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Tris(2,4,6-trimethoxyphenyl)methyl carbenium ion for charge derivatization of amines and amino acids.Hexacoordinated phosphates: how to teach old chiral anions new asymmetric tricks.Cationic triangulenes and helicenes: synthesis, chemical stability, optical properties and extended applications of these unusual dyes.Diversity-oriented synthesis of heterocycles and macrocycles by controlled reactions of oxetanes with α-iminocarbenes.Remote stereoselective deconjugation of α,β-unsaturated esters by simple amidation reactions.Enantioselective recognition of a chiral quaternary ammonium ion by C3 symmetric cyclic hexapeptides.Enantiomeric separation of functionalized ethano-bridged Tröger bases using macrocyclic cyclofructan and cyclodextrin chiral selectors in high-performance liquid chromatography and capillary electrophoresis with application of principal component anLarge-scale synthesis and resolution of TRISPHAT [tris(tetrachlorobenzenediolato) phosphate(V)] anion.Enantioselective and regioselective ruthenium-catalyzed decarboxylative etherification of allyl aryl carbonates.Biphasic enantioselective olefin epoxidation using Tropos dibenzoazepinium catalysts.Self-adaptable catalysts: substrate-dependent ligand configuration.Physicochemical and Electronic Properties of Cationic [6]Helicenes: from Chemical and Electrochemical Stabilities to Far-Red (Polarized) Luminescence.Functionalized cationic [4]helicenes with unique tuning of absorption, fluorescence and chiroptical properties up to the far-red range.Specific labeling of mitochondria of Chlamydomonas with cationic helicene fluorophores.Stereoselective and Enantiospecific Mono- and Bis-C-H Azidation of Tröger Bases: Insight on Bridgehead Iminium Intermediates and Application to Anion-Binding Catalysis.Synthesis of Pyrrolidines and Pyrrolizidines with α-Pseudoquaternary Centers by Copper-Catalyzed Condensation of α-Diazodicarbonyl Compounds and Aryl γ-Lactams.Efficient Synthesis of Ditopic Polyamide Receptors for Cooperative Ion Pair Recognition in Solution and Solid States.Enantiospecific Elongation of Cationic Helicenes by Electrophilic Functionalization at Terminal Ends.A Ratiometric Luminescent Switch Based on Platinum Complexes Tethered to a Crown-Ether Scaffold.Zwitterionic [4]helicene: a water-soluble and reversible pH-triggered ECD/CPL chiroptical switch in the UV and red spectral regions.Selective Imaging of Late Endosomes with a pH-Sensitive Diazaoxatriangulene Fluorescent Probe.New biphenyl iminium salt catalysts for highly enantioselective asymmetric epoxidation: role of additional substitution and dihedral angle.Potassium ion-selective fluorescent and pH independent nanosensors based on functionalized polyether macrocycles† †Electronic supplementary information (ESI) available. CCDC 1045592. For ESI and crystallographic data in CIF or other electronic formaPummerer fragmentation vs. Pummerer rearrangement: a mechanistic analysisCombined reversible switching of ECD and quenching of CPL with chiral fluorescent macrocyclesEffective chiral recognition among ions in polar mediaElectrogenerated Chemiluminescence of Cationic Triangulene Dyes: Crucial Influence of the Core HeteroatomsTrimesitylmethylphosphonium Cation. Supramolecular Stereocontrol and Simple Enantiomerization Mechanism DeterminationChiral Selectivity in the Binding of [4]Helicene Derivatives to Double-Stranded DNABimetallic Iridium(III) Complexes Consisting of Ir(ppy)2Units (ppy = 2-Phenylpyridine) and Two Laterally Connected N∧N Chelates as Bridge: Synthesis, Separation, and Photophysical PropertiesPhosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviourPolycyclic Indoline-Benzodiazepines through Electrophilic Additions of α-Imino Carbenes to Tröger Bases.Conformational preference and configurational control of highly symmetric spirobi[dibenzazepinium] cationNovel heteroleptic cis-(C--N)2Pd(II) chelates for the preparation of enantiopure planar chiral cyclopalladated 2-[tricarbonyl(eta6-phenyl)chromium]pyridineEfficient Enantioselective Extraction of Tris(diimine)ruthenium(II) Complexes by Chiral, Lipophilic TRISPHAT Anions This work was supported by the Swiss National Science Foundation. We thank A. Pinto, J.-P. Saulnier, W. Kloeti, and E. Sandmeyer forEfficient resolution of a dinuclear triple helicate by asymmetric extraction/precipitation with TRISPHAT anions as resolving agentsConfigurational ordering of cationic chiral dyes using a novel C(2)-symmetric hexacoordinated phosphate anionA highly configurationally stable [4]heterohelicenium cationSynthesis, enantiomeric conformations, and stereodynamics of aromatic ortho-substituted disulfonesOne-step stereoselective synthesis and NMR chiral shift properties of a novel hexacoordinated phosphorus cation
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P50
description
researcher
@en
name
Jérôme Lacour
@en
Jérôme Lacour
@nl
type
label
Jérôme Lacour
@en
Jérôme Lacour
@nl
prefLabel
Jérôme Lacour
@en
Jérôme Lacour
@nl
P106
P31
P496
0000-0001-6247-8059