Unexpectedly high concentrations of molecular chlorine in coastal air
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Atmospheric reactions Cl+CH3-(CH2)n-OH (n=0-4): a kinetic and theoretical study.Relative and absolute kinetic studies of 2-butanol and related alcohols with tropospheric Cl atoms.Combined vacuum ultraviolet laser and synchrotron pulsed field ionization study of CH2BrCl.CF3CF=CH2 and (Z)-CF3CF=CHF: temperature dependent OH rate coefficients and global warming potentials.The heterogeneous kinetics of HOBr and HOCl on acidified sea salt and model aerosol at 40-90% relative humidity and ambient temperature.Daytime reactions of 1,8-cineole in the troposphere.Theoretical investigation of the gas-phase reactions of CF2ClC(O)OCH3 with the hydroxyl radical and the chlorine atom at 298 K.Atmospheric reactions of methylcyclohexanes with Cl atoms and OH radicals: determination of rate coefficients and degradation products.Reactions of Cl atoms with alkyl esters: kinetic, mechanism and atmospheric implications.FTIR gas-phase kinetic study on the reactions of some acrylate esters with OH radicals and Cl atoms.Gas-phase reaction of two unsaturated ketones with atomic Cl and O3: kinetics and products.Atmospheric chemistry of (CF3)2C=CH2: OH radicals, Cl atoms and O3 rate coefficients, oxidation end-products and IR spectra.Theoretical insight into OH- and Cl-initiated oxidation of CF3OCH(CF3)2 and CF3OCF2CF2H &fate of CF3OC(X•)(CF3)2 and CF3OCF2CF2X• radicals (X=O, O2).Atmospheric oxidation mechanism and kinetic studies for OH and NO3 radical-initiated reaction of methyl methacrylateKinetics, products, and mechanisms of secondary organic aerosol formation.Reactive halogen chemistry in the troposphere.Computational study of H-abstraction reactions from CH3OCH2CH2Cl/CH3CH2OCH2CH2Cl by Cl atom and OH radical and fate of alkoxy radicals.Production of gas phase NO2 and halogens from the photolysis of thin water films containing nitrate, chloride and bromide ions at room temperature.Reactions between atomic chlorine and pyridine in solid para-hydrogen: infrared spectrum of the 1-chloropyridinyl (C5H5N-Cl) radical.Kinetic, mechanistic and temperature dependence study of Cl reactions with CH3OC(O)H and CH3CH2OC(O)H. Atmospheric implications.Linking electronic and molecular structure: insight into aqueous chloride solvation.Primary vs. secondary H-atom abstraction in the Cl-atom reaction with n-pentane.Theoretical investigations on the kinetics of Cl atom initiated reactions of series of 1-alkenes.Keto-ether and glycol-ethers in the troposphere: reactivity toward OH radicals and Cl atoms, global lifetimes, and atmospheric implications.Theoretical insight on atmospheric chemistry of HFE-365mcf3: reactions with OH radicals, atmospheric lifetime, and fate of alkoxy radicals (CF3CF2CH(O(•))OCH3/CF3CF2CH2OCH2O(•)).High levels of molecular chlorine in the Arctic atmosphereA global model of tropospheric chlorine chemistry: Organic versus inorganic sources and impact on methane oxidationThe role of BrNO3in marine tropospheric chemistry: A model studyThe first UK measurements of nitryl chloride using a chemical ionization mass spectrometer in central London in the summer of 2012, and an investigation of the role of Cl atom oxidationA dedicated study of New Particle Formation and Fate in the Coastal Environment (PARFORCE): Overview of objectives and achievementsOn OH uptake by sea salt under humid conditionsChlorine activation within urban or power plant plumes: Vertically resolved ClNO2and Cl2measurements from a tall tower in a polluted continental settingQuasi-Lagrangian investigation into dimethyl sulfide oxidation in maritime air using a combination of measurements and model
P2860
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P2860
Unexpectedly high concentrations of molecular chlorine in coastal air
description
article publié dans la revue scientifique Nature
@fr
scientific article published in Nature
@en
wetenschappelijk artikel
@nl
наукова стаття, опублікована в Nature в липні 1998
@uk
name
Unexpectedly high concentrations of molecular chlorine in coastal air
@en
Unexpectedly high concentrations of molecular chlorine in coastal air
@nl
type
label
Unexpectedly high concentrations of molecular chlorine in coastal air
@en
Unexpectedly high concentrations of molecular chlorine in coastal air
@nl
prefLabel
Unexpectedly high concentrations of molecular chlorine in coastal air
@en
Unexpectedly high concentrations of molecular chlorine in coastal air
@nl
P2093
P2860
P356
P1433
P1476
Unexpectedly high concentrations of molecular chlorine in coastal air
@en
P2093
B. J. Finlayson-Pitts
C. M. Berkowitz
C. W. Spicer
E. G. Chapman
J. D. Fast
J. M. Hubbe
R. A. Plastridge
P2860
P2888
P304
P356
10.1038/28584
P407
P577
1998-07-01T00:00:00Z
P6179
1025825970