about
Luminescent Gold(III) Thiolates: Supramolecular Interactions Trigger and Control Switchable Photoemissions from Bimolecular Excited States.Solventless supramolecular chemistry via vapor diffusion of volatile small molecules upon a new trinuclear silver(I)-nitrated pyrazolate macrometallocyclic solid: an experimental/theoretical investigation of the dipole/quadrupole chemisorption phenoStereo- and Regioselective Alkyne Hydrometallation with Gold(III) Hydrides.Performance Assessment in Fingerprinting and Multi Component Quantitative NMR Analyses.Anion-dependent tendency of di-long-chain quaternary ammonium salts to form ion quadruples and higher aggregates in benzene.Gold(III) Alkyne Complexes: Bonding and Reaction Pathways.Intriguing Influence of -COOH-Driven Intermolecular Aggregation and Acid-Base Interactions with N,N-Dimethylformamide on the Second-Order Nonlinear-Optical Response of 5,15 Push-Pull Diarylzinc(II) Porphyrinates.Arene C-H activation by gold(iii): solvent-enabled proton shuttling, and observation of a pre-metallation Au-arene intermediate.Carbon-sulfur bond formation by reductive elimination of gold(iii) thiolates.Reductive Elimination Leading to C-C Bond Formation in Gold(III) Complexes: A Mechanistic and Computational Study.Probing the association of frustrated phosphine-borane Lewis pairs in solution by NMR spectroscopy.Unlocking Structural Diversity in Gold(III) Hydrides: Unexpected Interplay of cis/ trans-Influence on Stability, Insertion Chemistry, and NMR Chemical ShiftsIsocyanide insertion into Au–H bonds: first gold iminoformyl complexesGold(III) Alkyne Complexes: Bonding and Reaction PathwaysFrontispiece: Luminescent Gold(III) Thiolates: Supramolecular Interactions Trigger and Control Switchable Photoemissions from Bimolecular Excited StatesStereo- and Regioselective Alkyne Hydrometallation with Gold(III) HydridesAn investigation on the second-order NLO properties of novel cationic cyclometallated Ir(III) complexes of the type [Ir(2-phenylpyridine)2(9-R-4,5-diazafluorene)]+ (R=H, fulleridene) and the related neutral complex with the new 9-fulleriden-4-monoazaMechanistic Aspects of Water Oxidation Catalyzed by Organometallic Iridium ComplexesOrganometallic Iridium Catalysts Based on Pyridinecarboxylate Ligands for the Oxidative Splitting of WaterThermally Stable Gold(III) Alkene and Alkyne Complexes: Synthesis, Structures, and Assessment of the trans -Influence on Gold-Ligand Bond EnthalpiesSynthesis and Photophysical Properties of Au(III)–Ag(I) AggregatesHeterolytic bond activation at gold: evidence for gold(iii) H–B, H–Si complexes, H–H and H–C cleavageSelf-aggregation tendency of zirconocenium ion pairs which model polymer-chain-carrying species in aromatic and aliphatic solvents with low polarityA phosphine gold(I) pi-alkyne complex: tuning the metal-alkyne bond character and counterion position by the choice of the ancillary ligandIridium-EDTA as an efficient and readily available catalyst for water oxidationLow-temperature kinetic NMR studies on the insertion of a single olefin molecule into a Zr-C bond: assessing the counterion-solvent interplayDiscriminating halogen-bonding from other noncovalent interactions by a combined NOE NMR/DFT approachProbing the interactions between all components of the catalytic pool for homogeneous olefin polymerisation by diffusion NMR spectroscopyDisclosing the multi-faceted world of weakly interacting inorganic systems by means of NMR spectroscopyUnusual hafnium-pyridylamido/ER(n) heterobimetallic adducts (ER(n) = ZnR2 or AlR3)H2 activation by zirconaziridinium ions: σ-bond metathesis versus frustrated Lewis pair reactivityHydride Transfer to Gold: Yes or No? Exploring the Unexpected Versatility of Au···H-M Bonding in Heterobimetallic Dihydrides
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P50
description
researcher, ORCID id # 0000-0002-2679-8407
@en
wetenschapper
@nl
name
Luca Rocchigiani
@ast
Luca Rocchigiani
@en
Luca Rocchigiani
@es
Luca Rocchigiani
@nl
type
label
Luca Rocchigiani
@ast
Luca Rocchigiani
@en
Luca Rocchigiani
@es
Luca Rocchigiani
@nl
prefLabel
Luca Rocchigiani
@ast
Luca Rocchigiani
@en
Luca Rocchigiani
@es
Luca Rocchigiani
@nl
P106
P1153
25229127300
P21
P31
P496
0000-0002-2679-8407