about
Off-line reaction monitoring of the oxidation of alkenes in water using drop coating deposition Raman (DCDR) spectroscopy.Ligand exchange and spin state equilibria of Fe(II)(N4Py) and related complexes in aqueous media.Reactivity of a Nickel(II) Bis(amidate) Complex with meta-Chloroperbenzoic Acid: Formation of a Potent Oxidizing Species.Transient Formation and Reactivity of a High-Valent Nickel(IV) Oxido ComplexIdentification and spectroscopic characterization of nonheme iron(III) hypochlorite intermediates.Novel artificial metalloenzymes by in vivo incorporation of metal-binding unnatural amino acids.Binding of copper(II) polypyridyl complexes to DNA and consequences for DNA-based asymmetric catalysis.Reinvestigating 2,5-di(pyridin-2-yl)pyrazine ruthenium complexes: selective deuteration and Raman spectroscopy as tools to probe ground and excited-state electronic structure in homo- and heterobimetallic complexes.Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds.Direct photochemical activation of non-heme Fe(iv)[double bond, length as m-dash]O complexes.Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with FeV═O and FeIV═O Units.Rapid Hydrogen and Oxygen Atom Transfer by a High-Valent Nickel-Oxygen Species.Conflicting Role of Water in the Activation of H2O2 and the Formation and Reactivity of Non-Heme Fe(III)-OOH and Fe(III)-O-Fe(III) Complexes at Room Temperature.Spectroscopic Analyses on Reaction Intermediates Formed during Chlorination of Alkanes with NaOCl Catalyzed by a Nickel Complex.Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands.On the Lewis Acidity of the Oxoiron(IV) Unit in a Tetramethylcyclam Complex.Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III).Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-oxo Intermediate.Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases.A Non-Heme Iron Photocatalyst for Light-Driven Aerobic Oxidation of Methanol.Characterisation of the interactions between substrate, copper(II) complex and DNA and their role in rate acceleration in DNA-based asymmetric catalysis.Photo-induced oxidation of [Fe(II)(N4Py)CH3CN] and related complexes.H2O2 Oxidation by FeIII–OOH Intermediates and Its Effect on Catalytic EfficiencyAn Electrochemical and Raman Spectroscopy Study of the Surface Behaviour of Mononuclear Ruthenium and Osmium Polypyridyl Complexes Based on Pyridyl- and Thiophene-Based LinkersFacile Conversion of syn -[FeIV (O)(TMC)]2+ into the anti Isomer via Meunier's Oxo-Hydroxo Tautomerism MechanismA Non-Heme Iron Photocatalyst for Light-Driven Aerobic Oxidation of MethanolDinuclear compounds without a metal–metal bond. Dirhodium(III,III) carboxamidatesSpectroscopy, photophysics and structural dynamics in metal‐centred species, some recent investigations: from spin‐crossover complexes and oxygen activation to photocatalysisUnexpected reversible pyrazine based methylation in a Ru(ii) complex bearing a pyrazin-2′-yl-1,2,4-triazolato ligand and its effect on acid/base and photophysical propertiesCrystallographic Evidence for a Sterically Induced Ferryl Tilt in a Non-Heme Oxoiron(IV) Complex that Makes it a Better OxidantCrystallographic Evidence for a Sterically Induced Ferryl Tilt in a Non-Heme Oxoiron(IV) Complex that Makes it a Better OxidantSc (or HClO) Activation of a Nonheme Fe-OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and BenzeneFacile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III)Sc3+-Promoted O-O Bond Cleavage of a (μ-1,2-Peroxo)diiron(III) Species Formed from an Iron(II) Precursor and O2 to Generate a Complex with an FeIV2(μ-O)2 CoreAcid pKa Dependence in O-O Bond Heterolysis of a Nonheme FeIII-OOH Intermediate To Form a Potent FeV═O Oxidant with Heme Compound I-Like ReactivityNMR Reveals That a Highly Reactive Nonheme FeIV =O Complex Retains Its Six-Coordinate Geometry and S=1 State in SolutionSpectroscopic and Reactivity Comparisons between Nonheme Oxoiron(IV) and Oxoiron(V) Species Bearing the Same Ancillary Ligand
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P50
description
researcher
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wetenschapper
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հետազոտող
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Apparao Draksharapu
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Apparao Draksharapu
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Apparao Draksharapu
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Apparao Draksharapu
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Apparao Draksharapu
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Apparao Draksharapu
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Apparao Draksharapu
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Apparao Draksharapu
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Apparao Draksharapu
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Apparao Draksharapu
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Apparao Draksharapu
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Apparao Draksharapu
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P106
P1153
55386770700
P21
P31
P496
0000-0001-7897-3230