Scales of Nucleophilicity and Electrophilicity: A System for Ordering Polar Organic and Organometallic Reactions
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Electrophilicity versus electrofugality of tritylium ions in aqueous acetonitrile.Generation of α,β-unsaturated iminium ions by laser flash photolysis.Characterization of the nucleophilic reactivities of thiocarboxylate, dithiocarbonate and dithiocarbamate anions.The efficiency of the metal catalysts in the nucleophilic substitution of alcohols is dependent on the nucleophile and not on the electrophile.Farewell to the HSAB treatment of ambident reactivity.Synergy, compatibility, and innovation: merging Lewis acids with stereoselective enamine catalysis.Molecular features in complex environment: Cooperative team players during excited state bond cleavageCarbonylmetallates--A Special Family of Nucleophiles in Aromatic and Vinylic Substitution Reactions.Stereospecific functionalizations and transformations of secondary and tertiary boronic esters.Direct Substitution of Alcohols in Pure Water by Brønsted Acid Catalysis.A quantitative approach to polar organic reactivity.Umpolung reactivity of indole through gold catalysis.On the electrophilic character of molecules through its relation with electronegativity and chemical hardness.Mechanism of Electrophilic Fluorination with Pd(IV): Fluoride Capture and Subsequent Oxidative Fluoride Transfer(.)Kinetic evidence for the formation of oxazolidinones in the stereogenic step of proline-catalyzed reactions.Organocatalytic stereoselective alpha-alkylation of aldehydes with stable carbocations.The Diels-Alder reaction of 4,6-dinitrobenzofuroxan with 1-trimethylsilyloxybuta-1,3-diene: a case example of a stepwise cycloaddition.Annelated pyridines as highly nucleophilic and Lewis basic catalysts for acylation reactions.Catalytic asymmetric [3+2] annulation of allylsilanes with isatins: synthesis of spirooxindoles.The Nucleophilicity of Persistent α-Monofluoromethide Anions.Steric, hydrogen-bonding and structural heterogeneity effects on the nucleophilic substitution of N-(p-fluorophenyldiphenylmethyl)-4-picolinium chloride in ionic liquids.Directed electrostatic activation in enantioselective organocatalytic cyclopropanation reactions: a computational study.On the intrinsic reactivity index for electrophilicity/nucleophilicity responses.Solvation Accounts for the Counterintuitive Nucleophilicity Ordering of Peroxide Anions.On Atoms-in-Molecules Energies from Kohn-Sham Calculations.Electronic forces as descriptors of nucleophilic and electrophilic regioselectivity and stereoselectivity.Visible-Light-Mediated [4+2] Cycloaddition of Styrenes: Synthesis of Tetralin Derivatives.Herbert Mayr.From carbanions to organometallic compounds: quantification of metal ion effects on nucleophilic reactivities.Pioneering Metal-Free Oxidative Coupling Strategy of Aromatic Compounds Using Hypervalent Iodine Reagents.Quantifying electro/nucleophilicity by partitioning the dual descriptor.Highly Functionalized Cyclopentane Derivatives by Tandem Michael Addition/Radical Cyclization/Oxygenation Reactions.C-C Coupling Reactions between Benzofurazan Derivatives and 1,3-Diaminobenzenes.Nucleophilicity parameters for amines, amino acids and peptides in water. Variations in selectivities for quinone methides.Autoinduced catalysis and inverse equilibrium isotope effect in the frustrated Lewis pair catalyzed hydrogenation of imines.Limitations of the s(E+N) and related equations: solvent dependence of electrophilicity.1,2,4-Dithiazole-5-ones and 5-thiones as efficient sulfurizing agents of phosphorus(III) compounds--a kinetic comparative study.The effect of backbone flexibility on site-selective modification of macrocycles.Exploration of Quantitative StructureReactivity Relationships for the Estimation ofMayrNucleophilicitySolvatation als Ursache für die unerwartete Nucleophilie-Reihung von Peroxid-Anionen
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P2860
Scales of Nucleophilicity and Electrophilicity: A System for Ordering Polar Organic and Organometallic Reactions
description
article
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована в травні 1994
@uk
ലേഖനം
@ml
name
Scales of Nucleophilicity and ...... c and Organometallic Reactions
@en
Scales of Nucleophilicity and ...... c and Organometallic Reactions
@nl
type
label
Scales of Nucleophilicity and ...... c and Organometallic Reactions
@en
Scales of Nucleophilicity and ...... c and Organometallic Reactions
@nl
prefLabel
Scales of Nucleophilicity and ...... c and Organometallic Reactions
@en
Scales of Nucleophilicity and ...... c and Organometallic Reactions
@nl
P356
P1476
Scales of Nucleophilicity and ...... c and Organometallic Reactions
@en
P2093
Herbert Mayr
Matthias Patz
P304
P356
10.1002/ANIE.199409381
P407
P577
1994-05-18T00:00:00Z