A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation.
about
Fluorinated dienes in transition-metal chemistry - the rich chemistry of electron-poor ligands.Synthesis of fluorinated building blocks by transition-metal-mediated hydrodefluorination reactions.Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution.Photochemical Reactions of Fluorinated Pyridines at Half-Sandwich Rhodium Complexes: Competing Pathways of Reaction.Oxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(I)Borylation of fluorinated arenes using the boron-centred nucleophile B(CN)32- - a unique entry to aryltricyanoborates.Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluoropyridine.Photolytic C-H activation and dehydrogenation of alkanes at cyclopentadienyl iridium complexes in a perfluorinated solvent.Catalytic hydrodefluorination of fluoromethanes at room temperature by silylium-ion-like surface species.Suzuki-Miyaura Cross-Coupling Reactions of Highly Fluorinated Arylboronic Esters: Catalytic Studies and Stoichiometric Model Reactions on the Transmetallation Step.Transition-Metal-Mediated Cleavage of Fluoro-Silanes under Mild Conditions.Catalytic defluorinative [3 + 2] cycloaddition of trifluoromethylalkenes with alkynes via reduction of nickel(II) fluoride species.Remarkable reactivity of a rhodium(I) boryl complex towards CO2 and CS2: isolation of a carbido complex.Transition-Metal-Free Formation of C-E Bonds (E = C, N, O, S) and Formation of C-M Bonds (M = Mn, Mo) from N-Heterocyclic Carbene Mediated Fluoroalkene C-F Bond Activation.Palladium-catalyzed amination of 2,3,3-trifluoroallyl esters: synthesis of trifluoromethylenamines via an intramolecular fluorine shift and CF3 group construction.Activation of SF6 at Platinum Complexes: Formation of SF3 Derivatives and Their Application in Deoxyfluorination Reactions.Palladium-Catalyzed Carbon-Fluorine and Carbon-Hydrogen Bond Alumination of Fluoroarenes and Heteroarenes.Iridium-catalyzed synthesis of diaryl ethers by means of chemoselective C-F bond activation and the formation of B-F bonds.Synthesis of a rhodium(i) germyl complex: a useful tool for C-H and C-F bond activation reactions.Reactivity of platinum alkyne complexes towards N-fluorobenzenesulfonimide: formation of platinum compounds bearing a β-fluorovinyl ligand.Catalytic borylation of SCF₃-functionalized arenes by rhodium(I) boryl complexes: regioselective C-H activation at the ortho-position.Insertion of CS(2) into iridium-fluorine bonds.Titanium-catalyzed vinylic and allylic C-F bond activation-scope, limitations and mechanistic insight.Synthesis of the smallest axially chiral molecule by asymmetric carbon-fluorine bond activation.Facile oxidative addition of water at iridium: reactivity of trans-[Ir(4-C5NF4)(H)(OH)(PiPr3)2] towards CO2 and NH3.Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin.Competing reaction pathways of 3,3,3-trifluoropropene at rhodium hydrido, silyl and germyl complexes: C-F bond activation versus hydrogermylation.A combined experimental and computational study on the reaction of fluoroarenes with Mg-Mg, Mg-Zn, Mg-Al and Al-Zn bonds.
P2860
Q37780468-83ADE92C-2ECB-44F6-B6B5-FD38EFD312B1Q39478127-3171BA53-FF4F-46F4-B557-6287AED0DE70Q41906578-690841B6-7042-4AFD-995C-EA8CA12977A8Q41965852-EF2F1387-AB72-4B7A-95FA-3ADC4F648A08Q41969293-6E06E24D-8E45-4A28-9875-3C82D6DF375EQ42055547-7A0093B6-513A-4F2D-B928-2DA1A1A7D034Q43019840-F30EDD42-64D5-4FF9-BCA1-1E63F40259D7Q44223456-25B8A3D5-475A-4E31-8BE7-3E099243C98CQ45307379-13AB99A1-7631-44AA-B509-486CB2D07D41Q46403875-B1918567-EB34-4873-A58D-15881C5521CFQ46601685-90FD2FFB-8FE2-49E9-A84B-DF2F57564FC3Q46675037-0EE5BF62-57F9-4D49-B07C-E0E37A2602C0Q46682293-C7FBFA70-A792-4A93-AE2E-63A086210535Q47986118-E68FE164-5DA2-46F6-A770-AD5C2F913C7BQ48045407-F9E7BFB7-3185-40F0-B340-BD10DF96295CQ48102958-CF9BC00A-D4D0-42EC-835D-FDF89059085DQ48237520-6268A656-CF1A-44F7-9F4A-64A75F1ED080Q51035612-F400E884-977D-43ED-8294-0B989F27D16CQ52856697-46AA8039-334C-4EDF-9564-DF8EEBC44982Q52862891-5EAE573F-698A-4102-A494-6494348B4923Q52874840-B7BCEC1C-35E1-46B0-8E9D-675497C86332Q52882491-FB0A0E1A-7CAC-4BC3-98ED-697D58E41098Q52887567-EEF77A08-F529-4E58-B3BF-4E4280D0517EQ52890089-683F97D2-B2FA-4BA0-87C5-440A8480D912Q52895261-C5FB2E71-4130-4E47-A4FD-5D26F0B6A45AQ53647230-F0003A87-30EA-4569-B833-62A4C09910C4Q54385326-8B1AFB69-01D8-4669-88B3-D887F1C683EEQ55074535-D31B8869-7EFC-46C5-8F69-491F475062DB
P2860
A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation.
description
2010 nî lūn-bûn
@nan
2010年の論文
@ja
2010年学术文章
@wuu
2010年学术文章
@zh
2010年学术文章
@zh-cn
2010年学术文章
@zh-hans
2010年学术文章
@zh-my
2010年学术文章
@zh-sg
2010年學術文章
@yue
2010年學術文章
@zh-hant
name
A highly reactive rhodium
@nl
A highly reactive rhodium(I)-b ...... catalytic C-F bond borylation.
@en
type
label
A highly reactive rhodium
@nl
A highly reactive rhodium(I)-b ...... catalytic C-F bond borylation.
@en
prefLabel
A highly reactive rhodium
@nl
A highly reactive rhodium(I)-b ...... catalytic C-F bond borylation.
@en
P2860
P356
P1476
A highly reactive rhodium(I)-b ...... catalytic C-F bond borylation.
@en
P2093
Michael Teltewskoi
Thomas Braun
P2860
P304
P356
10.1002/ANIE.201001070
P407
P577
2010-05-01T00:00:00Z