Thermal, Catalytic, Regiospecific Functionalization of Alkanes
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Selective oxidation of carbolide C-H bonds by an engineered macrolide P450 mono-oxygenaseUnderstanding and exploiting C-H bond activation.Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between theory and experimentSigma-chelation-directed C-H functionalizations using Pd(II) and Cu(II) catalysts: regioselectivity, stereoselectivity and catalytic turnover.Multimetallic catalysed radical oxidative C(sp(3))-H/C(sp)-H cross-coupling between unactivated alkanes and terminal alkynes.Regioselectivity of the borylation of alkanes and arenes.Transition-metal-catalyzed C-C bond formation through the fixation of carbon dioxide.If C-H bonds could talk: selective C-H bond oxidationMicrowave-assisted C-C bond forming cross-coupling reactions: an overview.Homogeneous photocatalytic reactions with organometallic and coordination compounds--perspectives for sustainable chemistry.Indenylmetal Catalysis in Organic Synthesis.Acylboranes: synthetic strategies and applications.The chemistry of organoimido derivatives of polyoxometalates.Ligand-Promoted Borylation of C(sp(3))-H Bonds with Palladium(II) Catalysts.Strain release in C-H bond activation?Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolboraneA multi-component domino reaction for the direct access to polyfunctionalized indoles via intermolecular allylic esterification and indolation.Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions.A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)]Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes.Chemo-, regio-, and stereoselective iron-catalysed hydroboration of alkenes and alkynes.Iridium-catalyzed triple C(sp3)-H borylations: construction of triborylated sp3-carbon centers.Iron-catalyzed, atom-economical, chemo- and regioselective alkene hydroboration with pinacolborane.Mechanism, reactivity, and selectivity of the iridium-catalyzed C(sp3)-H borylation of chlorosilanes.Mechanistic study on the cleavage and reorganization of C(sp3)-H and C=N bonds in carbodiimides: synthesis of 1,2-dihydrothiopyrimidines and 2,3-dihydropyrimidinthiones through four-component coupling.Theoretical study of reaction pathways for the rhodium phosphine-catalysed borylation of C-H bonds with pinacolborane.Photochemical reactions of [CH2(eta5-C5H4)2][Rh(C2H4)2]2 with silanes: evidence for Si-C and C-H activation pathways.Enantioselective Borylation of Aromatic C-H Bonds with Chiral Dinitrogen Ligands.Frustrated Lewis Pair Mediated Csp3 -H Activation.The synthesis and structure of [Zn(TEMPO)2]2 and [Zn(μ-H)(μ(2)-η(1):η(1)-TEMPO)]6.Thermal C-H borylation using a CO-free iron boryl complex.Amino-directed Rh(III)-catalyzed C-H activation leading to one-pot synthesis of N-H carbazoles.Stereoselective C-H borylations of cyclopropanes and cyclobutanes with silica-supported monophosphane-Ir catalysts.Metal-Free Arene and Heteroarene Borylation Catalyzed by Strongly Electrophilic Bis-boranes.Copper-Catalyzed Alkynylboration of Alkenes with Diboron Reagents and Bromoalkynes.Silver-catalysed direct amination of unactivated C-H bonds of functionalized molecules.Direct borylation of primary C-H bonds in functionalized molecules by palladium catalysis.Palladium-catalyzed monoselective C-H borylation of acetanilides under acidic conditions.Alkylboronic esters from copper-catalyzed borylation of primary and secondary alkyl halides and pseudohalides.Direct cross-coupling of C-H bonds with Grignard reagents through cobalt catalysis.
P2860
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P2860
Thermal, Catalytic, Regiospecific Functionalization of Alkanes
description
article publié dans la revue scientifique Science
@fr
im März 2000 veröffentlichter wissenschaftlicher Artikel
@de
scientific article published in Science
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована в березні 2000
@uk
name
Thermal, Catalytic, Regiospecific Functionalization of Alkanes
@en
Thermal, Catalytic, Regiospecific Functionalization of Alkanes
@nl
type
label
Thermal, Catalytic, Regiospecific Functionalization of Alkanes
@en
Thermal, Catalytic, Regiospecific Functionalization of Alkanes
@nl
prefLabel
Thermal, Catalytic, Regiospecific Functionalization of Alkanes
@en
Thermal, Catalytic, Regiospecific Functionalization of Alkanes
@nl
P2093
P1433
P1476
Thermal, catalytic, regiospecific functionalization of alkanes
@en
P2093
P304
P356
10.1126/SCIENCE.287.5460.1995
P407
P577
2000-03-01T00:00:00Z