclization.Asymmetric sequential Au(i)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles.Sequential Au(i)/chiral tertiary amine catalysis: a tandem C-H functionalization of anisoles or a thiophene/asymmetric Michael addition sequence to quaternary oxindoles.One-Pot Synthesis of Polysubstituted Benzenes through a N,N-dimethyl-4-aminopyridine (DMAP)-Catalyzed [4+2] Benzannulation of 1,3-Bis(sulfonyl)butadienes and γ-Substituted Allenoates.A controlled selective synthesis of dihydropyrans through tandem reaction of alkynes with diazo compounds.Gold/silver-catalyzed controllable regioselective vinylcarbene insertion into O-H bonds.Gold-Catalyzed Formal [4+1]/[4+3] Cycloadditions of Diazo Esters with Triazines.Stereodivergent Synthesis of N-Heterocycles by Catalyst-Controlled, Activity-Directed Tandem Annulation of Diazo Compounds with Amino Alkynes.Base-Promoted/Gold-Catalyzed Intramolecular Highly Selective and Controllable Detosylative Cyclization.Z-Selective iridium-catalyzed cross-coupling of allylic carbonates and α-diazo esters.Gold-catalyzed stereoselective dearomatization/metal-free aerobic oxidation: access to 3-substituted indolines/oxindoles.Gold(I)-catalyzed diazo cross-coupling: a selective and ligand-controlled denitrogenation/cyclization cascade.Origins of unique gold-catalysed chemo- and site-selective C–H functionalization of phenols with diazo compounds† †Electronic supplementary information (ESI) available: Data for new compounds, experimental procedures and theoretical studies on mechaIsolation of a Reactive Tricoordinate α-Oxo Gold Carbene Complex
P2860
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P2860
Gold(I)-catalyzed diazo coupling: strategy towards alkene formation and tandem benzannulation.
description
2014 nî lūn-bûn
@nan
2014年の論文
@ja
2014年学术文章
@wuu
2014年学术文章
@zh
2014年学术文章
@zh-cn
2014年学术文章
@zh-hans
2014年学术文章
@zh-my
2014年学术文章
@zh-sg
2014年學術文章
@yue
2014年學術文章
@zh-hant
name
Gold(I)-catalyzed diazo coupli ...... ion and tandem benzannulation.
@en
type
label
Gold(I)-catalyzed diazo coupli ...... ion and tandem benzannulation.
@en
prefLabel
Gold(I)-catalyzed diazo coupli ...... ion and tandem benzannulation.
@en
P2093
P2860
P356
P1476
Gold(I)-catalyzed diazo coupli ...... tion and tandem benzannulation
@en
P2093
Chenghao Zhu
Daming Zhang
Guangyang Xu
P2860
P304
11070-11074
P356
10.1002/ANIE.201406712
P407
P50
P577
2014-08-25T00:00:00Z