Nucleophilic Chiral Amines as Catalysts in Asymmetric Synthesis
about
The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Comparative study of various normal mode analysis techniques based on partial Hessians.Asymmetric Organocatalysis: The Emerging Utility of α,β-Unsaturated Acylammonium Salts.Enantioselective TADMAP-catalyzed carboxyl migration reactions for the synthesis of stereogenic quaternary carbonAsymmetric synthesis of nonracemic primary amines via spiroborate-catalyzed reduction of pure (E)- and (Z)-O-benzyloximes: applications toward the synthesis of calcimimetic agents.AcOLeDMAP and BnOLeDMAP: conformationally restricted nucleophilic catalysts for enantioselective rearrangement of indolyl acetates and carbonates.Highly enantioselective borane reduction of heteroaryl and heterocyclic ketoxime ethers catalyzed by novel spiroborate ester derived from diphenylvalinol: application to the synthesis of nicotine analogues.Bifunctional asymmetric catalysis: cooperative Lewis acid/base systems.Enantioselective nucleophilic catalysis: the synthesis of aza-beta-lactams through [2+2] cycloadditions of ketenes with azo compounds.Catalytic asymmetric synthesis of all-carbon quaternary stereocentersRecent advances in enantioselective organocatalyzed anhydride desymmetrization and its application to the synthesis of valuable enantiopure compounds.Increasing the reactivity of nitrogen catalysts.Low-loading asymmetric organocatalysis.Asymmetric organocatalysis at the service of medicinal chemistryJourney Heading Towards Enantioselective Synthesis Assisted by Organocatalysis.Catalytic Asymmetric Synthesis of Butenolides and Butyrolactones.Rapid assembly of complex cyclopentanes employing chiral, α,β-unsaturated acylammonium intermediates.A case of remote asymmetric induction in the peptide-catalyzed desymmetrization of a bis(phenol).Enantioselective synthesis of alpha,alpha-disubstituted cyclopentenes by an N-heterocyclic carbene-catalyzed desymmetrization of 1,3-diketonesEnantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies.Synthesis of Enantioenriched α,α-Disubstituted Cyclopentenes Catalyzed by N-Heterocyclic Carbenes.A case study of the mechanism of alcohol-mediated Morita Baylis-Hillman reactions. The importance of experimental observationsCatalytic, asymmetric reactions of ketenes and ketene enolates.Site-selective catalysis of phenyl thionoformate transfer as a tool for regioselective deoxygenation of polyols.Stereoselective cathodic synthesis of 8-substituted (1R,3R,4S)-menthylamines.Chiral bifunctional phase transfer catalysts for asymmetric fluorination of beta-keto esters.Organocatalytic synthesis of highly functionalized pyridines at room temperature.Inner workings of a cinchona alkaloid catalyzed oxa-Michael cyclization: evidence for a concerted hydrogen-bond-network mechanism.Kinetic resolution of tertiary alcohols: highly enantioselective access to 3-hydroxy-3-substituted oxindoles.Kinetic resolution of sec-alcohols using a new class of readily assembled (S)-proline-derived 4-(pyrrolidino)-pyridine analogues.Desymmetrization of 4,6-diprotected myo-inositol.Application of a Palladium-Catalyzed C-H Functionalization/Indolization Method to Syntheses of cis-Trikentrin A and Herbindole B.A simple method for the alpha-oxygenation of aldehydes.Direct catalytic asymmetric synthesis of N-heterocycles from commodity acid chlorides by employing α,β-unsaturated acylammonium salts.Gold(I)-catalyzed asymmetric desymmetrization of meso-alkynyl diols and kinetic resolution of the corresponding DL-diols: effects of celite filtration and silver salts.Kinetic Resolution of 2-Substituted Indolines by N-Sulfonylation using an Atropisomeric 4-DMAP-N-oxide Organocatalyst.Toward Fluorescence-Based High-Throughput Screening for Enantiomeric Excess in Amines and Amino Acid Derivatives.Nucleophilic β-Carbon Activation of Propionic Acid as a 3-Carbon Synthon by Carbene Organocatalysis.Enzymatic synthesis of L-norephedrine by coupling recombinant pyruvate decarboxylase and ω-transaminase.Asymmetric [4+2] Annulation of C1 Ammonium Enolates with Copper-Allenylidenes.
P2860
Q33797639-DE17A75C-F5AF-4C5B-920B-0519784C9BB1Q34576405-258D81B9-0B3C-49B5-A914-FFB3ED56CC58Q36138930-F80A4763-F994-48D4-A814-1ED8857763ECQ36867843-99741E49-8DB9-46C2-87AB-65F4CB985FBCQ37000185-41FA2A73-EBFA-4ED5-B377-D27F89F30606Q37133211-5D6F1DB8-0D87-4DFD-820A-6CA74F795099Q37239443-FC012266-2FEE-4D73-97BE-BC85811CC220Q37417214-A133F32E-F7CD-4C81-881F-6D84B1DE40BBQ37464343-E4FA01BB-639A-429E-AE7A-F6D015E7A36FQ37681301-519CD24A-3BC8-4D14-8275-C6179BCB7334Q37898012-ECB77B7B-9F56-4E46-AC70-6D93E4A7DDEDQ37947516-1BFB4ED7-F412-4353-80B1-9A5A157A8F2DQ37968170-616AE7F3-1159-44A9-B577-F5B7DE80BECDQ38223762-E9693979-A7DA-4F61-8F9A-9980EC3BF040Q38556808-8F434391-FDE6-44EC-ADCF-84C1C264C24EQ39391118-7F137881-EBA2-4D5B-8A3A-BFC7EB154692Q41300520-4CE69734-7C8E-42B4-8F64-A3F0FFAEDD03Q41927255-70F269CC-C3A4-4CA2-A544-DA5538CA661FQ42066623-A35C9C72-5363-439D-9E11-F57AA0135FE7Q42182848-F717C03B-1FED-4428-9AEE-2DFBC5B24421Q42363839-ECC9354A-B67E-433B-88B7-F50E67F2D03FQ42664684-AF1EE219-D76C-4458-A8BA-502106C299DEQ42714607-9C657BC3-C194-4716-AAAC-047455369E48Q42934419-E10C6DD4-0281-4165-A1D4-776CBE6AAB0BQ43188920-E4626A7E-4BC4-4946-98DE-2CBF960663F8Q43213666-B0F854E7-AE25-4E47-8E7B-2AEE52EAF617Q43417879-C3E90756-4ED8-4E47-830F-7581B00C382AQ43813751-7416A46C-3FF8-42C9-B4F0-65534D6548AAQ45159320-87C6639F-268E-415E-AAB9-2DFF6289291EQ45306150-D4E88C46-B88C-4651-A974-562C11E74AE4Q45826016-10CBEEEF-A25A-49FF-AEB8-C3360EAE2C9DQ46000420-333C121F-D569-4E48-B1F3-E4FC7D3C81E9Q46366175-3407C170-2649-4FD6-9D44-C2AB0FC24491Q46568743-E47A48A5-7452-4ED0-BCCB-7325622FC567Q46778792-14884B01-42D7-40F8-A4F9-FE24C69E128CQ47566197-C9048276-A5BE-4278-961E-3CB534379EB5Q50226428-25975ABA-9D9A-4AC1-AD28-089C97528964Q50272715-1B7A167C-2A88-46B0-A375-88038A62C1BBQ50456490-C778E27A-BD9C-4B50-B9E9-C5F651513509Q50933893-B0A150F4-C28E-416E-B548-A51051862DFF
P2860
Nucleophilic Chiral Amines as Catalysts in Asymmetric Synthesis
description
article
@en
im August 2003 veröffentlichter wissenschaftlicher Artikel
@de
wetenschappelijk artikel
@nl
наукова стаття, опублікована в серпні 2003
@uk
name
Nucleophilic Chiral Amines as Catalysts in Asymmetric Synthesis
@en
Nucleophilic Chiral Amines as Catalysts in Asymmetric Synthesis
@nl
type
label
Nucleophilic Chiral Amines as Catalysts in Asymmetric Synthesis
@en
Nucleophilic Chiral Amines as Catalysts in Asymmetric Synthesis
@nl
prefLabel
Nucleophilic Chiral Amines as Catalysts in Asymmetric Synthesis
@en
Nucleophilic Chiral Amines as Catalysts in Asymmetric Synthesis
@nl
P2093
P356
P1433
P1476
Nucleophilic chiral amines as catalysts in asymmetric synthesis
@en
P2093
David J Guerin
Stefan France
Thomas Lectka
P304
P356
10.1021/CR020061A
P577
2003-08-01T00:00:00Z