Total synthesis of bryostatin 7 via C-C bond-forming hydrogenationCatalytic enantioselective C-H functionalization of alcohols by redox-triggered carbonyl addition: borrowing hydrogen, returning carbonOrganocatalytic Michael cycloisomerization of bis(enones): the intramolecular Rauhut-Currier reaction.Catalytic C-C bond formation via capture of hydrogenation intermediates.Ruthenium-Catalyzed Transfer Hydrogenation for C-C Bond Formation: Hydrohydroxyalkylation and Hydroaminoalkylation via Reactant Redox Pairs.Cross-metathesis-based approaches to heteroaromatics: combining catalysts for furan formation.Diastereo- and enantioselective anti-alkoxyallylation employing allylic gem-dicarboxylates as allyl donors via iridium-catalyzed transfer hydrogenation.anti-Diastereo- and enantioselective carbonyl (hydroxymethyl)allylation from the alcohol or aldehyde oxidation level: allyl carbonates as allylmetal surrogates.Iridium-catalyzed anti-diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol or aldehyde oxidation level.Total synthesis of (+)-roxaticin via C-C bond forming transfer hydrogenation: a departure from stoichiometric chiral reagents, auxiliaries, and premetalated nucleophiles in polyketide construction.Enantioselective iridium-catalyzed vinylogous Reformatsky-aldol reaction from the alcohol oxidation level: linear regioselectivity by way of carbon-bound enolatesIridium-catalyzed anti-diastereo- and enantioselective carbonyl (α-trifluoromethyl)allylation from the alcohol or aldehyde oxidation level.Synthesis of seco-B-ring bryostatin analogue WN-1 via C-C bond-forming hydrogenation: critical contribution of the B-ring in determining bryostatin-like and phorbol 12-myristate 13-acetate-like properties.Enantioselective Alcohol C-H Functionalization for Polyketide Construction: Unlocking Redox-Economy and Site-Selectivity for Ideal Chemical Synthesis.Iridium-catalyzed C-C coupling via transfer hydrogenation: carbonyl addition from the alcohol or aldehyde oxidation level employing 1,3-cyclohexadiene.Enantioselective iridium-catalyzed carbonyl allylation from the alcohol or aldehyde oxidation level using allyl acetate as an allyl metal surrogateRuthenium-catalyzed C-C bond forming transfer hydrogenation: carbonyl allylation from the alcohol or aldehyde oxidation level employing acyclic 1,3-dienes as surrogates to preformed allyl metal reagents.Ruthenium catalyzed C-C bond formation via transfer hydrogenation: branch-selective reductive coupling of allenes to paraformaldehyde and higher aldehydes.Enantioselective iridium-catalyzed carbonyl allylation from the alcohol or aldehyde oxidation level via transfer hydrogenative coupling of allyl acetate: departure from chirally modified allyl metal reagents in carbonyl additionDiastereo- and Enantioselective Reductive Aldol Addition of Vinyl Ketones via Catalytic HydrogenationMechanism and origins of regio- and enantioselectivities in RhI-catalyzed hydrogenative couplings of 1,3-diynes and activated carbonyl partners: intervention of a cumulene intermediateFormation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and IminesEnantioselective C-H crotylation of primary alcohols via hydrohydroxyalkylation of butadieneDiastereo- and Enantioselective Iridium Catalyzed Carbonyl (α-Cyclopropyl)allylation via Transfer Hydrogenation.Formation of C-C bonds via ruthenium-catalyzed transfer hydrogenation().Catalytic carbonyl addition through transfer hydrogenation: a departure from preformed organometallic reagents.Enantioselective iridium-catalyzed carbonyl allylation from the alcohol oxidation level via transfer hydrogenation: minimizing pre-activation for synthetic efficiencyDesymmetrization of enone-diones via rhodium-catalyzed diastereo- and enantioselective tandem conjugate addition-aldol cyclization.Formation of C-C Bonds via Iridium-Catalyzed Hydrogenation and Transfer Hydrogenation.Polyketide construction via hydrohydroxyalkylation and related alcohol C-H functionalizations: reinventing the chemistry of carbonyl addition.Direct vinylation of alcohols or aldehydes employing alkynes as vinyl donors: a ruthenium catalyzed C-C bond-forming transfer hydrogenation.Catalyst-directed diastereoselectivity in hydrogenative couplings of acetylene to alpha-chiral aldehydes: formal synthesis of all eight L-hexoses.anti-Diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level employing a cyclometallated iridium catalyst: alpha-methyl allyl acetate as a surrogate to preformed crotylmetal reagents.Diene hydroacylation from the alcohol or aldehyde oxidation level via ruthenium-catalyzed C-C bond-forming transfer hydrogenation: synthesis of beta,gamma-unsaturated ketones.Formation of C-C Bonds via Ruthenium Catalyzed Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation LevelAsymmetric Iridium-Catalyzed C-C Coupling of Chiral Diols via Site-Selective Redox-Triggered Carbonyl AdditionCatalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol-Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier.Nickel-Catalyzed Cross-Coupling of Vinyl Dioxanones to Form Enantiomerically Enriched Cyclopropanes.Metal-catalyzed reductive coupling of olefin-derived nucleophiles: Reinventing carbonyl addition.Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents.
P50
Q24607710-2CF03D80-AB2C-4540-92E5-1C36C702B745Q26849589-F2774141-DC06-4A27-AB59-9B9EA1A6943CQ29042426-E0FE49EF-8B44-4F42-BB11-2C1DB2BDD081Q30961052-54DE52E0-3E0A-47E6-A0D9-9AA77F8D3DCFQ31125381-A3DF06AF-ECC9-4724-A4FC-5D33EF9F310FQ33734854-0E22B769-95CC-41F6-9BDC-A6FDCA52C3F0Q34094596-7B4311EE-E848-46DF-BDC1-387FB144FD0DQ34103647-7DEC79F7-5EAE-433E-8D49-A36A9FE4E0CEQ34120288-F2723740-1D96-45D3-ACC5-934482F873B0Q34144693-3BF7B827-EF09-42DA-A6BF-277028791ED7Q34168946-3BFE3456-509D-4E25-8A72-105CED0C2A72Q34176496-D97DD68E-35D2-44A3-A631-F6E0001C48CAQ34282542-C7EFC156-87F1-4FC7-B574-F8BA287A316BQ34523499-06B0BF32-27E6-4237-B547-AAB71832CA00Q34746872-089BDD43-9ED7-4C5F-8F5D-C44D72AF5017Q34774734-EB3EE865-BB42-4D18-A9DE-90D606E3AD7AQ34774738-72397770-30F3-4071-8130-1D5DFBD0BFAFQ34784981-C34DC07F-5B7B-4C99-96FB-F65754B2CA86Q34848081-68143919-F119-4490-8A82-D540622CC550Q35173755-297DCFC4-EC02-4F57-9E1C-33FD87493C05Q35176203-E3261EAF-3280-4BBE-9C75-1AA55196BDA4Q35808518-FC39FC94-3D0E-4EF3-BDC0-76C78E6D8497Q36226256-4FF7118E-19B0-47F7-80F3-2B8282403898Q36233558-DBB6F59A-B1EE-495D-8CBD-FE48ECC2F3ACQ36619411-A6B6447B-AA9E-470E-A031-2D1F0F1D7496Q37336741-1922E447-BE32-4A72-B5F8-7F3345087746Q37660116-A9494DDE-6402-4CDA-BF55-AAE49244507EQ37681507-66D8C716-27AD-4FA6-909C-9B94EAB43299Q37913035-703A14BF-BD04-4261-9C1F-524879691195Q38186988-43322AA5-D7B7-424B-B0F7-3543E855B717Q38280672-FC84D7A5-031D-467E-8DDD-2A124535CC04Q38280684-0EE7ED86-D59F-44B0-BBD2-51800A18797DQ38280705-21EA1BC1-1250-471E-BB5F-E666CC7A3354Q38280750-A87526CA-2FC1-4193-998E-2B2E1A97E88AQ38414807-D2565FDC-0DDD-4998-82B6-9D7282643D22Q38549564-74DE792E-4CEF-4E23-862B-7882B3EA1AA1Q38632330-B493D471-1CE5-4452-8FA6-37A1AD52B250Q38794345-B7932ECE-F2CD-4612-9EBA-EFBAFDC75E81Q39009434-21AC26AF-B43E-441A-B2AA-519DEAAB0B8EQ39021555-44B2D10E-31D7-4144-9172-DB1791E725DA
P50
description
Ameerika Ühendriikide keemik
@et
American chemist
@en
Amerikaans scheikundige
@nl
amerikai kémikus
@hu
ceimiceoir Meiriceánach
@ga
chimist american
@ro
chimiste américain
@fr
kimist amerikan
@sq
químic estatunidenc
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químico estadounidense
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name
Michael J. Krische
@ast
Michael J. Krische
@ca
Michael J. Krische
@de
Michael J. Krische
@en
Michael J. Krische
@es
Michael J. Krische
@fr
Michael J. Krische
@ga
Michael J. Krische
@hu
Michael J. Krische
@nl
Michael J. Krische
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type
label
Michael J. Krische
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Michael J. Krische
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Michael J. Krische
@de
Michael J. Krische
@en
Michael J. Krische
@es
Michael J. Krische
@fr
Michael J. Krische
@ga
Michael J. Krische
@hu
Michael J. Krische
@nl
Michael J. Krische
@sl
prefLabel
Michael J. Krische
@ast
Michael J. Krische
@ca
Michael J. Krische
@de
Michael J. Krische
@en
Michael J. Krische
@es
Michael J. Krische
@fr
Michael J. Krische
@ga
Michael J. Krische
@hu
Michael J. Krische
@nl
Michael J. Krische
@sl
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0000 0000 4699 7396
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no2007087565