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Chiral gold(I) vs chiral silver complexes as catalysts for the enantioselective synthesis of the second generation GSK-hepatitis C virus inhibitor.Stereodivergent synthesis of chiral fullerenes by [3 + 2] cycloadditions to C₆₀.Synthetic scope and DFT analysis of the chiral binap-gold(I) complex-catalyzed 1,3-dipolar cycloaddition of azlactones with alkenes.Concerted and stepwise mechanisms in metal-free and metal-assisted [4+3] cycloadditions involving allyl cations.Aggregation and cooperative effects in the aldol reactions of lithium enolates.Mono- and Di-Alkylation Processes of DNA Bases by Nitrogen Mustard Mechlorethamine.New Insights into the Reactivity of Cisplatin with Free and Restrained Nucleophiles: Microsolvation Effects and Base Selectivity in Cisplatin-DNA Interactions.Catalysis of a 1,3-dipolar reaction by distorted DNA incorporating a heterobimetallic platinum(ii) and copper(ii) complex.Intramolecular SE Ar Reactions of Phosphorus Compounds: Computational Approach to the Synthesis of π-Extended Heterocycles.Diastereoselective [3 + 2] vs [4 + 2] Cycloadditions of Nitroprolinates with α,β-Unsaturated Aldehydes and Electrophilic Alkenes: An Example of Total Periselectivity.Alkenyl Arenes as Dipolarophiles in Catalytic Asymmetric 1,3-Dipolar Cycloaddition Reactions of Azomethine Ylides.Ion-Pair SN 2 Substitution: Activation Strain Analyses of Counter-Ion and Solvent Effects.A Three-Component Enantioselective Cyclization Reaction Catalyzed by an Unnatural Amino Acid Derivative.Ion-Pair SN2 Reaction of OH- and CH3Cl: Activation Strain analyses of Counterion and Solvent Effects.Enantioselective Synthesis of Polysubstituted Spiro-nitroprolinates Mediated by a (R,R)-Me-DuPhos·AgF-Catalyzed 1,3-Dipolar Cycloaddition.Synthesis and Structure of a Base-Stabilized C-Phosphino-Si-Amino SilyneA Cationic Rh(III) Complex That Efficiently Catalyzes Hydrogen Isotope Exchange in HydrosilanesAsymmetric identity S N 2 transition states: Nucleophilic substitution at α-substituted carbon and silicon centersCooperative Catalysis with Coupled Chiral Induction in 1,3-Dipolar Cycloadditions of Azomethine YlidesCyclopropanation reactions catalysed by dendrimers possessing one metalloporphyrin active site at the core: linear and sigmoidal kinetic behaviour for different dendrimer generationsRemote Substituent Effects on the Stereoselectivity and Organocatalytic Activity of Densely Substituted Unnatural Proline Esters in Aldol ReactionsDonor-Stabilized 1,3-Disila-2,4-diazacyclobutadiene with a Nonbonded Si⋅⋅⋅Si Distance Compressed to a Si=Si Double Bond LengthEffect of an α-Methyl Substituent on the Dienophile on Diels-Alder : SelectivityStereodivergent SN2@P Reactions of Borane Oxazaphospholidines: Experimental and Theoretical StudiesAn Amine-Catalyzed Enantioselective [3+2] Cycloaddition of Azomethine Ylides and α,β-Unsaturated Aldehydes: Applications and Mechanistic ImplicationsHierarchical Selectivity in Fullerenes: Site-, Regio-, Diastereo-, and Enantiocontrol of the 1,3-Dipolar Cycloaddition to C70On the stereodivergent behavior observed in the Staudinger reaction between methoxyketene and (E)-N-benzylidenearyl aminesBinap-gold(I) versus Binap-silver trifluoroacetate complexes as catalysts in 1,3-dipolar cycloadditions of azomethine ylidesInfluence of polarity on the scalability and reproducibility of solvent-free microwave-assisted reactionsSynthesis and characterization of metallodendritic palladium-biscarbene complexes derived from 1,1'-methylenebis(1,2,4-triazole)Stereocontrolled (3+2) cycloadditions between azomethine ylides and dipolarophiles: a fruitful interplay between theory and experimentReversible binding of ethylene to silylene-phosphine complexes at room temperatureAzobenzene-functionalized iridium(III) triscyclometalated complexesIs it possible to achieve a complete desaturation of cycloalkanes promoted by o-benzyne?Phosphoramidite-Cu(OTf)2 complexes as chiral catalysts for 1,3-dipolar cycloaddition of iminoesters and nitroalkenesSynthesis of radiolabelled aryl azides from diazonium salts: experimental and computational results permit the identification of the preferred mechanismDismantling the Hyperconjugation of π-Conjugated Phosphorus HeterocyclesSwitching Diastereoselectivity in Catalytic Enantioselective (3+2) Cycloadditions of Azomethine Ylides Promoted by Metal Salts and Privileged Segphos-Derived LigandsAlkaloids Reactivity: DFT Analysis of Selective Demethylation ReactionsSynthesis and reactivity of a phosphine-stabilized monogermanium analogue of alkynes
P50
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P50
description
onderzoeker
@nl
researcher, ORCID id # 0000-0001-8430-4076
@en
name
Abel de Cózar
@ast
Abel de Cózar
@en
Abel de Cózar
@nl
type
label
Abel de Cózar
@ast
Abel de Cózar
@en
Abel de Cózar
@nl
prefLabel
Abel de Cózar
@ast
Abel de Cózar
@en
Abel de Cózar
@nl
P106
P21
P31
P496
0000-0001-8430-4076