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A macrocyclic approach to transition metal and uranyl Pacman complexes.Metal-ligand multiple bonding in uranium: structure and reactivity.New reactivity of the uranyl(VI) ion.Ligand size dependence of U-N and U-O bond character in a series of uranyl hexaphyrin complexes: quantum chemical simulation and density based analysis.Subtle Interactions and Electron Transfer between U(III) , Np(III) , or Pu(III) and Uranyl Mediated by the Oxo Group.Relativistic DFT and experimental studies of mono- and bis-actinyl complexes of an expanded Schiff-base polypyrrole macrocycle.Uranium-mediated activation of small molecules.Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin.Crystal structure of [UO2(NH3)5]NO3·NH3.Metathesis of a UV imido complex: a route to a terminal UV sulfide.Cation-cation complexes of pentavalent uranyl: from disproportionation intermediates to stable clusters.Stabilising pentavalent actinides--visible-near infrared and X-ray absorption spectroscopic studies of the utility of the [(Np3W4O15)(H2O)3(MW9O33)3]18- (M = Sb, Bi) structural type.Oxo-group-14-element bond formation in binuclear uranium(V) Pacman complexes.Isolation of a Star-Shaped Uranium(V/VI) Cluster from the Anaerobic Photochemical Reduction of Uranyl(VI).Synthesis and electronic structure determination of uranium(vi) ligand radical complexes.Axially Symmetric U-O-Ln- and U-O-U-Containing Molecules from the Control of Uranyl Reduction with Simple f-Block Halides.Theoretical exploration of uranyl complexes of a designed polypyrrolic macrocycle: structure/property effects of hinge size on Pacman-shaped complexes.[UO2(NH3)5]Br2·NH3: synthesis, crystal structure, and speciation in liquid ammonia solution by first-principles molecular dynamics simulations.Insights into uranyl chemistry from molecular dynamics simulations.Density functional theory and molecular dynamics study of the uranyl ion (UO₂)²⁺.Reliable modeling of the electronic spectra of realistic uranium complexes.A Mixed-Valent Uranium Phosphonate Framework Containing U(IV) , U(V) , and U(VI).Schiff base thorium(iv) and uranium(iv) chloro complexes: synthesis, substitution and oxidation chemistry.Synthesis and SMM behaviour of trinuclear versus dinuclear 3d-5f uranyl(v)-cobalt(ii) cation-cation complexes.Theoretical investigation of low-valent uranium and transuranium complexes of a flexible small-cavity macrocycle: structural, formation reaction and redox properties.Facile Reductive Silylation of UO22+ to Uranium(IV) Chloride.Axially Symmetric U−O−Ln- and U−O−U-Containing Molecules from the Control of Uranyl Reduction with Simple f-Block HalidesSingle-Electron Uranyl Reduction by a Rare-Earth CationThe Effect of the Equatorial Environment on Oxo-Group Silylation of the Uranyl Dication: A Computational StudySynthesis and Characterization of the First 2 D Neptunyl Structure Stabilized by Side-on Cation-Cation Interactions
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description
im August 2009 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована в серпні 2009
@uk
name
Pentavalent uranyl complexes
@en
Pentavalent uranyl complexes
@nl
type
label
Pentavalent uranyl complexes
@en
Pentavalent uranyl complexes
@nl
prefLabel
Pentavalent uranyl complexes
@en
Pentavalent uranyl complexes
@nl
P1476
Pentavalent uranyl complexes
@en
P2093
Dipti Patel
Jason B. Love
P304
P356
10.1016/J.CCR.2009.03.014
P50
P577
2009-08-01T00:00:00Z