Switching radical stability by pH-induced orbital conversion
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Theory and practice of uncommon molecular electronic configurationsDissociation Behavior of a TEMPO-Active Ester Cross-Linker for Peptide Structure Analysis by Free Radical Initiated Peptide Sequencing (FRIPS) in Negative ESI-MS.Enhancing the Oxidation of Toluene with External Electric Fields: a Reactive Molecular Dynamics StudyComputational electrochemistry: prediction of liquid-phase reduction potentials.Oriented electric fields as future smart reagents in chemistry.Photodissociation of TEMPO-modified peptides: new approaches to radical-directed dissociation of biomolecules.In vitro studies to assess the antioxidative, radical scavenging and arginase inhibitory potentials of extracts from Artocarpus altilis, Ficus exasperate and Kigelia africana.Proton transfer induced SOMO-to-HOMO level switching in one-electron oxidized A-T and G-C base pairs: a density functional theory study.Reactive intermediates: radicals with multiple personalities.SOMO-HOMO Level Inversion In Biologically Important Radicals.Computational design of pH-switchable control agents for nitroxide mediated polymerization.Electrostatic catalysis of a Diels-Alder reaction.Can electrostatic catalysis of Diels-Alder reactions be harnessed with pH-switchable charged functional groups?Effect of heteroatom and functionality substitution on the oxidation potential of cyclic nitroxide radicals: role of electrostatics in electrochemistry.Unimolecular reaction chemistry of a charge-tagged beta-hydroxyperoxyl radical.Dissociative electron transfer to diphenyl-substituted bicyclic endoperoxides: the effect of molecular structure on the reactivity of distonic radical anions and determination of thermochemical parameters.Experimental demonstration of pH-dependent electrostatic catalysis of radical reactions.
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P2860
Switching radical stability by pH-induced orbital conversion
description
im April 2013 veröffentlichter wissenschaftlicher Artikel
@de
scientific article published on 21 April 2013
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована у квітні 2013
@uk
name
Switching radical stability by pH-induced orbital conversion
@en
Switching radical stability by pH-induced orbital conversion
@nl
type
label
Switching radical stability by pH-induced orbital conversion
@en
Switching radical stability by pH-induced orbital conversion
@nl
prefLabel
Switching radical stability by pH-induced orbital conversion
@en
Switching radical stability by pH-induced orbital conversion
@nl
P2860
P50
P356
P1433
P1476
Switching radical stability by pH-induced orbital conversion
@en
P2093
David L. Marshall
Stephen J. Blanksby
P2860
P2888
P304
P356
10.1038/NCHEM.1625
P577
2013-04-21T00:00:00Z