The search for larger and more weakly coordinating anions
about
Carboranes in the chemist's toolbox.Palladium, iridium and ruthenium complexes with acyclic imino-N-heterocyclic carbenes and their application in aqua-phase Suzuki-Miyaura cross-coupling reaction and transfer hydrogenation.Lead(II) tetrafluoroborate and hexafluorophosphate complexes with crown ethers, mixed O/S- and O/Se-donor macrocycles and unusual [BF(4)](-) and [PF(6)](-) coordination.Synthesis and properties of the tetrakis(trifluoromethyl)borate anion, [b(CF3)4]-: structure determination of Cs[B(CF3)4] by single-crystal X-ray diffraction.Organometallic complexes as anion hosts.Simple modification of basic dyes with bulky &symmetric WCAs for improving their solubilities in organic solvents without color change.Solution-phase counterion effects in supramolecular and mechanostereochemical systems.Organometallic synthesis, reactivity and catalysis in the solid state using well-defined single-site speciesReactive p-block cations stabilized by weakly coordinating anions.Tetracyanido(difluorido)phosphates M(+) [PF2 (CN)4 ](.).An Icosidodecahedral Supramolecule Based on Pentaphosphaferrocene: From a Disordered Average Structure to Individual Isomers.Phase behaviour and conductivity study on multi-component mixtures for electrodeposition in supercritical fluids.The stable pentamethylcyclopentadienyl cation.Pseudohalonium ions: [Me3Si-X-SiMe3]+ (X=CN, OCN, SCN, and NNN).Quantum-chemical and electrochemical investigation of the electrochemical windows of halogenated carborate anions.Reductive degradation of nido-1-CB8H12 into smaller-cage carborane systems via new monocarbaboranes [arachno-5-CB8H13](-) and closo-2-CB6H8.Synthesis of a [2]catenane from the sodium ion templated orthogonal arrangement of two diethylene glycol chains.H(OEt2)2[P(1,2-O2C6Cl4)3]: synthesis, characterization, and application as a single-component initiator for the carbocationic polymerization of olefins.Synthesis, photochromic, and computational studies of dithienylethene-containing β-diketonate derivatives and their near-infrared photochromic behavior upon coordination of a boron(III) center.A systematic investigation of coinage metal carbonyl complexes stabilized by fluorinated alkoxy aluminates.Coordination and extraction of mercury(II) with an ionic liquid-based thione extractant.Exploration of the pentacyano-cyclo-pentadienide ion, C(5)(CN)(5)(-), as a weakly coordinating anion and potential superacid conjugate base. Silylation and protonation.Imidazolinium salts as catalysts for the aza-Diels-Alder reaction.Cationic fac-tris(pyrazole) complexes as anion receptors.An anionic microporous polymer network prepared by the polymerization of weakly coordinating anions.Chemisorption of exchange-coupled [Ni2L(dppba)]+ complexes on gold by using ambidentate 4-(diphenylphosphino)benzoate co-ligands.Weakly coordinating counter-ions for highly efficient catalysis of intramolecular hydroamination.Zwitterionic stabilization of a reactive cobalt tris-isocyanide monoanion by cation coordination.Copper(i) complexes based on ligand systems with two different binding sites: synthesis, structures and reaction with O2.Teaching old compounds new tricks: efficient N2 fixation by simple Fe(N2)(diphosphine)2 complexes.Unique Group 1 cations stabilised by homoleptic neutral phosphine coordination.Highly stereoselective β-mannopyranosylation via the 1-α-glycosyloxy-isochromenylium-4-gold(I) intermediates.Second-sphere interaction of anions with a weakly binding metal complex host: probing the effect of counteranions.Molecular structure and stability of dissolved lithium polysulfide species.Tuning ground states of bis(triarylamine) dications: from a closed-shell singlet to a diradicaloid with an excited triplet state.Difunctionalized {closo-1-CB11 } clusters: 1- and 2-amino-12-ethynylcarba-closo-dodecaborates.The impact of ionic liquids on the coordination of anions with solvatochromic copper complexes.Interlocked Photo-degradable Macrocycles Allow One-Off Photo-triggerable Gelation of Organo- and Hydrogelators.Controlling ligand binding for tunable and switchable catalysis: cation-modulated hemilability in pincer-crown ether ligands.Gold(I)-Catalysed Asymmetric Hydroamination of Alkenes: A Silver- and Solvent-Dependent Enantiodivergent Reaction.
P2860
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P2860
The search for larger and more weakly coordinating anions
description
im Mai 1993 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована в травні 1993
@uk
name
The search for larger and more weakly coordinating anions
@en
The search for larger and more weakly coordinating anions
@nl
type
label
The search for larger and more weakly coordinating anions
@en
The search for larger and more weakly coordinating anions
@nl
prefLabel
The search for larger and more weakly coordinating anions
@en
The search for larger and more weakly coordinating anions
@nl
P356
P1433
P1476
The search for larger and more weakly coordinating anions
@en
P2093
Steven H. Strauss
P304
P356
10.1021/CR00019A005
P577
1993-05-01T00:00:00Z