about
Activation of a water molecule using a mononuclear Mn complex: from Mn-aquo, to Mn-hydroxo, to Mn-oxyl via charge compensation.Hydroxide ion versus chloride and methoxide as an exogenous ligand reveals the influence of hydrogen bonding with second-sphere coordination water molecules in the electron transfer kinetics of Mn complexes.Electrochemical study of a nonheme Fe(ii) complex in the presence of dioxygen. Insights into the reductive activation of O2 at Fe(ii) centers.Fe(II) and Fe(III) mononuclear complexes with a pentadentate ligand built on the 1,3-diaminopropane unit. Structures and spectroscopic and electrochemical properties. Reaction with H2O2.Characterizations of chloro and aqua Mn(II) mononuclear complexes with amino-pyridine ligands. Comparison of their electrochemical properties with those of Fe(II) counterparts.Electrochemical formation of Mn(III)-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands.Controlled redox conversion of new X-ray-Characterized Mono- and dinuclear heptacoordinated Mn(II) complexes into di-micro-oxo-dimanganese core complexes.A systematic resolution of sulfur in reticulated vitreous carbon using X-ray absorption spectroscopy.Syntheses, X-ray structures, solid state high-field electron paramagnetic resonance, and density-functional theory investigations on chloro and aqua Mn(II) mononuclear complexes with amino-pyridine pentadentate ligands.Characterization and Subsequent Reactivity of an Fe-Peroxo Porphyrin Generated by Electrochemical Reductive Activation of O2.Synthesis, structure, and characterization of new mononuclear Mn(II) complexes. Electrochemical conversion into new oxo-bridged Mn(2)(III,IV) complexes. Role of chloride ions.Reactivity of an aminopyridine [LMnII]2+ complex with H2O2. Detection of intermediates at low temperature.Geometric and electronic structures of peroxomanganese(III) complexes supported by pentadentate amino-pyridine and -imidazole ligands.Proton-coupled electron transfers in biomimetic water bound metal complexes. The electrochemical approach.Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes.A new mononuclear manganese(III) complex of an unsymmetrical hexadentate N3O3 ligand exhibiting superoxide dismutase and catalase-like activity: synthesis, characterization, properties and kinetics studies.Reactivity of MnII with superoxide. Evidence for a [MnIIIOO]+ unit by low-temperature spectroscopies.Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal CenterMolecular Electrochemical Catalysis of the CO2-to-CO Conversion with a Co Complex: A Cyclic Voltammetry Mechanistic InvestigationHighly Selective Molecular Catalysts for the CO2-to-CO Electrochemical Conversion at Very Low Overpotential. Contrasting Fe vs Co Quaterpyridine Complexes upon Mechanistic StudiesDual Homogeneous and Heterogeneous Pathways in Photo- and Electrocatalytic Hydrogen Evolution with Nickel(II) Catalysts Bearing Tetradentate Macrocyclic LigandsA New Manganese Dinuclear Complex with Phenolate Ligands and a Single Unsupported Oxo Bridge. Storage of Two Positive Charges within Less than 500 mV. Relevance to PhotosynthesisSynthesis, structure, and characterisation of a new phenolato-bridged manganese complex [Mn2(mL)2]2+: chemical and electrochemical access to a new mono-mu-oxo dimanganese core unitCobalt clathrochelate complexes as hydrogen-producing catalystsInfluence of second sphere hydrogen bonding interaction on a manganese(II)-aquo complexPhotochromic and reductive electrochemical switching of a dithiazolylethene with large redox modulation
P50
Q30576856-4018346B-D738-43D0-A2AE-46D5FFE98073Q34188698-2DCF79D3-779C-4252-8BA5-7708BC46CE73Q41588761-A21DCA0C-35D4-413C-A0D4-305DFB150C17Q44382849-A2CEFBAD-74FB-4518-B74B-0B024521BFCAQ44482400-0E376510-75BF-4D9B-B7D9-E3D592FFA876Q44643671-AF60DFE8-C7C7-45DD-9812-B1C21217F8BDQ44965633-F46F1D25-3300-4754-9ADB-1F4B88A5708BQ46321402-F056E631-45EB-418E-95B8-AF97668333E8Q46347005-E9206BED-29CC-408F-B9A5-3E2FA043AD1AQ46448382-462885FF-2C0C-49E4-934C-8533528D2649Q46475587-B8266285-B4F2-4337-AE4A-4502742D2025Q46679567-2C5EBAAB-D6A4-488E-A4BD-ED72A17E2B94Q46950816-FA75E4E7-6138-4FAB-BD8F-E50679DDCFCBQ48153493-07DF18E2-6AD9-4C7C-8143-F0E432542BEDQ50199747-5B8C31FC-0689-48A9-B92A-9BDBE10F67B5Q50216544-0CA15295-7B66-4C10-B90C-3D07DC69766FQ50471581-C77D4253-C79B-4B69-A8FD-979972AC38C9Q57631657-27E4BA53-BE19-4B46-91B1-AFA42C1034A7Q59165474-95D637B4-4165-4555-99A9-DA6D907C1FBCQ59165485-96CB0B62-CD8D-4EF5-9FE9-6700ADB7582CQ59165540-27CE5EB4-38A5-4F6D-9B77-809F4F1BB1C5Q74833084-BFAE1D88-C070-4F40-939A-C0487DBCB560Q79915612-3F52F65A-FA6B-470B-ADA5-07EA2B199240Q82607645-5E4F2C39-F9F5-46F8-A7ED-7CAAEF2E8D44Q83065575-F8462036-AC6D-42B9-AB29-A1C202363A57Q83367739-D225AE4D-EEAB-46DA-8AB8-D2DA0CABD4BC
P50
name
Elodie Anxolabéhère-Mallart
@en
type
label
Elodie Anxolabéhère-Mallart
@en
prefLabel
Elodie Anxolabéhère-Mallart
@en