Selective P4 activation by an organometallic nickel(i) radical: formation of a dinuclear nickel(ii) tetraphosphide and related di- and trichalcogenides
about
Complexes of Ni(i): a "rare" oxidation state of growing importance.Persistent four-coordinate iron-centered radical stabilized by π-donation.[Ni(cod)2][Al(OR(F))4], a Source for Naked Nickel(I) ChemistryMetalate-Mediated Functionalization of P4 by Trapping Anionic [Cp*Fe(CO)2(η1-P4)]- with Lewis Acids.Activation of white phosphorus by low-valent group 5 complexes: formation and reactivity of cyclo-P4 inverted sandwich compounds.Kinetic Destabilization of Metal-Metal Single Bonds: Isolation of a Pentacoordinate Manganese(0) Monoradical.Synthesis and Reactivity of Nickel-Stabilised μ2 :η2 ,η2 -P2 , As2 and PAs Units.Tuning the overpotential of electrocatalytically active cyclopentadienylnickel complexes containing 1,4-diaza-1,3-butadienes (DAB) for proton reduction.Bi-P Bond Homolysis as a Route to Reduced Bismuth Compounds and Reversible Activation of P4.Selective P4 Activation by a Highly Reduced Cobaltate: Synthesis of Dicobalt Tetraphosphido Complexes.Cp*Co(IPr): synthesis and reactivity of an unsaturated Co(i) complex.Redox-active ligand-induced homolytic bond activation.Stabilization and Transfer of the Transient [Mes*P4](-) Butterfly Anion Using BPh3.Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P3 Complexes.Axially chiral racemic half-sandwich nickel(ii) complexes by ring-closing metathesis.Cp(PEt)2 As4 -An Organic-Substituted As4 Butterfly Compound.Insertion of phenyl isothiocyanate into a P-P bond of a nickel-substituted bicyclo[1.1.0]tetraphosphabutane.Selective [3+1] Fragmentations of P4 by "P" Transfer from a Lewis Acid Stabilized [RP4 ]- Butterfly Anion.Synthese und Reaktivität von Nickel-stabilisierten μ2 :η2 ,η2 -P2 -, As2 - und PAs-Einheiten
P2860
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P2860
Selective P4 activation by an organometallic nickel(i) radical: formation of a dinuclear nickel(ii) tetraphosphide and related di- and trichalcogenides
description
article
@en
im Januar 2014 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована у 2014
@uk
ലേഖനം
@ml
name
Selective P4 activation by an organometallic nickel
@nl
Selective P4 activation by an ...... lated di- and trichalcogenides
@en
type
label
Selective P4 activation by an organometallic nickel
@nl
Selective P4 activation by an ...... lated di- and trichalcogenides
@en
prefLabel
Selective P4 activation by an organometallic nickel
@nl
Selective P4 activation by an ...... lated di- and trichalcogenides
@en
P2093
P2860
P356
P1476
Selective P4 activation by an ...... lated di- and trichalcogenides
@en
P2093
Dirk Herrmann
František Hartl
Stefan Pelties
P2860
P304
P356
10.1039/C4CC02601B
P407
P577
2014-01-01T00:00:00Z