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Water-soluble Mo3S4 clusters bearing hydroxypropyl diphosphine ligands: synthesis, crystal structure, aqueous speciation, and kinetics of substitution reactions.Mechanism of [3+2] cycloaddition of alkynes to the [Mo3 S4 (acac)3 (py)3 ][PF6 ] cluster.Chiral [Mo3S4H3(diphosphine)3]+ hydrido clusters and study of the effect of the metal atom on the kinetics of the acid-assisted substitution of the coordinated hydride: Mo vs W.Site specific ligand substitution in cubane-type Mo3FeS(4)(4+) clusters: kinetics and mechanism of reaction and isolation of mixed ligand Cl/SPh complexes.Combined kinetic and DFT studies on the stabilization of the pyramidal form of H3PO2 at the heterometal site of [Mo3M'S4(H2O)10]4+ clusters (M' = Pd, Ni).Synthesis, reactivity, and kinetics of substitution in W3PdSe4 cuboidal clusters. A reexamination of the kinetics of substitution of the related W3S4 cluster with thiocyanate.A DFT and TD-DFT approach to the understanding of statistical kinetics in substitution reactions of M3Q4 (M = Mo, W; Q = S, Se) cuboidal clusters.Kinetic and DFT studies on the mechanism of C-S bond formation by alkyne addition to the [Mo3S4(H2O)9]4+ cluster.Studies on the Reactivity of the [W3 S4 Br3 (edpp)3 ]+ [edpp = (2-aminoethyl)diphenylphosphine] Cluster Cation towards Bases: The Active Role of the Amino GroupNew Insights into the Mechanism of Proton Transfer to Hydride Complexes: Kinetic and Theoretical Evidence Showing the Existence of Competitive Pathways for Protonation of the Cluster [W3S4H3(dmpe)3]+ with AcidsSynthesis of the Novel [W3PdS4H3(dmpe)3(CO)]+Cubane Cluster and Kinetic Studies on the Substitution of Coordinated Hydrides in Acidic MediaThe Structure of ([W3Q4X3(dmpe)3]+, Y-) Ion Pairs (Q = S, Se; X = H, OH, Br; Y = BF4, PF6, dmpe = Me2PCH2CH2PMe2) in Dichloromethane Solution and the Effect of Ion-Pairing on the Kinetics of Proton Transfer to the Hydride Cluster [W3S4H3(dmpe)3]+The Effect of the “Inert” Counteranions in the Deprotonation of the Dihydrogen Complextrans-[FeH(η2-H2)(dppe)2]+: Kinetic and Theoretical StudiesCrucial role of anions on the deprotonation of the cationic dihydrogen complex trans-[FeH(eta2-H2)(dppe)2]+Catalytic effect of a second H3PO2 in the mechanism of stabilisation of the unstable pyramidal tautomer of H3PO2 coordinated at [Mo3S4M'] clusters (M' = Ni, Pd)Ag(I) complexes with alkylidene-bis(2-aminopyrimidines) as building units for discrete metallomacrocyclic frames. A structural and solution studyDihydrogen complexes: striking effect of ion pairing to BF(4)(-) on the rotation of coordinated dihydrogen and the (19)F relaxation timeKinetic, DFT and TD-DFT studies on the mechanism of stabilization of pyramidal H3PO3 at the [Mo3M'S4(H2O)10]4+ clusters (M' = Pd, Ni)
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description
onderzoeker
@nl
researcher
@en
հետազոտող
@hy
name
M. Jesús Fernández-Trujillo
@ast
M. Jesús Fernández-Trujillo
@en
M. Jesús Fernández-Trujillo
@es
M. Jesús Fernández-Trujillo
@nl
type
label
M. Jesús Fernández-Trujillo
@ast
M. Jesús Fernández-Trujillo
@en
M. Jesús Fernández-Trujillo
@es
M. Jesús Fernández-Trujillo
@nl
prefLabel
M. Jesús Fernández-Trujillo
@ast
M. Jesús Fernández-Trujillo
@en
M. Jesús Fernández-Trujillo
@es
M. Jesús Fernández-Trujillo
@nl
P106
P1153
6602929471
P31
P496
0000-0003-2832-822X