about
Cyclopropylmethylation of benzylic and allylic chlorides with cyclopropylmethylstannane catalyzed by gallium or indium halideDiastereoselective production of homoallylic alcohols bearing quaternary centers from gamma-substituted allylic indiums and ketones.Regioselective carboindation of simple alkenes with indium tribromide and ketene silyl acetals.Direct reduction of alcohols: highly chemoselective reducing system for secondary or tertiary alcohols using chlorodiphenylsilane with a catalytic amount of indium trichloride.Diastereoselective addition of gamma-substituted allylic nucleophiles to ketones: highly stereoselective synthesis of tertiary homoallylic alcohols using an allylic tributylstannane/stannous chloride system.Direct conversion of carbonyl compounds into organic halides: indium(III) hydroxide-catalyzed deoxygenative halogenation using chlorodimethylsilane.Indium-catalyzed direct chlorination of alcohols using chlorodimethylsilane-benzil as a selective and mild system.Esters as acylating reagent in a Friedel-Crafts reaction: indium tribromide catalyzed acylation of arenes using dimethylchlorosilane.Germanium(II)-mediated reductive cross-aldol reaction of bromoaldehydes with aldehydes: NMR studies and ab initio calculations.First Isolation and Characterization of the Highly Coordinated Group 14 Enolates: Effects of the Coordination Controls on the Geometry and Tautomerization of Germyl Enolates.Bu2SnIH-promoted proximal bond cleavage of methylenecyclopropanes and successive radical cyclization and/or Pd-catalyzed coupling reaction.In- or In(I)-employed tailoring of the stereogenic centers in the Reformatsky-type reactions of simple ketones, alpha-alkoxy ketones, and beta-keto esters.InCl3/I2-catalyzed cross-coupling of alkyl trimethylsilyl ethers and allylsilanes via an in situ derived combined Lewis acid of InCl3 and Me3SiI.Zn(II) chloride-catalyzed direct coupling of various alkynes with acetals: facile and inexpensive access to functionalized propargyl ethers.Direct coupling of alcohols with alkenylsilanes catalyzed by indium trichloride or bismuth tribromide.Indium Catalyzed Hydrofunctionalization of Styrene Derivatives Bearing a Hydroxy Group with Organosilicon Nucleophiles.Generation of α-Iminyl Radicals from α-Bromo Cyclic N-Sulfonylimines and Application to Coupling with Various Radical Acceptors Using a Photoredox Catalyst.Synthesis and Characterization of Dibenzo[a,f]pentalene: Harmonization of the Antiaromatic and Singlet Biradical Character.Regio- and stereoselective hydrostannation of allenes using dibutyliodotin hydride (Bu2SnIH) and successive coupling with aromatic halides.C3 -Symmetric Boron Lewis Acid with a Cage-Shape for Chiral Molecular Recognition and Asymmetric Catalysis.Tuning Lewis Acidity by a Transannular pπ -σ* Interaction between Boron and Silicon/Germanium Atoms Supported by a Cage-Shaped Framework.1,8-Diphenyl-9,10-Bis(arylethynyl)phenanthrenes: Synthesis, Distorted Structure, and Optical Properties.Coupling reaction of alkyl chlorides with silyl enolates catalyzed by indium trihalide.In(III)-mediated chemoselective dehydrogenative interaction of ClMe(2)SiH with carboxylic acids: direct chemo- and regioselective Friedel-Crafts acylation of aromatic ethers.Synthesis of 1,4-Dicarbonyl Compounds from Silyl Enol Ethers and Bromocarbonyls, Catalyzed by an Organic Dye under Visible-Light Irradiation with Perfect Selectivity for the Halide Moiety over the Carbonyl Group.Direct coupling reaction between alcohols and silyl compounds: enhancement of Lewis acidity of Me3SiBr using InCl3.The reductive amination of aldehydes and ketones by catalytic use of dibutylchlorotin hydride complex.Synthesis of Thioethers by InI₃-Catalyzed Substitution of Siloxy Group Using Thiosilanes.High chelation control of three contiguous stereogenic centers in the Reformatsky reactions of indium enolates with alpha-hydroxy ketones: unexpected stereochemistry of lactone formation.Coupling Reaction of Enol Derivatives with Silyl Ketene Acetals Catalyzed by Gallium Trihalides.Direct carbon-carbon bond formation from alcohols and active methylenes, alkoxyketones, or indoles catalyzed by indium trichloride.Synthesis, characterization, and properties of a benzofuran-based cage-shaped borate: photo activation of Lewis acid catalysts.In- or in(I)-employed diastereoselective Reformatsky-type reactions with ketones: 1H NMR investigations on the active species.Indium Tribromide Catalyzed Coupling Reaction of Enol Ethers with Silyl Ketene Imines toward the Synthesis of β,γ-Unsaturated Nitriles.Allylic tantalums as highly imine-selective reagents.Catalytic generation of indium hydride in a highly diastereoselective reductive aldol reaction.One-pot synthesis of nitrogen heterocycles initiated by regio- and diastereoselective carbon-carbon bond formation of bifunctional carbonyl compounds.Indium chloride catalyzed alkylative rearrangement of propargylic acetates using alkyl chlorides, alcohols, and acetates: facile synthesis of α-alkyl-α,β-unsaturated carbonyl compounds.Synthesis of alkylbismuths by regiodivergent carbobismuthination of simple alkenes.Regio- and Stereoselective Allylindation of Alkynes Using InBr₃ and Allylic Silanes: Synthesis, Characterization, and Application of 1,4-Dienylindiums toward Skipped Dienes.
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description
researcher
@en
wetenschapper
@nl
name
Makoto Yasuda
@en
Makoto Yasuda
@nl
type
label
Makoto Yasuda
@en
Makoto Yasuda
@nl
prefLabel
Makoto Yasuda
@en
Makoto Yasuda
@nl
P106
P31
P496
0000-0002-6618-2893